摘要
以具有粗糙结构的超疏水的聚四氟乙烯(PTFE)涂层为基体,研究具有不同表面张力的乙醇/水混合溶液在表面的润湿.通过空气分率的计算并进行液滴受力分析.结果表明,随着表面张力的降低,乙醇/水混合溶液逐渐填满涂层表面的粗糙结构,当表面张力大于约28mN·m-1时,溶液首先填满表面上的条纹状结构;当表面张力小于约28mN·m-1时,溶液填满表面上的乳突状结构.当条纹状结构被填满时,粗糙表面空气分率下降很小,溶液不能润湿PTFE涂层表面;当乳突状结构被填满时,粗糙表面空气分率迅速下降,溶液能够润湿PTFE涂层.
The wetting behaviors of ethanol/water solutions with different surface tensions were studied on the rough superhydrophobic polytetrafluoroethylene （PTFE） coating. Air fraction was calculated using Cassie equation and the forces were compared. The result indicated that the ethanol/water solutions gradually filled in the multilevel structures of the PTFE coating with the decrease in the surface tension. Only the stripe structure was filled when the surface tension was greater than 28 mN·m^-1. When the surface tension was less than 28 mN ·m^-1, the papillary structure was also filled. Because it has little contribution to the air fraction, the surface could not be wetted when the stripe structure was filled. However, the surface could be wetted by the solutions when the papillary structure, which had a considerable contribution to the air fraction, was filled.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
2007年第8期1168-1172,共5页
Acta Physico-Chimica Sinica
基金
国家自然科学基金(20236010
20246002
20376032
20676062)
国家重点基础研究发展计划项目(2003CB615700)
海外青年学者合作研究基金(20428606)
江苏省自然科学重点基金前期预演项目(BK2004215)
国家高技术研究发展规划(863项目)(2006AA03Z455)资助
