期刊文献+

双极膜电渗析技术在有机酸生产中的应用进展 被引量:19

Applications of bipolar membrane electrodialysis in the production of organic acids
下载PDF
导出
摘要 双极膜电渗析技术能直接将水解离为H+和OH-,因而能在不外加酸的情况下使有机酸盐转化为有机酸,且不产生任何废液.这一特殊的优势是传统工艺中的酸化沉淀法、离子交换法和普通电渗析无法比拟的.近年来,双极膜在柠檬酸和乳酸等有机酸生产中的应用研究进展迅猛.因此现谨就双极膜电渗析技术的原理、与传统工艺相比的优势、在实验和生产方面的研究进展和对未来的展望作一综述,以指导相关的研究工作. Under the driving force of an electrical field, a bipolar membrane can efficiently dissociate water into hydrogen(H^+ ) and hydroxyl (OH^-)ions. So electrodialysis with bipolar membrane (EDBM) can be used to directly acidify the organic salt without the addition of other inorganic acids and avoiding waste streams. Therefore, this technique is simultaneously economically attractive and has a low impact on the environment as compared with ion - exchange and conventional electrodialysis techniques. However, the number of installed EDBM plants worldwide has been relatively small until now. This is due to many reasons, such as high investment, a perceived unreliability of the technology and the limited range of economical/practical applications. With the development of EDBM technology, the number of EDBM plants in operation should greatly increase in the next few years. The principle of EDBM, the recent advances in this filed are reviewed. And the future development trends are also proposed.
出处 《膜科学与技术》 CAS CSCD 北大核心 2007年第3期75-79,共5页 Membrane Science and Technology
关键词 双极膜 电渗析 有机酸 柠檬酸 乳酸 bipolar membranes electrodialysis organic acids citric acid lactic acid
  • 相关文献

参考文献4

二级参考文献15

  • 1周溪,殷斌烈.亚氨基二乙酸的合成研究[J].湖北化工,1994,11(4):57-58. 被引量:2
  • 2R. Simons,G. Khanarian.Water dissociation in bipolar membranes: Experiments and theory[J]. The Journal of Membrane Biology . 1978 (1-2) 被引量:1
  • 3Simons,R.A mechanism for water flow in bipolar membranes, J. Membrane Science and Technology . 1993 被引量:1
  • 4Coster,H. G. L.A quantitative analysis of the voltage-current relationships of fixed charge membranes and the associated property of "punch-through". Biophysical Journal . 1965 被引量:1
  • 5Mauro,A.Space charge region in fixed charge membranes and the associated property of capacitance. Biophysical Journal . 1962 被引量:1
  • 6Coster,H. G. L.The double fixed charge membrane. Biophysical Journal . 1973 被引量:1
  • 7Simons,R.Strong electric fields effects on proton transfer between membrane-bound amines and water. Nature . 1979 被引量:1
  • 8Simons,R.Preparation of a high performance bipolar membrane, J. Membrane Science and Technology . 1993 被引量:1
  • 9Onsager,L.Deviations from Ohm’s Law in weak electrolytes, J. The Journal of Chemical Physics . 1934 被引量:1
  • 10Mani,K. N.Electrodialysis water splitting technology, J. Membrane Science and Technology . 1991 被引量:1

共引文献18

同被引文献242

引证文献19

二级引证文献60

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部