摘要
The adductive reaction of Ni[S2P(OCH2CH2Ph)2]2 with pyridine was studied by spectrographic method and the equilibrium constants was found to be β1=(1.12±0.09)×102,β2=(2.40±0.41)×104,R1=0.997,R2=0.998.The adduct Ni[S2P(OCH2CH2Ph)2]2·2Py was characterized by elemental analysis,IR spectra,single-crystal X-ray diffraction method.The crystal structure belongs to monoclinic system,space group P 21/c with the following crystallographic parameters:a=9.240(3),b=16.124(8),c=14.148(7),α=90.00°,β=92.07(4)°,γ=90.00°.
The adductive reaction of Ni[ S2 P（OCH2 CH2 Ph）2 ] 2 with pyridine was studied by spectrographic method and the equilibrium constants was found to be β1 = （1.12 ±0. 09） × 10^2 ,β2 = （2. 40 ±0. 41） × 10^4 ,R1 =0. 997,R2 =0. 998. The adduct Nil S2P （OCH2CH2Ph） 2 ] 2 · 2Py was characterized by elemental analysis, IR spectra, single-crystal X-ray diffraction method. The crystal structure belongs to monoclinic system, space group P 21/c with the following crystallographic parameters： a = 9. 240 （3）A, b = 16. 124 （8）A,c = 14. 148 （7）A,α = 90. 00° ,13 =92. 07（4）° ,γ =90. 00°
出处
《化学研究与应用》
CAS
CSCD
北大核心
2007年第5期527-531,共5页
Chemical Research and Application
基金
四川省教育厅自然科学基金预研项目(2005C016)资助
自贡市科技局项目(06G2045)资助
