摘要
Small addition of mischmetal (MM) into aluminum alloys can lead to grain refinement. However, it is still uncertain whether the same effect applies to Mg-Al alloys. This work indicated that small amount of mischmetal addition ranging from 0.1% to 1.2% (mass fraction) did not cause grain refinement in Mg-Al alloys. On the contrary, they tended to coarsen the grains. When added into Mg-Al alloys, MM reacted preferentially with Al to form Al11 MM3 phase. As Al11 MM3 phase mainly distributed within α-Mg grains than at grain boundaries, it had little effect in restricting grain growth. In addition, MM reacted with Al8(Mn, Fe)5 or ε-AlMn particles to form Al-MM-Mn compounds, thus it reduced the amount of heterogeneous nuclei in the melt and resulted in remarkable grain coarsening.
Small addition of mischmetal (MM) into aluminum alloys can lead to grain refinement. However, it is still uncertain whether the same effect applies to Mg-Al alloys. This work indicated that small amount of mischmetal addition ranging from 0.1% to 1.2% (mass fraction) did not cause grain refinement in Mg-Al alloys. On the contrary, they tended to coarsen the grains. When added into Mg-Al alloys, MM reacted preferentially with Al to form Al11 MM3 phase. As Al11 MM3 phase mainly distributed within α-Mg grains than at grain boundaries, it had little effect in restricting grain growth. In addition, MM reacted with Al8(Mn, Fe)5 or ε-AlMn particles to form Al-MM-Mn compounds, thus it reduced the amount of heterogeneous nuclei in the melt and resulted in remarkable grain coarsening.
基金
Project supported by Beijing Municipal Science & Technology Research Project (Y0405004040211)