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电解法制备高纯度^(18)O_2 被引量:1

Preparation of High Purity ^(18)O_2 by Electrolysis Method
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摘要 采用自行设计制造的石英玻璃电解装置,以重氧重水为原料,通过碱性介质电解法进行了18O气体的制备,在原料重氧重水18O的摩尔分数>80%条件下,最终制得18O气体中18O2摩尔分数达63.66%,表明整个电解系统气密性良好。此外,制得的气体能够满足电子回旋共振离子源提供18O重离子束的实验要求。 ^18O2 gas is prepared from the electrolysis of heavy oxygen heavy water using a set of self-made quartz glass electrolysis system. Under the condition of raw material heavy oxygen heavy water ^18O molar content is higher than 80%, the ^18O2 content of the prepared oxygen gas is determined to be 63.66%, which indicates that the whole electrolysis system is tight. In addition, the requirement of delivering ^18O2 beams from the electron cyclotron resonance ion source can be satisfied by the obtained ^18O2 gas.
出处 《同位素》 CAS 北大核心 2007年第1期29-32,共4页 Journal of Isotopes
基金 国家自然科学基金项目(10575122)
关键词 电解 重氧重水 ^18O2 electrolysis heavy oxygen heavy water ^18O2
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  • 1郑永飞,陈江峰编著..稳定同位素地球化学[M].北京:科学出版社,2000:316.
  • 2埃尔维奇 JA,琼斯 JR.同位素的基本化学和应用[M].北京:原子能出版社,1987:228-229. 被引量:2
  • 3ZHANG L,ZHAO JH,ZHENG JW,et al.Neutron-rich Heavy Residues and Exotic Multinucleon Transfer[J].Physical Rev C,1998,58:156-163. 被引量:1
  • 4YUAN S,YANG W,MOU W.A New Isotope of Proactinium ^239Pa[J].ZPA,1995,235-236. 被引量:1
  • 5BECHTEL A,HOERNES S.Oxygen Isotope Fractionation Between Oxygen of Different Sites in Illite Minerals:a Potential Geothermometer[J].Contrib Mineral Petrol,1990,104:463-470. 被引量:1
  • 6SHARP ZD,KIRSCHNER DL.Quartz-calcite Oxygen Isotope Thermometry:a Calibration Based on Natural Isotopic Variations[J].Geochim Cosmochim Acta,1994,58:4 491-4 501. 被引量:1
  • 7张锦明,田嘉禾,周丹,陈英茂.快速自动化合成2-^(18)F-β-D-脱氧葡萄糖[J].中华核医学杂志,2003,23(1):52-54. 被引量:18
  • 8杨绮琴 ... ..应用电化学[M],2001.
  • 9Ivanchuk OM,Goryanna VG,Rozenkevich MB.Isotopic Effects of Hydrogen During the Decomposition of Water in Electrolysis With a Solid Polymer Electrolyte[J].Atomic Energy,2000,89:745-749. 被引量:1
  • 10张小康主编..化学分析基本操作[M].北京:化学工业出版社,2006:229.

二级参考文献34

  • 1罗祎青,袁希钢,刘春江.氢同位素的低温精馏分离及模拟技术[J].化学工程,2004,32(5):10-14. 被引量:7
  • 2李桂花,郑彦巍.红外光谱法测定中等浓度重水[J].同位素,1993,6(3):168-171. 被引量:7
  • 3郑彦巍,李桂花.密度计法测定重水浓度[J].同位素,1994,7(1):43-46. 被引量:5
  • 4江骥,焦颖,李晓明,胡玉芳,杨则宜,王世真.人总体水的GC/MS法测定[J].同位素,1995,8(1):6-11. 被引量:1
  • 5Dugan J P,Borthwick J,Russell S,et al.Guanidine Hydrochloride Method for Determination of Water Oxygen Isotope Ratios and the Oxygen-18 Fractionation Between Carbon Dioxide and Water at 25.Degree C[J].Anal Chem,1985,57(8): 1 734-1 736. 被引量:1
  • 6Brown GR.Review of Analytical Methods Used at AEE (Atomic Energy Establishment) Winfrith for Determination of the Isotopic Purity of Heavy Water[R].Winfrith (England): Atomic Energy Establishment,1984.1-28. 被引量:1
  • 7周锡煌 姚明武.气相色谱法测定重水标样的氘含量[A]..第七届稳定同位素学术成果交流会论文集[C].北京:,1990.1-9. 被引量:1
  • 8L(A) SSER R,BELL A C,BAINBRIDGE N,et al.The preparative gas chromatographic system for the JET Active Gas Handling System-tritium commissioning and use during and after DTE1[J].Fusion Engineering and Design,1999,47(2 -3):301 -319. 被引量:1
  • 9FUKADA S,FUJIWARA H.Comparison of chromatographic methods for hydrogen isotope separation by Pd beds[J].Chromatography A,2000,898(1):125-131. 被引量:1
  • 10WATANABE K,MATSUYAMA M,KOBAYASHI T,et al.Gas chromatographic separation of H2-D2 mixtures by Pd-Pt alloy near room temperature[J].Alloys and Compounds,1997,257:278-284. 被引量:1

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