摘要
联苯二甲酸类化合物是很好的刚性桥联配体,可用于制备纳米多孔材料.设计了一条制备联苯二甲酸类新配体的合成路线,以4-氨基水杨酸为原料,经过4步反应最终合成了新配体3,3′-二羟基-4,4′-联苯二甲酸,并通过红外光谱、核磁共振氢谱和元素分析进行了表征.
Substituted 4,4＇- biphenyldicarboxylate compound is a kind of good rigid bridge-linking ligand which can be used to make nano-porous materials. A rational synthesis route has been designed in order to make the substituted 4,4＇- biphenyldicarboxylate derivatives. A novel ligand, 3,3＇- dihydroxy -4,4＇- biphenyl dicarboxylic acid （ H2dbdc）, has been synthesized successfully by the four-step reactions from 4 - amidosalicylic acid and characterized by the FT-IR,^1H NMR spectra and elemental analysis.
出处
《南京工业大学学报（自然科学版）》
CAS
2007年第1期16-18,35,共4页
Journal of Nanjing Tech University(Natural Science Edition)
基金
江苏省高校自然科学研究计划基金资助项目(05KJB150045)
关键词
配体合成
表征
3
3'-二羟基-4
4'-联苯二甲酸
ligand synthesis
characterization
3,3 ＇- dihydroxy - 4,4＇- biphenyldicarboxylic acid （ H2 dbdc）
