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Synthesis and Characterization of Tungsten Doped Vanadium Dioxide Nanopowders by Thermolysis 被引量:3

Synthesis and Characterization of Tungsten Doped Vanadium Dioxide Nanopowders by Thermolysis
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摘要 As far as we known, with white powdery tungstic acid (WPTA) used as the dopant for the first time, tungsten-doped vanadium dioxide (VO2) nanopowders were synthesized through thermolysis at low temperature. The products were characterized by XRD, TEM and DSC. When WPTA was added into V205 (with W/V = 2 atom %), the phase transition temperature (Tc) of VO2 decreased markedly from 67.15℃ to 26.46℃ after annealing at 500℃. Such a low Tc is beneficial to the application and development of smart windows materials. As far as we known, with white powdery tungstic acid (WPTA) used as the dopant for the first time, tungsten-doped vanadium dioxide (VO2) nanopowders were synthesized through thermolysis at low temperature. The products were characterized by XRD, TEM and DSC. When WPTA was added into V205 (with W/V = 2 atom %), the phase transition temperature (Tc) of VO2 decreased markedly from 67.15℃ to 26.46℃ after annealing at 500℃. Such a low Tc is beneficial to the application and development of smart windows materials.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第10期1417-1420,共4页 中国化学快报(英文版)
关键词 Vanadium dioxide white powdery tungstic acid phase transition THERMOLYSIS Vanadium dioxide, white powdery tungstic acid, phase transition, thermolysis
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  • 1Chenmou Zheng,Jieli Zhang,Guobin Luo,Jianqing Ye,Mingmei Wu.Preparation of vanadium dioxide powders by thermolysis of a precursor at low temperature[J].Journal of Materials Science.2000(13) 被引量:1
  • 2S DEKI,Y AOI,A KAJINAMI.A novel wet process for the preparation of vanadium dioxide thin film[J].Journal of Materials Science.1997(16) 被引量:1

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