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聚脲甲醛包覆双环戊二烯微胶囊的热稳定性研究 被引量:5

RESEARCH ON THERMAL STABILITY OF DICYCLPENTADIENE MICROCAPSULES COATED WITH POLY(UREA-FORMALDEHYDE)
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摘要 采用原位聚合法,以聚脲甲醛为壁材、以双环戊二烯(DCPD)为囊芯合成聚脲甲醛包覆DCPD微胶囊。采用傅立叶变换红外光谱对其化学结构进行表征,利用热失重分析法和差示扫描量热法表征微胶囊的热稳定性。研究结果表明,聚脲甲醛包覆DCPD微胶囊在温度低于50℃时具有很好的热稳定性并能保持微胶囊的完整性,适合于制备低温或室温成型自修复复合材料。 Dicyclpentadiene(DCPD) microcapsules coated with poly (urea-formaldehyde) were prepared by in-situ polymerization technology. The chemical structures and the thermal stability of microcapsules were analyzed by using Fourier-transform infrared spoetroseopy(FTIR), thermogravimetrie analysis(TGA) and differential scanning calorimetry(DSC) respectively. The results indicated that the microeapsules had good stability and kept intaetstate when the temperature was below 50℃. They were qualified for preparing serf-healing composites fabricated at low or room temperature.
出处 《工程塑料应用》 CAS CSCD 北大核心 2006年第3期48-50,共3页 Engineering Plastics Application
关键词 聚脲甲醛 双环戊二烯 微胶囊 热稳定性 自修复 poly ( urea-formaldehyde), dicyclopentadiene, microcapsules, thermal stability, self-healing
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  • 1White S R, Scottos N R, Geubelle P H, et al. Autonomic healing of polymer composites. Nature,2001,409:794. 被引量:1
  • 2Brown E N, Kessler M R, Sottos N R, et al. In situ poly( urea-formaldehyde) microencapsulation of dicyclopentadiene. J Microencapsu-lation, 2003, 20(6) :719. 被引量:1
  • 3Brown E N, Sottos N R , White S R. Fracture testing of a self-healing polymer composite. Experimental Mechanics, 2002, 42(4) :372. 被引量:1
  • 4Kessler M R, White S R. Self-activated healing of delamination damage in woven composites. Composites: Part A, 2003, 34 (8) :743. 被引量:1
  • 5Brown E N, White S R, Sottos N R. Microcapsule induced toughening in a self-healing polymer composite. J Mater Sci, 2004, 39( 5 ) :1703. 被引量:1
  • 6Camino G, Opetti L, Trossarelli L. Mcchanism of thermal degradation of urea-formaldehyde polycondensates. Polym Degrad Stab,1983, 5 (3) :161. 被引量:1

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