摘要
概述了原子转移自由基聚合(ATRP)的基本原理,同时介绍了有关引发剂、催化剂、反应条件、聚合方法等方面的研究进展;最新的研究成果表明,ATRP可以制备窄分子量分布聚合物、末端官能团聚合物、无规和梯度共聚物、嵌段共聚物、接技和梳状聚合物、星型及超支化聚合物等,具有非常广泛的应用前景。
The fundamental principle of atom transfer radical polymerization （ATRP） and the recent advances of these reaction in inititator, catalyst, reaction coddition as well as polymerize method were briefly introduced in this article. The recent research indicated that ATRP may be used in preparing polymers with narrow molecular weight distribution , polymers with end functional group, random and gradient copolymers, block copolymers, graft and comb shaped polymers, star and hyperbranched polymers. The applied prospects of ATRP will be great widespread.
出处
《长春理工大学学报（自然科学版）》
2005年第3期92-99,共8页
Journal of Changchun University of Science and Technology(Natural Science Edition)
基金
江苏省高校自然科学研究基金项目(05KJB430146)
关键词
原子转移自由基聚合
原理
进展
atom transfer radical polymerization
principle
advance
