摘要
报道了锰卟啉系列化合物被ＰｈＩＯ氧化开环的反应动力学和取代基效应对反应的影响规律．研究结果表明：单锰卟啉被ＰｈＩＯ氧化反应在动力学上为一级反应，且反应动力学常数ｋ与取代基特性常数σ之间存在线性关系．
This work reported the kinetic properties and substituent effects of theoxidations of monoporphinatomanganese(Ⅲ)compounds with PhIO. The resultsshowed that the oxidations were first order for monoporphinatomanganese(Ⅲ). Wefound that there was the linear relationship between the reaction kinetic constant k andthe substituent constant σ for monoporphinatomanganese(Ⅲ).
出处
《湖南大学学报（自然科学版）》
EI
CAS
CSCD
1995年第2期55-57,82,共4页
Journal of Hunan University:Natural Sciences
基金
国家自然科学基金
关键词
锰卟啉
取代基效应
反应动力学
porphinatomanganese , self-oxidation, kinetics, substituent effect
