摘要
开发了一种新的馏分油脱酸剂技术,完成了该技术的最佳实验室操作条件评选和工业试验研究。与馏分油碱洗脱酸工艺相比较,该技术具有适应原料范围宽,碱用量低,混合强度不影响脱酸效果,脱酸剂可再生循环使用,无废碱液排放等优点。在最优操作条件下精制油酸度小于7.0mgKOH/(100mL),回收石油酸达到石油酸一级品65号酸的质量标准(SH/T0530-92)。馏分油脱酸剂技术使用现有的馏分油碱洗电精制工艺设备,只需增加水洗和脱酸剂回收系统,技术改造费用少,具有良好的开发应用前景。
A new technology to remove naphthenic acid from distillates using a multi-functional complex agent was developed, optimum operation conditions were investigated, and a commercial trial was completed. As comparing with the conventional alkali treatment, said technology showed good adaptability for distillates with various acidity, less alkali consumption (reduced 67%~75%), better refined oil yield, and the acid removal was not affected by mixing intensity. Under optimum operation conditions the acidity of refined oil was below 7.0 mgKOH/100mL, and the quality of recovered acid met the 65# petroleum acid standard (SH/T 0530-92). Said technology could be applied in the existed alkali treating unit while adding a water washing system, and also a system to recover the complex agent was needed since said agent could be recycled after regeneration. No polluted waste alkali was discharged, and the revamping cost was low.
出处
《石油炼制与化工》
CAS
CSCD
北大核心
2005年第5期8-12,共5页
Petroleum Processing and Petrochemicals
