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ZnAl类水滑石吸附Cr(VI)性能研究 被引量:12

Studies on adsorption of Cr ( VI ) from aqueous solutions onto Zn/Al -layered double hydroxides
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摘要 对影响ZnAl-LDO吸附Cr(VI)性能的各因素(溶液pH值、温度、搅拌和沉降时间、初始Cr(VI)浓度、Zn/Al比)进行探讨,并考察了材料再生后的吸附性能.研究结果表明,控制溶液pH值是提高ZnAl-LDO吸附Cr(VI)性能的关键点;在最佳吸附条件下,Zn2Al-LDO对Cr(VI)的饱和吸附量高达73.83mg/g;吸附材料可再生,循环使用3次,吸附性能无明显变化. <Abstrcat> The performances of ZnAl-LDO for adsorption and desorption of hexavalent chromium was investigated. The influence of stir and subside time, solution pH, initial chromium concentration and temperature, the ratio Zn/Al has been tested. The results indicated that strictly controlling solution pH in the reaction was the key of enhanceing adsorption. Under the best adsorption conditions, the adsorption capacity of Zn_2Al-LDO reached 73.83 mg/g. Materials can reuse through desorption in the sodium carbonate solution,and the adsorption efficient had not changed markedly after three cycles.
出处 《浙江工业大学学报》 CAS 2005年第3期334-336,共3页 Journal of Zhejiang University of Technology
关键词 类水滑石 结构重组 六价铬 hydrotalcite-like compounds restructure chromium(VI)
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参考文献7

  • 1Cavani F, Trifiro F, Vaccari A. Hydrotalcite-type anionic clays: Preparation, properties and applications[J]. Catalysts Today, 1991,11 (2): 173-301. 被引量:1
  • 2You Youwen, Vance G F, Zhao Hongting. Selenium adsorption on Mg-Al and Zn-Al layered double hydroxides[J]. Applied Clay Science, 2001,20(1-2): 13-25. 被引量:1
  • 3Miyata S. Physico-chemical properties of synthetic hydrotalcites in relation to composition[J]. Clay Miner, 1980,28(1):50-56. 被引量:1
  • 4陈天虎 ,冯有亮 ,XU Hui-fang ,彭书传 ,黄川徽 ,唐述培 .层状双氢氧化物即时合成处理含Cr(Ⅵ)废水[J].环境科学,2004,25(2):89-93. 被引量:24
  • 5郑丽波,叶瑛,季珊珊,杨帅杰.Mg/Al型双金属氧化物对六价铬的吸附作用[J].地球化学,2004,33(2):208-214. 被引量:41
  • 6Das N N, Konar J, Mohanta M K, et al. Adsorption of Cr (Ⅵ) and Se(Ⅳ) from their aqueous solutions onto Zr^4+ -substituted ZnAl/MgAl-layered double hydroxides: effect of Zr4+ substitution in the layer[J]. Colloid Interface Science,2004,270(1) :1-8. 被引量:1
  • 7Lazaridis N K, Asouhidou D D. Kinetics of sorptive removal of chromium(Ⅵ) from aqueous solutions by calcined Mg-AlCO3 hydrotalcite[J]. Water Research, 2003, 37(12): 2 875-2 882. 被引量:1

二级参考文献55

  • 1[1]Cavani F,Trifiro F,Vaccari A.Hydrotalcite-type anionic clays:Preparation,properties and application [J].Catal Today,1991,11(2):173~301. 被引量:1
  • 2[2]Inacio J,Taviot-Gueho C,Forano C,et al.Adsorption of MCPA pesticide by MgAl-layered double hydroxides [J] .Appl Clay Sci,2001,18(5-6):255~264. 被引量:1
  • 3[3]You Youwen,Vance G F,Zhao Hongting.Selenium adsorption on Mg-Al and Zn-Al layered double hydroxides [J].Appl Clay Sci,2001,20(1-2):13~25. 被引量:1
  • 4[4]Allman R.The crystal structure of pyroaurite[J].Acta Crystal,1968,B(24):972~977. 被引量:1
  • 5[5]Rives V,Ulibarri M A.Layered double hydroxides (LDH)intercalated with metal coordination compounds and oxometalates[J].Coord Chem Rev,1999,181(1):61~120. 被引量:1
  • 6[6]Taylor H F W.Crystal structures of some double hydroxide minerals [J].Mineral Mag,1973,39(304):377~389. 被引量:1
  • 7[7]Miyata S.Anion exchange properties of hydrotalcite-like compounds[J].Clay Clay Miner,1983,31:305~311. 被引量:1
  • 8[8]Bish D L.Anion exchange in the pyroaurite group:Applications to other hydroxide minerals [J].Bull Mineral,1980,103:170~175. 被引量:1
  • 9[9]Meyn M,Beneke,Lagaly G.Anion-exchange reactions of layered double hydroxides [J].Inorg Chem,1990,29:5201 ~5207. 被引量:1
  • 10[10]Chatelet L,Bottero J Y,Yvon J,et al.Competition between monovalent and divalent anions for calcined and uncalcined hydrotalcite:Anion exchange and adsorption sites [J].Colloid Surf A,1996,111(3):167~175. 被引量:1

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