摘要
本文报导了三氯化铁(水合物)与4′-溴苯并-15-冠-5(L)固态配合物的合成,对合成的新配合物,进行了元素定量分析及摩尔电导测定,并作了红外光谱、紫外光谱,热重和差热以及X-射线粉末衍射分析的性质表征。从而证明,该配合物中FeCl_3与配体L比为1:1,是溶化剂,含有结晶水的固态配合物。
This paper reports the syntheses and properties of iron three halides with 4'-bromobenzo-15-crown-5-ether solid coordination compound. FeCl3 · L · 1/2 CH3CN · 2H2O synthesized is a new kind of crown ether coordination compound, in which FeCl3 :L is equal to 1:1. It is solvatcd and it contains two moles crystal water. It was identified by elemental analysis, TR,UV, TG, DTA, mole conductance and X-ray powder diffraction analysis.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1989年第1期115-118,共4页
Chinese Journal of Inorganic Chemistry
关键词
冠醚配合物
铁系元素
三氯化铁
iron series element coordination compound crown ether coordination compound
