摘要
合成和表征了两种新的冠醚Schiff碱锰(Ⅲ)和钴(Ⅱ)配合物,并对其催化膦酸二酯(BNPP)水解的动力学进行了研究。结果表明,这两种冠醚Schiff碱锰(Ⅲ)和钴(Ⅱ)
Two new Schiff base Mn (Ⅲ) and Co (Ⅱ) complexes containing were synthesized and characterized.The kinetics and the mechanism on BNPP hydrolysis catalyzed by two crown schiff base complexes were inwestigated.The catalytic activity of two new complexes were reported.and the mechanism ofcatalyuic BNPP hydrolysis were reported.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2005年第2期200-204,共5页
Chemical Research and Application
基金
四川省教育厅重点项目
重庆工学院科研启动项目
