摘要
本文叙述了合成甲醇反应机理的研究现状,指出在含铜催化剂上,甲醇合成是CO_2加氢的结果,同时伴随有CO水转化反应。其中间表面化合物的结构至今尚未弄清楚。参考文献53篇。
This review describes the present situation in the research of reactionmechanism of methanol synthesis. On the copper catalyst methanol results from carbondionde hydrogenation, which is simultaneously accon,panied by water-gas shifte reaction. So far the structure of intermediate surface compound has not been understood. 53references are presented.
出处
《合成化学》
CAS
CSCD
1994年第1期18-26,共9页
Chinese Journal of Synthetic Chemistry
关键词
甲醇
合成
反应机理
络合物
Methanol synthesis, Reaction mechanism, Intermediate complex, Adsorption replacement, Competitive adsorption.