摘要
A novel graft macromolecular coupling agent with well-defined structure was synthesized by atom transfer radical polymerization(ATRP). Since the silicon of graft polymers possesses a strong affinity to hydroxyl mineral, it gives fillers some new properties such as the increase of the interaction of fillers with matrix. The properties, structure of macromolecular coupling agent and its composite were studied by dynamic mechanical spectra, IR, UV, NMR, GPC and SEM.
A novel graft macromolecular coupling agent with well-defined structure was synthesized by atom transfer radical polymerization(ATRP). Since the silicon of graft polymers possesses a strong affinity to hydroxyl mineral, it gives fillers some new properties such as the increase of the interaction of fillers with matrix. The properties, structure of macromolecular coupling agent and its composite were studied by dynamic mechanical spectra, IR, UV, NMR, GPC and SEM.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2004年第12期2381-2383,共3页
Chemical Journal of Chinese Universities
关键词
原子转移自由基聚合
大分子偶联剂
阻尼性
相容性
Atom transfer radical polymerization(ATRP)
Macromolecular coupling agent
Damping
Compatibility