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用原子转移自由基方法合成新型大分子偶联剂 被引量:2

Synthesis of a Novel Macromolecular Coupling Agent from ATRP
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摘要 A novel graft macromolecular coupling agent with well-defined structure was synthesized by atom transfer radical polymerization(ATRP). Since the silicon of graft polymers possesses a strong affinity to hydroxyl mineral, it gives fillers some new properties such as the increase of the interaction of fillers with matrix. The properties, structure of macromolecular coupling agent and its composite were studied by dynamic mechanical spectra, IR, UV, NMR, GPC and SEM. A novel graft macromolecular coupling agent with well-defined structure was synthesized by atom transfer radical polymerization(ATRP). Since the silicon of graft polymers possesses a strong affinity to hydroxyl mineral, it gives fillers some new properties such as the increase of the interaction of fillers with matrix. The properties, structure of macromolecular coupling agent and its composite were studied by dynamic mechanical spectra, IR, UV, NMR, GPC and SEM.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2004年第12期2381-2383,共3页 Chemical Journal of Chinese Universities
关键词 原子转移自由基聚合 大分子偶联剂 阻尼性 相容性 Atom transfer radical polymerization(ATRP) Macromolecular coupling agent Damping Compatibility
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