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PAMAM树枝状高分子自组装膜的微摩擦性能研究 被引量:7

MICROTRIBOLOGICAL PROPERTY OF SELF-ASSEMBLY MULTILAYER FILMS BASED ON PAMAM DENDRIMERS
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摘要 H 2PtCl 6 was coordinated with the carboxyl-terminated G4.5PAMAM dendrimer molecules (PAMAMC) in aqueous solution,followed by reduction using NaBH 4 as reducer,and formed Pt-PAMAMC hybrid nano-particles.The stable multilayer films were obtained by fabricating diazo resin(DR) with these hybrid nanoparticles (Pt-PAMAMC) and PAMAMC,respectively.The films were subsequently irradiated under UV-light.It was found that the films from Pt-PAMAMC as polyanions exhibit stable frictional responses under the applied load,and the lubricative property of the films from Pt-PAMAMC hybrid nanoparticles is obviously superior to that of the films from dendrimer without platinum inside. H 2PtCl 6 was coordinated with the carboxyl-terminated G4.5PAMAM dendrimer molecules (PAMAMC) in aqueous solution,followed by reduction using NaBH 4 as reducer,and formed Pt-PAMAMC hybrid nano-particles.The stable multilayer films were obtained by fabricating diazo resin(DR) with these hybrid nanoparticles (Pt-PAMAMC) and PAMAMC,respectively.The films were subsequently irradiated under UV-light.It was found that the films from Pt-PAMAMC as polyanions exhibit stable frictional responses under the applied load,and the lubricative property of the films from Pt-PAMAMC hybrid nanoparticles is obviously superior to that of the films from dendrimer without platinum inside.
出处 《高分子学报》 SCIE CAS CSCD 北大核心 2004年第5期780-784,共5页 Acta Polymerica Sinica
基金 国家自然科学基金资助课题 (基金号 2 0 3 740 0 2 2 0 3 40 42 0 0 0 2)
关键词 PAMAM树枝状高分子自组装膜 微摩擦性能 重氮树脂 乙二胺 制备 云母片 PAMAM, Self-assembly, Microtribology, AFM/FFM
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