摘要
本文发现钼(Ⅱ)与鲁米诺可以发生化学发光反应,产生很强的发光信号,不稳定的钼(Ⅱ)可在流动注射体系中通过锌汞齐还原柱由钼(Ⅵ)产生。此反应能够用于痕量钼的测定。方法的线性范围是1×10^(-9)～4×10^(-7)g/ml钼,相对标准偏差小于2％(n=11)。此方法用于测定几种水样和钢样中的痕量钼,得到满意的结果。
The chemiluminescence reaction of the Mo(Ⅱ)-luminol system was examined by the flow injection system with the Jones reductor. A new method for the determination of Mo on the basis of this reaction was reported. The calibration curve was linear over the concentration range of 1×10 -9-4×10-7g/ml for Mo and the relative standard deviation of determination was less than 2% (n = 11). The method has been applied to the determination of Mo in water and steel samples.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
1993年第9期1000-1002,共3页
Chinese Journal of Analytical Chemistry
基金
国家自然科学基金
关键词
还原剂
鲁米诺
钼
化学发光分析
Reductant,Molybdenum,Luminol ,Chemiluminescence analysis.
