摘要
电致变色材料作为一种绿色环保、节能低碳的新型功能材料,可广泛应用于显示器件、智能窗、节能建筑、国防军事伪装等领域,得到了人们极大的关注。本文综合前人工作,总结了聚苯胺类电致变色材料的最新研究进展,详细介绍了苯胺和取代苯胺均聚物、苯胺和取代苯胺共聚物、聚苯胺衍生物基杂化材料和带有苯胺齐聚物侧链的变色材料的合成及研究现状,特别从材料的分子结构、溶解及变色性能出发,指出了目前聚苯胺类变色材料所存在的问题,并展望了未来改进的方向。
Electrochromic materials as a kind of new functional materials of green environmental protection,energy saving and low carbon,can be widely used in multitudinous fields as display devices,smart windows,energy-efficient buildings,national defensive military camouflage etc,attract people's great attentions.This paper presents a review of the latest research progress of electrochromic materials based on polyaniline.It introduces in detail the synthesis and current research of aniline and substituted aniline homopolymer,aniline and substituted aniline copolymer,hybrid materials based on polyaniline derivatives and electrochromic materials with oligoaniline side chains.Especially from the molecular structure,dissolution and electrochromic properties,the authors point out the existing problems of the current electrochromic materials based on polyaniline,give the future directions for improvement.
出处
《高分子通报》
CAS
CSCD
北大核心
2015年第6期10-18,共9页
Polymer Bulletin
基金
陕西省教育厅自然科学专项(2013JK0653)
国家自然科学基金项目(51303147)
中国博士后科学基金项目(2014M562588)资助
关键词
聚苯胺
电致变色
杂化材料
齐聚物
Polyaniline
Electrochromism
Hybrid materials
Oligomer
