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Molecular Cloning of a Glycyrrhiza uralensis F.Aquaporin GuPIP1 Up-regulated in Response to Drought,Salt and ABA Stress 被引量:8
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作者 WANG Fang JIANG Yong +7 位作者 FENG Xue-chao XU Li-na LI Ming-tang LIANG Hai-tao LI Yong-ming ZHU Na LIU Yan-li MA Tong-hui 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2007年第1期52-57,共6页
A PCR-bosed homologous cloning strategy was used to identify aquaporin genes from the roots of Chinese licorice ( Glycyrrhiza uralertsis F. ). A 1236 bp cDNA with 870 bp open reading frame encoding a 290 amino acids... A PCR-bosed homologous cloning strategy was used to identify aquaporin genes from the roots of Chinese licorice ( Glycyrrhiza uralertsis F. ). A 1236 bp cDNA with 870 bp open reading frame encoding a 290 amino acids aquaporin ortholog, GuPIP1, was successfully cloned and characterized. The deduced GuPIP1 protein contains six putative transmembrane domains; two conserved NPA motifs as well as the MIP and PIP family signature sequences. A rabbit polyelonal antibody against N-terminal peptide of GuPIP1 corresponded to a 31 kDa GuPIP1 protein on Western blot of plasma membrane preparation of root tissue. RT-PCR and Western blot analysis indicated the expression of GuPIP1 in the root, leaf, and stem tissues. Thus far, GuPIP1 is the first Glycyrrhiza uralensis F. aquaporin that has been identified at a molecular level. Quantitative real-time PCR analysis showed that the expression of GuPIP1 was up-regulated in response to drought, ABA, and salt stress. 展开更多
关键词 AQUAPORIN CLONING Gtyeyrrhiza uralensis F. PIP C.ene regulation
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A Covert Communication Method Using Special Bitcoin Addresses Generated by Vanitygen 被引量:7
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作者 Lejun Zhang Zhijie Zhang +4 位作者 Weizheng Wang Rasheed Waqas Chunhui Zhao Seokhoon Kim Huiling Chen 《Computers, Materials & Continua》 SCIE EI 2020年第10期597-616,共20页
As an extension of the traditional encryption technology,information hiding has been increasingly used in the fields of communication and network media,and the covert communication technology has gradually developed.T... As an extension of the traditional encryption technology,information hiding has been increasingly used in the fields of communication and network media,and the covert communication technology has gradually developed.The blockchain technology that has emerged in recent years has the characteristics of decentralization and tamper resistance,which can effectively alleviate the disadvantages and problems of traditional covert communication.However,its combination with covert communication thus far has been mostly at the theoretical level.The BLOCCE method,as an early result of the combination of blockchain and covert communication technology,has the problems of low information embedding efficiency,the use of too many Bitcoin addresses,low communication efficiency,and high costs.The present research improved on this method,designed the V-BLOCCE which uses base58 to encrypt the plaintext and reuses the addresses generated by Vanitygen multiple times to embed information.This greatly improves the efficiency of information embedding and decreases the number of Bitcoin addresses used.Under the premise of ensuring the order,the Bitcoin transaction OP_RETURN field is used to store the information required to restore the plaintext and the transactions are issued at the same time to improve the information transmission efficiency.Thus,a more efficient and feasible method for the application of covert communication on the blockchain is proposed.In addition,this paper also provides a more feasible scheme and theoretical support for covert communication in blockchain. 展开更多
关键词 Covert communication blockchain Bitcoin address
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Highly efficient nanoporous CoBP electrocatalyst for hydrogen evolution reaction 被引量:7
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作者 Hui-Lan Guang Sheng-Li Zhu +5 位作者 Yan-Qin Liang Shui-Lin Wu Zhao-Yang Li Shui-Yuan Luo Zhen-Duo Cui Akihisa Inoue 《Rare Metals》 SCIE EI CAS CSCD 2021年第5期1031-1039,共9页
Water splitting is an environment friendly and efficient way to produce hydrogen.Highly efficient and low-cost non-noble metal catalysts play an important role in hydrogen evolution reaction(HER).Dealloying is a simpl... Water splitting is an environment friendly and efficient way to produce hydrogen.Highly efficient and low-cost non-noble metal catalysts play an important role in hydrogen evolution reaction(HER).Dealloying is a simple method to prepare three-dimensional self-supporting nanoporous materials without conductive supports and binders.In this work,we prepared self-supporting nanoporous CoBP electrocatalyst by dealloying method.The influence of the synergistic effect of nonmetallic elements on catalytic activity was investigated.The synergistic electronic effect of Co,B and P atoms on the surface optimizes the H atoms desorption and results in superior HER activity.The bi-continuous structure of nanoporous CoBP provides more active area and favors of electron and electrolyte transfer.The nanoporous CoBP with the B/P atomic ratio of 1/3 exhibits low overpotential of 42 mV at 10 mA·cm^(-2),small Tafel slope of 39.8 mV·dec-1 and good long-term stability with no performance decrease for 20 h in alkaline solution. 展开更多
关键词 Hydrogen evolution reaction NANOPOROUS Self-supporting electrocatalyst Co-B-P alloy DEALLOYING
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On the Cauchy Problem of Evolution p-Laplacian Equation with Nonlinear Gradient Term 被引量:7
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作者 Mingyu CHEN Junning ZHAO 《Chinese Annals of Mathematics,Series B》 SCIE CSCD 2009年第1期1-16,共16页
The authors study the existence of solution to p-Laplacian equation with nonlinear forcing term under optimal assumptions on the initial data, which are assumed to be measures. The existence of local solution is obtai... The authors study the existence of solution to p-Laplacian equation with nonlinear forcing term under optimal assumptions on the initial data, which are assumed to be measures. The existence of local solution is obtained. 展开更多
关键词 p-Laplacian equation Nonlinear gradient term Measures initial data Local solution
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Carbon dots enhanced gelatin/chitosan bio-nanocomposite packaging film for perishable foods 被引量:4
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作者 Bofei Fu Qiaoling Liu +7 位作者 Minghuan Liu Xiaofang Chen Hetong Lin Zongping Zheng Junqiu Zhu Congjie Dai Xiaochen Dong Da-Peng Yang 《Chinese Chemical Letters》 SCIE CAS CSCD 2022年第10期4577-4582,共6页
Carbon dots(CDs)with intriguing fluorescent property,good biocompatibility,high stability,easy interaction with substrates,are burgeoning carbon nanoparticles with large potential in various applications.Incorporating... Carbon dots(CDs)with intriguing fluorescent property,good biocompatibility,high stability,easy interaction with substrates,are burgeoning carbon nanoparticles with large potential in various applications.Incorporating CDs into the polymer matrix is becoming a popular strategy to endow the complex with new functions.Herein,the green-synthesized CDs was integrated into the mixture of gelatin(derived from waste fish scale)and chitosan,and a multifunctional bio-nanocomposite(defined as Gelatin/Chitosan/CDs)film was developed,which showed the excellent antibacterial,antioxidant,pH-sensitivity,UV shielding,and blue-emission properties.The effects of different concentrations of CDs on the physical,mechanical,structural,and functional activity of bio-nanocomposite film were tested.Compared with the Gelatin/Chitosan film,the Gelatin/Chitosan/CDs film with an optimum addition of 20%CDs showed the enhanced antibacterial,antioxidant as well as UV shielding activities.More importantly,it was used as an effective packaging material for fish meat preservation,reducing the loss of nutritional quality consumption,extending the shelf life of food.Besides,the bio-nanocomposite films also possessed the anti-counterfeiting and pH-responsive properties due to the strong fluorescent emission of CDs,and had the great potential in developing the intelligent packaging materials.Our work shed new light on the new application of CDs and the synthesis of bio-nanocomposite film in food industry. 展开更多
关键词 Carbon dots Bio-nanocomposite GELATIN UV shielding Intelligent packaging
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Secure and Efficient Data Storage and Sharing Scheme Based on Double Blockchain 被引量:5
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作者 Lejun Zhang Minghui Peng +3 位作者 Weizheng Wang Yansen Su Shuna Cui Seokhoon Kim 《Computers, Materials & Continua》 SCIE EI 2021年第1期499-515,共17页
In the digital era,electronic medical record(EMR)has been a major way for hospitals to store patients’medical data.The traditional centralized medical system and semi-trusted cloud storage are difficult to achieve dy... In the digital era,electronic medical record(EMR)has been a major way for hospitals to store patients’medical data.The traditional centralized medical system and semi-trusted cloud storage are difficult to achieve dynamic balance between privacy protection and data sharing.The storage capacity of blockchain is limited and single blockchain schemes have poor scalability and low throughput.To address these issues,we propose a secure and efficient medical data storage and sharing scheme based on double blockchain.In our scheme,we encrypt the original EMR and store it in the cloud.The storage blockchain stores the index of the complete EMR,and the shared blockchain stores the index of the shared part of the EMR.Users with different attributes can make requests to different blockchains to share different parts according to their own permissions.Through experiments,it was found that cloud storage combined with blockchain not only solved the problem of limited storage capacity of blockchain,but also greatly reduced the risk of leakage of the original EMR.Content Extraction Signature(CES)combined with the double blockchain technology realized the separation of the privacy part and the shared part of the original EMR.The symmetric encryption technology combined with Ciphertext-Policy Attribute-Based Encryption(CP–ABE)not only ensures the safe storage of data in the cloud,but also achieves the consistency and convenience of data update,avoiding redundant backup of data.Safety analysis and performance analysis verified the feasibility and effectiveness of our scheme. 展开更多
关键词 Cloud storage blockchain electronic medical records access control data sharing PRIVACY
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ThyroidNet:A Deep Learning Network for Localization and Classification of Thyroid Nodules
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作者 Lu Chen Huaqiang Chen +6 位作者 Zhikai Pan Sheng Xu Guangsheng Lai Shuwen Chen Shuihua Wang Xiaodong Gu Yudong Zhang 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第4期361-382,共22页
Aim:This study aims to establish an artificial intelligence model,ThyroidNet,to diagnose thyroid nodules using deep learning techniques accurately.Methods:A novel method,ThyroidNet,is introduced and evaluated based on... Aim:This study aims to establish an artificial intelligence model,ThyroidNet,to diagnose thyroid nodules using deep learning techniques accurately.Methods:A novel method,ThyroidNet,is introduced and evaluated based on deep learning for the localization and classification of thyroid nodules.First,we propose the multitask TransUnet,which combines the TransUnet encoder and decoder with multitask learning.Second,we propose the DualLoss function,tailored to the thyroid nodule localization and classification tasks.It balances the learning of the localization and classification tasks to help improve the model’s generalization ability.Third,we introduce strategies for augmenting the data.Finally,we submit a novel deep learning model,ThyroidNet,to accurately detect thyroid nodules.Results:ThyroidNet was evaluated on private datasets and was comparable to other existing methods,including U-Net and TransUnet.Experimental results show that ThyroidNet outperformed these methods in localizing and classifying thyroid nodules.It achieved improved accuracy of 3.9%and 1.5%,respectively.Conclusion:ThyroidNet significantly improves the clinical diagnosis of thyroid nodules and supports medical image analysis tasks.Future research directions include optimization of the model structure,expansion of the dataset size,reduction of computational complexity and memory requirements,and exploration of additional applications of ThyroidNet in medical image analysis. 展开更多
关键词 ThyroidNet deep learning TransUnet multitask learning medical image analysis
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Multi-functional metasurface:ultra-wideband/multi-band absorption switching by adjusting guided-mode resonance and local surface plasmon resonance effects 被引量:1
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作者 Wenxin Li Shubo Cheng +6 位作者 Huafeng Zhang Zao Yi Bin Tang Can Ma Pinghui Wu Qingdong Zeng Rizwan Raza 《Communications in Theoretical Physics》 SCIE CAS CSCD 2024年第6期174-184,共11页
This study introduces an innovative dual-tunable absorption film with the capability to switch between ultra-wideband and narrowband absorption.By manipulating the temperature,the film can achieve multi-band absorptio... This study introduces an innovative dual-tunable absorption film with the capability to switch between ultra-wideband and narrowband absorption.By manipulating the temperature,the film can achieve multi-band absorption within the 30-45 THz range or ultra-wideband absorption spanning 30-130 THz,with an absorption rate exceeding 0.9.Furthermore,the structural parameters of the absorption film are optimized using the particle swarm optimization(PSO)algorithm to ensure the optimal absorption response.The absorption response of the film is primarily attributed to the coupling of guided-mode resonance and local surface plasmon resonance effects.The film's symmetric structure enables polarization incoherence and allows for tuning through various means such as doping/voltage,temperature and structural parameters.In the case of a multi-band absorption response,the film exhibits good sensitivity to refractive index changes in multiple absorption modes.Additionally,the absorption spectrum of the film remains effective even at large incidence angles,making it highly promising for applications in fields such as biosensing and infrared stealth. 展开更多
关键词 PSO optimization ultra-wideband/narrowband absorption switching intelligent absorption film vanadium dioxide
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Redundant Data Detection and Deletion to Meet Privacy Protection Requirements in Blockchain-Based Edge Computing Environment
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作者 Zhang Lejun Peng Minghui +6 位作者 Su Shen Wang Weizheng Jin Zilong Su Yansen Chen Huiling Guo Ran Sergey Gataullin 《China Communications》 SCIE CSCD 2024年第3期149-159,共11页
With the rapid development of information technology,IoT devices play a huge role in physiological health data detection.The exponential growth of medical data requires us to reasonably allocate storage space for clou... With the rapid development of information technology,IoT devices play a huge role in physiological health data detection.The exponential growth of medical data requires us to reasonably allocate storage space for cloud servers and edge nodes.The storage capacity of edge nodes close to users is limited.We should store hotspot data in edge nodes as much as possible,so as to ensure response timeliness and access hit rate;However,the current scheme cannot guarantee that every sub-message in a complete data stored by the edge node meets the requirements of hot data;How to complete the detection and deletion of redundant data in edge nodes under the premise of protecting user privacy and data dynamic integrity has become a challenging problem.Our paper proposes a redundant data detection method that meets the privacy protection requirements.By scanning the cipher text,it is determined whether each sub-message of the data in the edge node meets the requirements of the hot data.It has the same effect as zero-knowledge proof,and it will not reveal the privacy of users.In addition,for redundant sub-data that does not meet the requirements of hot data,our paper proposes a redundant data deletion scheme that meets the dynamic integrity of the data.We use Content Extraction Signature(CES)to generate the remaining hot data signature after the redundant data is deleted.The feasibility of the scheme is proved through safety analysis and efficiency analysis. 展开更多
关键词 blockchain data integrity edge computing privacy protection redundant data
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Matching Dyeing and Properties of Silk Fabrics with Natural Edible Pigments
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作者 CHEN Yangyi ZHOU Shihang +4 位作者 SU Tong LI Jingzhi CHEN Hongshan QI Huan QIU Yiping 《Journal of Donghua University(English Edition)》 CAS 2024年第4期428-435,共8页
The silk fabrics were matching dyed with three natural edible pigments(red rice red,ginger yellow and gardenia blue).By investigating the dyeing rates and lifting properties of these pigments,it was observed that thei... The silk fabrics were matching dyed with three natural edible pigments(red rice red,ginger yellow and gardenia blue).By investigating the dyeing rates and lifting properties of these pigments,it was observed that their compatibilities were excellent in the dyeing process:dye dosage 2.5%(omf),mordant alum dosage 2.0%(omf),dyeing temperature 80℃and dyeing time 40 min.The silk fabrics dyed with secondary colors exhibited vibrant and vivid color owing to the remarkable lightness and chroma of ginger yellow.However,gardenia blue exhibited multiple absorption peaks in the visible light range,resulting in significantly lower lightness and chroma for the silk fabrics dyed with tertiary colors,thus making it suitable only for matte-colored fabrics with low chroma levels.In addition,the silk fabrics dyed with these three pigments had a color fastness that exceeded grade 3 in resistance to perspiration,soap washing and light exposure,indicating acceptable wearing properties.The dyeing process described in this research exhibited a wide range of potential applications in matching dyeing of protein-based textiles with natural colorants. 展开更多
关键词 matching dyeing silk fabric natural edible pigment secondary color tertiary color
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Progress on fiber engineering for fabric innovation in ecological hydrophobic design and multifunctional applications
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作者 Wei Li Libing Yang +8 位作者 Jianying Huang Chan Zheng Yu Chen Yunbo Li Dapeng Yang Shuhui Li Zhong Chen Weilong Cai Yuekun Lai 《Industrial Chemistry & Materials》 2024年第3期393-423,共31页
The application of fluorinated coatings on textiles has garnered substantial research interest over the past years,owing to their ability to endow fabrics with exceptional hydrophobic characteristics,thereby mitigatin... The application of fluorinated coatings on textiles has garnered substantial research interest over the past years,owing to their ability to endow fabrics with exceptional hydrophobic characteristics,thereby mitigating issues associated with high moisture absorption and susceptibility to contamination.Nevertheless,the deployment of fluorinated substances has been proscribed due to concerns regarding their ecological impact and potential human toxicity.Consequently,there has been a burgeoning demand for hydrophobic textile alternatives derived from non-fluorinated,natural materials that are both sustainable and environmentally benign.This paper presents a thorough overview of the advancements in the development and functionalization of eco-friendly,hydrophobic textiles.Initially,the natural materials and their derivatives utilized in the creation of superhydrophobic textiles are delineated,including cellulose,lignin and chitosan,among others.Subsequently,methodologies for crafting efficient,stable,and resilient hydrophobic textiles are elucidated,encompassing conventional techniques as well as novel,inventive concepts.Furthermore,the current state of research and the obstacles faced in the evolution of multifunctional textiles based on superhydrophobic fabrics are examined.In conclusion,this discussion presents incisive insights into the impending direction of advancements in functional textiles. 展开更多
关键词 ECO-FRIENDLY SUPERHYDROPHOBIC BIOINSPIRED Multifunctional textiles Natural materials
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3D flower-like heterostructured TiO_2@Ni(OH)_2 microspheres for solar photocatalytic hydrogen production 被引量:5
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作者 Wei Zhang Hongwen Zhang +2 位作者 Jianzhong Xu Huaqiang Zhuang Jinlin Long 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第3期320-325,共6页
TiO2@Ni(OH)2 core-shell microspheres were synthesized by a facile strategy to obtain a perfect 3D flower-like nanostructure with well-arranged Ni(OH)2 nanoflakes on the surfaces of TiO2 microspheres;this arrangement l... TiO2@Ni(OH)2 core-shell microspheres were synthesized by a facile strategy to obtain a perfect 3D flower-like nanostructure with well-arranged Ni(OH)2 nanoflakes on the surfaces of TiO2 microspheres;this arrangement led to a six-fold enhancement in photocatalytic hydrogen evolution. The unique p-n type heterostructure not only promotes the separation and transfer of photogenerated charge carriers significantly, but also offers more active sites for photocatalytic hydrogen production. A photocatalytic mechanism is proposed based on the results of electrochemical measurements and X-ray photoelectron spectroscopy. 展开更多
关键词 3D flower-like core-shell microspheres TiO2 NI(OH)2 Photocatalytic hydrogen production
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Effects of TAT-SOD at Acupoints on Essential Hypertension by Monitoring Meridians Electrical Potential 被引量:4
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作者 GUO Jing-ke XU Jin-sen +7 位作者 CHEN Tian-bao XU Ming-ming LIU Shu-tao ZHANG Chao-xin KE Li-jing ZHOU Jian-wu WANG Qiang RAO Ping-fan 《Chinese Journal of Integrative Medicine》 SCIE CAS CSCD 2020年第9期694-700,共7页
Objectives:To investigate the effect on essential hypertension of the topical application of TAT-Cu,Zn-superoxide dismutase(TAT-SOD)at left acupoint Zusanli(ST 36),and to observe whether the change of electrical poten... Objectives:To investigate the effect on essential hypertension of the topical application of TAT-Cu,Zn-superoxide dismutase(TAT-SOD)at left acupoint Zusanli(ST 36),and to observe whether the change of electrical potential difference(EPD)can be related to the change of blood pressure.Methods:Sixteen patients with essential hypertension and 16 healthy subjects were included in the study.EPD between the left acupoints of Yanglingquan(GB 34)and Qiuxu(GB 40)was firstly screened out for the EPD detection.An intracellular superoxide quenching enzyme,TAT-SOD,was topically applied to the acupoint ST 36 within an area of 1 cm^2 once a day,and the influence on EPD was investigated.The dosage applied to TAT-SOD group(n=8)was 0.2 mL of 3000 U/mL TAT-SOD cream prepared by adding purified TAT-SOD to a vehicle cream,while placebo group(n=8)used the vehicle cream instead.The left acupoints of Yanglingquan(GB 34)and Qiuxu(GB 40)were selected for EPD measurement after comparing EPD readings between 5 acupoints on each of all 12 meridians.Results:EPDs between the left acupoints of GB 34 and GB 40 for 16 patients of essential hypertension and 16 healthy subjects were 44.9±6.4 and 5.6±0.9 mV,respectively.Daily application of TAT-SOD for 15 days at ST 36 of essential hypertension patients significantly decreased systolic blood pressure(SBP)and diastolic blood pressure(DBP)of 179.6 and 81.5 mm Hg to 153.1 and 74.1 mm Hg,respectively.Responding to the change in blood pressure,EPD between the left acupoints of GB 34 and GB 40 also declined from 44.4 to 22.8 mV with the same trend.No change was observed with SBP,DBP and EPD between the left acupoints of GB 34 and GB 40 with the daily application of the placebo cream.Conclusion:Enzymatic scavenging of the intracellular superoxide at ST 36 proved to be effective in decreasing SBP and DBP.The results reconfirm the involvement of superoxide anions and its transportation along the meridians,and demonstrate that EPD between acupoints may be an indicator to reflect its functioning status.Moreov 展开更多
关键词 TAT-SOD reactive oxygen species electrical potential essential hypertension ACUPOINTS
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Synthesis, characterization, and catalytic performance of hierarchical ZSM-11 zeolite synthesized via dual-template route 被引量:5
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作者 Hui Liu Shuang Zhang +4 位作者 Sujuan Xie Wanshuo Zhang Wenjie Xin Shenglin Liu Longya Xu 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第1期167-180,共14页
Hierarchical zeolite materials were prepared via one‐pot synthesis of ZSM‐11zeolites with different molar ratios(R)of a mesoporogen,i.e.,cetyltrimethylammonium bromide template(CTAB),to a microporogen,i.e.,tetra‐n... Hierarchical zeolite materials were prepared via one‐pot synthesis of ZSM‐11zeolites with different molar ratios(R)of a mesoporogen,i.e.,cetyltrimethylammonium bromide template(CTAB),to a microporogen,i.e.,tetra‐n‐butylammonium bromide(TBABr).The structures,morphologies,and textural properties of the resultant materials were investigated.Initially,with increasing R,the crystal size of the synthesized product decreased,the number of intercrystalline mesopores increased,and a pure ZSM‐11zeolite phase was present.Then an MCM‐41‐like phase was produced and embedded in the ZSM‐11zeolite phase.Finally,an MCM‐41‐like phase was obtained.The alkalinity had important effects on the physicochemical and textural properties of the prepared samples.A possible mechanism of formation of the hierarchical ZSM‐11zeolite was proposed on the basis of a combination of various characterization results.The role of CTAB varied depending on the R value,and it showed a capping effect,micellar effect,and template effect.These effects of CTAB were synergetic in ZSM‐11synthesis,but they were competitive with the structure‐directing effect of TBABr.In addition,the impact of the acidic properties and porosities of the hierarchical ZSM‐11catalysts on their performances in the alkylation of benzene with dimethyl ether was investigated.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved. 展开更多
关键词 Hierarchical material ZSM‐11 Dual‐template Cetyltrimethylammonium bromide Alkylation of benzene
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Self-supporting amorphous nanoporous NiFeCoP electrocatalyst for efficient overall water splitting 被引量:4
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作者 Yao Pang Wence Xu +6 位作者 Shengli Zhu Zhenduo Cui Yanqin Liang Zhaoyang Li Shuilin Wu Chuntao Chang Shuiyuan Luo 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2021年第23期96-104,共9页
The design of cost-effective and earth-abundant bifunctional electrocatalysts for highly efficient oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)is important for water splitting as an advanced rene... The design of cost-effective and earth-abundant bifunctional electrocatalysts for highly efficient oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)is important for water splitting as an advanced renewable energy transformation system.In this work,the self-supporting amorphous Ni Fe Co P catalyst with nanoporous structure via a facile electrochemical dealloying method is reported.Benefiting from the bicontinuous nanostructure,disordered atomic arrangement,abundant active sites and synergic effect of various transition metals,the as-prepared nanoporous NiFeCoP(np-NiFeCoP)catalyst exhibits good electrocatalytic activity,which achieves the current densities of 10 mA cm^(-2) at low overpotentials of 244 mV and 105 mV for OER and HER in 1.0 M KOH,respectively.In addition,the bifunctional electrocatalyst also shows outstanding and durable electrocatalytic activity in water splitting with a small voltage of 1.62 V to drive a current density of 10 mA cm^(-2) in a two-electrode electrolyzer system.The present work would provide a feasible strategy to explore the efficient and low-cost bifunctional electrocatalysts toward overall water splitting. 展开更多
关键词 DEALLOYING Amorphous NiFeCoP Water splitting Hydrogen evolution reaction Oxygen evolution reaction
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Cocktail effect of ionic patch driven by triboelectric nanogenerator for diabetic wound healing
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作者 Yixia Zhang Caili Xue +10 位作者 Yunpeng Zhang Qi Zhang Kai Zhang Yulin Liu Zhaohui Shan Wu Qiu Gang Chen Na Li Hulin Zhang Jiang Zhao Da-Peng Yang 《Chinese Chemical Letters》 SCIE CAS CSCD 2024年第8期460-465,共6页
There is increasing evidence shows that either electrical stimulation(ES)or metal ion is an effective way to accelerate ulcerative wound healing.However,less attention is paid to investigating the synergistic effect b... There is increasing evidence shows that either electrical stimulation(ES)or metal ion is an effective way to accelerate ulcerative wound healing.However,less attention is paid to investigating the synergistic effect between them.Herein,we explore the combined effects of ES and multiple metal ions on dia-betic wound healing assisted by a triboelectric nanogenerator(TENG).Firstly,the novel Eggshell@CuFe_(2)O_(4)nanocomposites(NCs)are prepared,which show unique structure and intrinsic antimicrobial properties.Subsequently,the as-prepared nanocomposites are embedded in oxidized starch hydrogel to form a mul-tifunctional composite gel,which is further assembled into a wearable ionic triboelectric nanogenerator(iTENG)patch with polydimethylsiloxane(PDMS).It can convert the mechanical energy produced by a human body motion to electric energy and mediate the sequential release of metal ions(Fe^(2+)/Ca^(2+)/Cu^(2+)),thereby resulting in the“cocktail effect”on impaired tissue.Under their effects,a satisfying healing re-sult in diabetic mouse is identified,which can effectively accelerate wound healing process by relieving inflammation,promoting angiogenesis and collagen deposition.The work puts forward the cocktail effect of electric simulation coupled with the multiple metal ions,and opens up a new perspective in designing iTENG patch towards repair of hard-to-heal wounds. 展开更多
关键词 iTENG Cocktail effect CuFe_(2)O_(4) EGGSHELL Diabetic wound
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A Novel Cable-Driven Soft Robot for Surgery
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作者 李茹 陈方 +3 位作者 俞文伟 IGARASH Tatsuo 舒雄鹏 谢叻 《Journal of Shanghai Jiaotong university(Science)》 EI 2024年第1期60-72,共13页
Robot-assisted laparoscopic radical prostatectomy(RARP)is widely used to treat prostate cancer.The rigid instruments primarily used in RARP cannot overcome the problem of blind areas in surgery and lead to more trauma... Robot-assisted laparoscopic radical prostatectomy(RARP)is widely used to treat prostate cancer.The rigid instruments primarily used in RARP cannot overcome the problem of blind areas in surgery and lead to more trauma such as more incision for the passage of the instrument and additional tissue damage caused by rigid instruments.Soft robots are relatively fexible and theoretically have infinite degrees of freedom which can overcome the problem of the rigid instrument.A soft robot system for single-port transvesical robot-assisted radical prostatectomy(STvRARP)is developed in this study.The soft manipulator with 10 mm in diameter and a maximum bending angle of 270°has good fexibility and dexterity.The design and mechanical structure of the soft robot are described.The kinematics of the soft manipulator is established and the inverse kinematics is compensated based on the characteristics of the designed soft manipulator.The master-slave control system of soft robot for surgery is built and the feasibility of the designed soft robot is verified. 展开更多
关键词 soft robot kinematics model robot-assisted surgery
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High accuracy non-equidistant method for singular perturbation reaction-diffusion problem 被引量:5
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作者 蔡新 蔡丹琳 +1 位作者 吴瑞潜 谢康和 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2009年第2期175-182,共8页
Singular perturbation reaction-diffusion problem with Dirichlet boundary condition is considered. It is a multi-scale problem. Presence of small parameter leads to boundary layer phenomena in both sides of the region.... Singular perturbation reaction-diffusion problem with Dirichlet boundary condition is considered. It is a multi-scale problem. Presence of small parameter leads to boundary layer phenomena in both sides of the region. A non-equidistant finite difference method is presented according to the property of boundary layer. The region is divided into an inner boundary layer region and an outer boundary layer region according to transition point of Shishkin. The steps sizes are equidistant in the outer boundary layer region. The step sizes are gradually increased in the inner boundary layer region such that half of the step sizes are different from each other. Truncation error is estimated. The proposed method is stable and uniformly convergent with the order higher than 2. Numerical results are given, which are in agreement with the theoretical result. 展开更多
关键词 singular perturbation REACTION-DIFFUSION uniform convergence high accuracy non-equidistant
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Conversion of Au(Ⅲ)-polluted waste eggshell into functional CaO/Au nanocatalyst for biodiesel production 被引量:3
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作者 Jiadi Liu Minghuan Liu +5 位作者 Shaoyun Chen Bingqing Wang Jin Chen Da-Peng Yang Shangzhou Zhang Wenxiao Du 《Green Energy & Environment》 SCIE EI CSCD 2022年第2期352-359,共8页
Developing an environmental-friendly and highly active catalyst in transesterification for biodiesel production is of great importance for a more economic biodisel process.Herein,we reported that waste eggshells were ... Developing an environmental-friendly and highly active catalyst in transesterification for biodiesel production is of great importance for a more economic biodisel process.Herein,we reported that waste eggshells were used to adsorb Au(Ⅲ) in water and convert the Au(Ⅲ)-polluted eggshells into the functional nanocatalyst-Ca O/Au for the transesterification reaction between soybean oil and methanol to the preparation of biodiesel.By coupling of Ca O and Au nanoparticles,Ca O/Au nanoparticles showed superior catalytic activity for the transesterification reaction between soybean oil and methanol.An optimum performance was observed over Ca O/Au nanocomposites in a methanol-oil molar ratio at 12:1with catalyst content of 1.0 wt% at 70°C for 3 h.Besides,the catalytic activity of Ca O/Au nanocatalyst was almost unchanged after recycling for 5 times and the yield of biodiesel still kept at 88.9%.The proof-of concept study provided us a sustainable method for utilization of waste eggshells to remedy the metal ions-polluted wastewater and the synthesis of functional nanocomposite for biodiesel production,show great potential application of waste eggshell in adsorption and catalytic reactions. 展开更多
关键词 process Au(Ⅲ) CATALYST
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Molecularly imprinted sensor based on carboxylated carbon nanotubes/Keggin-type polyoxometalates nanocomposite for the detection of furazolidone
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作者 Yu-Lan Huang Bing Zhang +3 位作者 Yu-Lian Li Li Wang Le Dong Jian Li 《Tungsten》 EI CSCD 2024年第2期394-409,共16页
Due to its properties of mutagenic,teratogenic,and carcinogenic,the detection of furazolidone(FZD)in aquaculture is of great importance for food safety and human health.In this study,molecularly imprinted fi lms modif... Due to its properties of mutagenic,teratogenic,and carcinogenic,the detection of furazolidone(FZD)in aquaculture is of great importance for food safety and human health.In this study,molecularly imprinted fi lms modifi ed with carboxylated multi-walled carbon nanotube-phosphomolybdic acid composite were used to fabricate an electrochemical sensor for the determination of FZD.The nanocomposites were characterized using infrared spectroscopy,scanning electron microscopy,energy-dispersive X-ray spectroscopy,and X-ray diff raction.The electrochemical characteristics of the modifi ed electrodes were examined using electrochemical impedance spectroscopy,cyclic voltammetry,and diff erential pulse voltammetry.The sensor exhibited exceptional catalytic performance.The calibration curves were acquired in the concentration range of 6 nmol·L^(−1)to 0.6μmol·L^(−1),with a limit of detection of 3.38 nmol·L^(−1).Additionally,the sensor proved successful in recognizing FZD in shrimp samples with satisfactory recoveries and precision.The method provides a strategy to construct a molecularly imprinted electrochemical sensing platform using nanomaterials,which has great promise in the field of food safety. 展开更多
关键词 PHOSPHOMOLYBDATE FURAZOLIDONE POLYOXOMETALATES Carboxylated multi-walled carbon nanotube Molecularly imprinted polymers Electrochemical sensor
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