According to AWPA E11-2006 standard,copper fixation rates of several copper-based formulations,such as ammoniacal copper,amine copper,and ammoniacal-ethanolamine copper,as well as alkaline copper quaternary(ACQ),were ...According to AWPA E11-2006 standard,copper fixation rates of several copper-based formulations,such as ammoniacal copper,amine copper,and ammoniacal-ethanolamine copper,as well as alkaline copper quaternary(ACQ),were tested and compared in this paper.And the fixation rates of tebuconazole(TEB) and propiconazole(PPZ) in several formulations,such as copper azole,emulsified type and solvent type,were also compared.The determination of copper content in the leachate was analyzed by atomic absorption spectrom...展开更多
The changes in relative crystalline, chemical composition and internal structure of compressed Chinese fir wood after different heating fixations were found strictly related to fixation conditions. The compressed wood...The changes in relative crystalline, chemical composition and internal structure of compressed Chinese fir wood after different heating fixations were found strictly related to fixation conditions. The compressed wood powders were fixed either by heating at different temperatures all resulting in a 10% recovery, or by incubating at 180 °C for different periods with subsequent recovery levels. Both X-ray diffraction and infrared absorption of those samples have been measured. Relative crystalline increases at early stage of heating fixation, and then decreased gradually. Hemicellulose and lignin decomposition were induced by the fixation process, especially at 180 °C, and lignin was degraded actively. Furthermore, absorbed water was lost after heating, but cellulose did not change markedly. Although different fixation pathways can result in the same recovery level, the major chemical reactions un- derlying them vary, which is consistent with the difference of fixation mechanisms.展开更多
There are many advantages of bended wood, such as good-looking shape, simple process and low cost. The product, however, is easy to get recovery, which is urgent to be dealt with. This paper concludes the features of ...There are many advantages of bended wood, such as good-looking shape, simple process and low cost. The product, however, is easy to get recovery, which is urgent to be dealt with. This paper concludes the features of deformation and recovery of bended wood and wood-based composites and summarizes four treating methods to keep dimensional stability. Compared to bended solid wood, some elementary perspectives on the research of bended wood-based composites are presented. The purpose of this paper is to suggest: 1) to investigate the optimum heating time and temperature that bended wood and wood-based composites need from the formation of deformation to the recovery and to the permanent fixation, according to its changes of dimensional stability such as curvature radius; 2) to measure the composites comprised of wood and adhesives on the changes of stress relaxation, dynamic viscoelasticity and crystallization field; 3) to quantitatively analyze changes of the major components in wood cell wall polymers as well as the composites under heat/steam treatment and untreated conditions. It will be helpful for subsequent research to clarify on the mechanisms of permanent fixation of bended wood and also contribute to that of wood-based composites.展开更多
基金supported by The 11th Five-year Plan(under code 2006BAD18B09)The "948" Project(under code 2006-4-95)
文摘According to AWPA E11-2006 standard,copper fixation rates of several copper-based formulations,such as ammoniacal copper,amine copper,and ammoniacal-ethanolamine copper,as well as alkaline copper quaternary(ACQ),were tested and compared in this paper.And the fixation rates of tebuconazole(TEB) and propiconazole(PPZ) in several formulations,such as copper azole,emulsified type and solvent type,were also compared.The determination of copper content in the leachate was analyzed by atomic absorption spectrom...
基金the National Natural Science Foundation of China (Grant No.30070606) and Association of International Education of Japan
文摘The changes in relative crystalline, chemical composition and internal structure of compressed Chinese fir wood after different heating fixations were found strictly related to fixation conditions. The compressed wood powders were fixed either by heating at different temperatures all resulting in a 10% recovery, or by incubating at 180 °C for different periods with subsequent recovery levels. Both X-ray diffraction and infrared absorption of those samples have been measured. Relative crystalline increases at early stage of heating fixation, and then decreased gradually. Hemicellulose and lignin decomposition were induced by the fixation process, especially at 180 °C, and lignin was degraded actively. Furthermore, absorbed water was lost after heating, but cellulose did not change markedly. Although different fixation pathways can result in the same recovery level, the major chemical reactions un- derlying them vary, which is consistent with the difference of fixation mechanisms.
文摘There are many advantages of bended wood, such as good-looking shape, simple process and low cost. The product, however, is easy to get recovery, which is urgent to be dealt with. This paper concludes the features of deformation and recovery of bended wood and wood-based composites and summarizes four treating methods to keep dimensional stability. Compared to bended solid wood, some elementary perspectives on the research of bended wood-based composites are presented. The purpose of this paper is to suggest: 1) to investigate the optimum heating time and temperature that bended wood and wood-based composites need from the formation of deformation to the recovery and to the permanent fixation, according to its changes of dimensional stability such as curvature radius; 2) to measure the composites comprised of wood and adhesives on the changes of stress relaxation, dynamic viscoelasticity and crystallization field; 3) to quantitatively analyze changes of the major components in wood cell wall polymers as well as the composites under heat/steam treatment and untreated conditions. It will be helpful for subsequent research to clarify on the mechanisms of permanent fixation of bended wood and also contribute to that of wood-based composites.