In this work, a scalable and cost-effective method including mechanical milling, centrifugation and spray drying was developed to fabricate Si nanoparticles.The synthesized Si nanoparticles show an average size of 62 ...In this work, a scalable and cost-effective method including mechanical milling, centrifugation and spray drying was developed to fabricate Si nanoparticles.The synthesized Si nanoparticles show an average size of 62 nm and exhibit a narrow particle size distribution. The influence of particle sizes on electrochemical performance of Si-based electrode was investigated, and it is found that as the particle size decreases in the studied range, the Si particles show a lower specific capacity and a higher irreversible capacity loss(ICL). Furthermore, an oxide layer with thickness of ～3 nm was detected on the surface of the as-received Si nanoparticles, and this layer can be effectively removed by hydrofluoric acid(HF) etching,resulting in much improved electrochemical performance over the as-received samples.展开更多
针对多工况条件下球磨机关键负荷参数测量面临的复杂性问题,提出基于流形正则化域适应(domain adaptation with manifold regularization,DAMR)湿式球磨机负荷参数软测量的方法。该方法首先采用集成流形约束、最大方差及最大均值差异寻...针对多工况条件下球磨机关键负荷参数测量面临的复杂性问题,提出基于流形正则化域适应(domain adaptation with manifold regularization,DAMR)湿式球磨机负荷参数软测量的方法。该方法首先采用集成流形约束、最大方差及最大均值差异寻找特征变换矩阵,然后,将源建模领域和未建模领域的特征信息投射到公共子空间,最后,在子空间建立模型得到球磨机关键负荷参数的预测值。实验结果表明该方法能以较高的精度实现未知工况下湿式球磨机关键负荷参数的预测,且该方法对于流程工业多工况软测量和过程监控研究有一定的参考价值。展开更多
基金financially supported by the National Natural Science Foundation of China (No. 51404030)the National Key Technologies Research and Development Program (No. 2016YFB0100400)+2 种基金the Natural Science Foundation of Beijing Municipality (No. 3154043)the Beijing Science and Technology Plan (No. Z151100000115015)the Beijing Nova Program (No. Z161100004916096)
文摘In this work, a scalable and cost-effective method including mechanical milling, centrifugation and spray drying was developed to fabricate Si nanoparticles.The synthesized Si nanoparticles show an average size of 62 nm and exhibit a narrow particle size distribution. The influence of particle sizes on electrochemical performance of Si-based electrode was investigated, and it is found that as the particle size decreases in the studied range, the Si particles show a lower specific capacity and a higher irreversible capacity loss(ICL). Furthermore, an oxide layer with thickness of ～3 nm was detected on the surface of the as-received Si nanoparticles, and this layer can be effectively removed by hydrofluoric acid(HF) etching,resulting in much improved electrochemical performance over the as-received samples.
文摘针对多工况条件下球磨机关键负荷参数测量面临的复杂性问题,提出基于流形正则化域适应(domain adaptation with manifold regularization,DAMR)湿式球磨机负荷参数软测量的方法。该方法首先采用集成流形约束、最大方差及最大均值差异寻找特征变换矩阵,然后,将源建模领域和未建模领域的特征信息投射到公共子空间,最后,在子空间建立模型得到球磨机关键负荷参数的预测值。实验结果表明该方法能以较高的精度实现未知工况下湿式球磨机关键负荷参数的预测,且该方法对于流程工业多工况软测量和过程监控研究有一定的参考价值。
