Thermoelectric materials have aroused widespread concern due to their unique ability to directly convert heat to electricity without any moving parts or noxious emissions.Taking advantages of two-dimensional structure...Thermoelectric materials have aroused widespread concern due to their unique ability to directly convert heat to electricity without any moving parts or noxious emissions.Taking advantages of two-dimensional structures of thermoelectric films,the potential applications of thermoelectric materials are diversified,particularly in microdevices.Well-controlled nanostructures in thermoelectric films are effective to optimize the electrical and thermal transport,which can significantly improve the performance of thermoelectric materials.In this paper,various physical and chemical approaches to fabricate thermoelectric films,including inorganic,organic,and inorganic–organic composites,are summarized,where more attentions are paid on the inorganic thermoelectric films for their excellent thermoelectric responses.Additionally,strategies for enhancing the performance of thermoelectric films are also discussed.展开更多
A theoretical model taking into consideration the interface effects is established to predict the Seebeck coefficient and the electrical conductivity for a polycrystalline thermoelectric(TE)thin film.The interface sca...A theoretical model taking into consideration the interface effects is established to predict the Seebeck coefficient and the electrical conductivity for a polycrystalline thermoelectric(TE)thin film.The interface scattering mechanisms(including the film-surface scattering and grain-boundary scattering)of the transport electrons in the film materials are revealed.The relations between the Seebeck coefficient,the electrical conductivity and the interface parameters(the film-surface reflection coefficient and the grain-boundary transmission coefficient)are then discussed with respect to the proposed model.The differences in the TE properties between the films and bulk materials caused by size restriction are investigated.The results indicate that the higher grain number leads to stronger grain-boundary scattering and more distinct size effects of the TE properties.In contrast to the surface effect,the grain-boundary effect plays a main role in the TE properties of TE films with polycrystalline structures.展开更多
基金Project supported by the Joint Funds of the National Natural Science Foundation of China(Grant No.U1601213)the National Natural Science Foundation of China(Grant Nos.51601005 and 61704006)+1 种基金the Beijing Natural Science Foundation(Grant No.2182032)the Fundamental Research Funds for the Central Universities
文摘Thermoelectric materials have aroused widespread concern due to their unique ability to directly convert heat to electricity without any moving parts or noxious emissions.Taking advantages of two-dimensional structures of thermoelectric films,the potential applications of thermoelectric materials are diversified,particularly in microdevices.Well-controlled nanostructures in thermoelectric films are effective to optimize the electrical and thermal transport,which can significantly improve the performance of thermoelectric materials.In this paper,various physical and chemical approaches to fabricate thermoelectric films,including inorganic,organic,and inorganic–organic composites,are summarized,where more attentions are paid on the inorganic thermoelectric films for their excellent thermoelectric responses.Additionally,strategies for enhancing the performance of thermoelectric films are also discussed.
基金National Natural Science Foundation of China(11834012,51620105014,51572210,51521001)National Key Research and Development Plan of China(2018YFB0703600)
基金supported by the National Natural Science Foundation of China(11072093,11121202 and11372120)the PhD Program Foundation of Ministry of Education of China(20110211110023)
文摘A theoretical model taking into consideration the interface effects is established to predict the Seebeck coefficient and the electrical conductivity for a polycrystalline thermoelectric(TE)thin film.The interface scattering mechanisms(including the film-surface scattering and grain-boundary scattering)of the transport electrons in the film materials are revealed.The relations between the Seebeck coefficient,the electrical conductivity and the interface parameters(the film-surface reflection coefficient and the grain-boundary transmission coefficient)are then discussed with respect to the proposed model.The differences in the TE properties between the films and bulk materials caused by size restriction are investigated.The results indicate that the higher grain number leads to stronger grain-boundary scattering and more distinct size effects of the TE properties.In contrast to the surface effect,the grain-boundary effect plays a main role in the TE properties of TE films with polycrystalline structures.
