The braided river is a typical river pattern in nature, but there is a paucity of comprehensive data set describing the three-dimensional flow field in the braided river. A physical model experiment was used to study ...The braided river is a typical river pattern in nature, but there is a paucity of comprehensive data set describing the three-dimensional flow field in the braided river. A physical model experiment was used to study the flow characteristics in the typical braided river with a mid-bar between two anabranches. In the experiment, two kinds of mid-bar with the ratios of its length to maximal width of 3 and 5 were considered. Moreover, the mid-bar could be moved to adjust the width of two anabranches. The detailed measurements of velocity were conducted using an acoustic Doppler velocimeter over a grid defined throughout the whole braided river region, including the bifurcation, two anabranches and the confluence. In two kinds of mid-bar braided models, a separation zone was observed in the anabranch of the model in which the ratio of length to maximal width of mid-bar is 3, however the separation zone was not found in another model in which the ratio is 5. In addition, the opposite secondary cells were observed at the bend apex of anabranch in two models, and different longitudinal velocity distributions in the entrance region of anabranch account for this opposite flow structure. Finally, turbulent kinetic energy were shown and compared in different situations. The high turbulence occurs at the place with strong shear, especially at the boundary of the separation zone and the high velocity passing flow.展开更多
Graphite material was used as the electrode for an all-vanadium redox flow battery, and the electrode was modified by transition metallic ions to enhance its electrochemical behavior. An porous graphite composite elec...Graphite material was used as the electrode for an all-vanadium redox flow battery, and the electrode was modified by transition metallic ions to enhance its electrochemical behavior. An porous graphite composite electrode has high specific surface area and high current density. The electrode modified by transition metallic ions has improved catalysis behavior that can catalyze the V（Ⅱ）-V（Ⅴ） redox reaction showed by cyclic voltammograms. This article studied the impedance of the modified electrode by electrochemical impedance spectroscopy （EIS）, and approved that the electrode modified by Co^2＋ and Mn^2＋ has a lower charge transfer resistance than the non-modified electrode. The effect of average particle size distribution is at lower frequencies that the slope of Warburg impedance is reduced by large particle size distribution. The voltage efficiency of the Co^2＋ modified electrode test cell is 81.5%, which is higher than that of the non-modified electrode.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.50679019)the National Basic Research Program of China(973Program,Grant No.2008CB418202)+1 种基金the project of"Six Talent Peak"of Jiangsu Province(Grant No.08-C)the Social Technology Development Foundation of Jiangsu Province(Grant No.BS2006095).
文摘The braided river is a typical river pattern in nature, but there is a paucity of comprehensive data set describing the three-dimensional flow field in the braided river. A physical model experiment was used to study the flow characteristics in the typical braided river with a mid-bar between two anabranches. In the experiment, two kinds of mid-bar with the ratios of its length to maximal width of 3 and 5 were considered. Moreover, the mid-bar could be moved to adjust the width of two anabranches. The detailed measurements of velocity were conducted using an acoustic Doppler velocimeter over a grid defined throughout the whole braided river region, including the bifurcation, two anabranches and the confluence. In two kinds of mid-bar braided models, a separation zone was observed in the anabranch of the model in which the ratio of length to maximal width of mid-bar is 3, however the separation zone was not found in another model in which the ratio is 5. In addition, the opposite secondary cells were observed at the bend apex of anabranch in two models, and different longitudinal velocity distributions in the entrance region of anabranch account for this opposite flow structure. Finally, turbulent kinetic energy were shown and compared in different situations. The high turbulence occurs at the place with strong shear, especially at the boundary of the separation zone and the high velocity passing flow.
基金This work was financially supported by the National Natural Science Foundation of China (No. 90510001).
文摘Graphite material was used as the electrode for an all-vanadium redox flow battery, and the electrode was modified by transition metallic ions to enhance its electrochemical behavior. An porous graphite composite electrode has high specific surface area and high current density. The electrode modified by transition metallic ions has improved catalysis behavior that can catalyze the V（Ⅱ）-V（Ⅴ） redox reaction showed by cyclic voltammograms. This article studied the impedance of the modified electrode by electrochemical impedance spectroscopy （EIS）, and approved that the electrode modified by Co^2＋ and Mn^2＋ has a lower charge transfer resistance than the non-modified electrode. The effect of average particle size distribution is at lower frequencies that the slope of Warburg impedance is reduced by large particle size distribution. The voltage efficiency of the Co^2＋ modified electrode test cell is 81.5%, which is higher than that of the non-modified electrode.
