Non-equilibrium radiation measurements behind strong shock wave for simulated Martian atmosphere are presented in this paper. The shock wave is established in a hydrogen oxygen combustion driven shock tube. Time- reso...Non-equilibrium radiation measurements behind strong shock wave for simulated Martian atmosphere are presented in this paper. The shock wave is established in a hydrogen oxygen combustion driven shock tube. Time- resolved spectra of the Av = 0 sequence of the B^2∑^＋ → X^2∑^＋ electronic transition of CN have been observed through optical emission spectroscopy （OES）. A new method, which is based on fitting high resolution spectrum for rotational and vibrational temperatures measurement, is proposed to diag- nose temperature distribution behind the shock wave. It is estimated that the current scheme has the maximum deviation less than 8% （lσ） for vibrational temperature measurement through detailed analysis of the influence of the uncertainties of spectroscopic constants and spectral resolution. Radiation structure of the shock layer, including induction, relaxation and equilibrium process, and corresponding rotational and vibrational temperatures are obtained through time gating OES diagnostics with sub-microsecond temporal resolution. The present extensive results will strongly benefit the reaction rate estimation and computational fluid dynamics （CFD） code validation in high enthalpy Mars reentry chemistry.展开更多
Excitation（ Texc ） and rotation（ Trot ） temperatures were determined under different conditions for an oxygen-shielded argon microwave plasmsa torch source（OS-Ar-MPT）. The Texc value, which was shown to be betwe...Excitation（ Texc ） and rotation（ Trot ） temperatures were determined under different conditions for an oxygen-shielded argon microwave plasmsa torch source（OS-Ar-MPT）. The Texc value, which was shown to be between 4300 and 5250 K under different operating conditions, was calculated from the slope of the Boltzmann plot with Fe as the thermometric species. The Trot value, which was in the range of 2100-2500 K, was measured with OH molecular spectra. The influences of microwave power, flow rates of the support gas, cartier gas, and shielding gas, as well as the observation height on Texc and Trot were investigated and discussed. The detailed results of Texc and Trot provided a better understanding of the performance of an OS-ArMPT as a source for atomic emission spectrometry.展开更多
文摘Non-equilibrium radiation measurements behind strong shock wave for simulated Martian atmosphere are presented in this paper. The shock wave is established in a hydrogen oxygen combustion driven shock tube. Time- resolved spectra of the Av = 0 sequence of the B^2∑^＋ → X^2∑^＋ electronic transition of CN have been observed through optical emission spectroscopy （OES）. A new method, which is based on fitting high resolution spectrum for rotational and vibrational temperatures measurement, is proposed to diag- nose temperature distribution behind the shock wave. It is estimated that the current scheme has the maximum deviation less than 8% （lσ） for vibrational temperature measurement through detailed analysis of the influence of the uncertainties of spectroscopic constants and spectral resolution. Radiation structure of the shock layer, including induction, relaxation and equilibrium process, and corresponding rotational and vibrational temperatures are obtained through time gating OES diagnostics with sub-microsecond temporal resolution. The present extensive results will strongly benefit the reaction rate estimation and computational fluid dynamics （CFD） code validation in high enthalpy Mars reentry chemistry.
基金Supported by the Science and Technology Development Program of Jilin Province, P. R. China(No. 20010306-1).
文摘Excitation（ Texc ） and rotation（ Trot ） temperatures were determined under different conditions for an oxygen-shielded argon microwave plasmsa torch source（OS-Ar-MPT）. The Texc value, which was shown to be between 4300 and 5250 K under different operating conditions, was calculated from the slope of the Boltzmann plot with Fe as the thermometric species. The Trot value, which was in the range of 2100-2500 K, was measured with OH molecular spectra. The influences of microwave power, flow rates of the support gas, cartier gas, and shielding gas, as well as the observation height on Texc and Trot were investigated and discussed. The detailed results of Texc and Trot provided a better understanding of the performance of an OS-ArMPT as a source for atomic emission spectrometry.
