摘要
利用光学多通道分析仪(OMA)对酒精和煤油在大气中燃烧时的火焰发射光谱进行了分析.实验发现上述火焰发射光谱在275—600nm波段范围内存在多支辐射强度很大的带状分子光谱,其中以OH自由基A2Σ+→X2Πr(300—330nm),CH自由基A2Δ→X2Π(410—440nm)和C2自由基A3Πg→X3Πu(500—520nm)电子带系的发射光谱最为强烈.实验中采用高分辨率光栅对OH自由基A2Σ+→X2Πr和CH自由基A2Δ→X2Π电子带系发射光谱的精细结构进行了分析.与此同时,本文基于分子光谱理论计算了不同转动温度和振动温度条件下OH自由基A2Σ+→X2Πr和CH自由基A2Δ→X2Π电子带系发射光谱的强度分布,同时通过理论计算光谱和实验光谱进行比较确定了酒精燃烧火焰的转动温度和振动温度.
This study addresses emission spectra of Air-ethanol and Air-kerosene flames by using optical multichannel analysis system（OMA）.Experimental results show that there are several bands of molecular spectrum in a range from 275 to 600nm.Among them,the OH A2Σ＋→X2Πr（300—330 nm）,the CH A2Δ→X2Π（410—440 nm）,and C2 A3Πg→X3Πu（500— 520 nm） emissions have the strongest intensity.In turn,the fine structures of OH（A2Σ＋→X2Πr） and CH（A2Δ→X2Π） emission are studied by using a high resolution grating in experiment,and the distributions of spectra intensity are calculated at different rotational and vibrational temperatures based on the molecular spectroscopy.Moreover,by comparing the simulated spectra with the experimental spectra of OH（A2Σ＋→X2Πr） and CH（A2Δ→X2Π） emissions,the rotational and the vibrational temperatures of Air-ethanol flame are determined in this paper.
出处
《物理学报》
SCIE
EI
CAS
CSCD
北大核心
2011年第10期454-460,共7页
Acta Physica Sinica
关键词
火焰发射光谱
谱线强度
转动温度
振动温度
flame emission spectroscopy
line intensity
rotational temperature
vibrational temperature
