Based on our discovery of neutral aluminum molecular rings,we herein introduce rare earth ions into the center of the ring and reveal their structural adaptability.The resulting yoyo-like cationic macrocycles are high...Based on our discovery of neutral aluminum molecular rings,we herein introduce rare earth ions into the center of the ring and reveal their structural adaptability.The resulting yoyo-like cationic macrocycles are highly adaptive to guests,creating unusual supramolecular assemblies.The first category is stacked with singly oriented rhombohedral channels,which exhibit fast and reversible solvent-triggered molecular motions and structural rearrangements.The second type of assembly is that yoyo macrocycles and guest molecules form a nested host-guest sodalite cage supramolecular structure.It is uncommon for guest molecules to be well-defined within cages although caged structures have been well-documented.Their host-guest interaction discussion reveals the self-adaptation and flexibility of the yoyo macrocycles.Considering their good water stability,we investigated their anion exchange properties.The results show that they have significant exchange capacity for KI/I_(2),ReO_(4)^(-),and MnO_(4)^(-),revealing their potential application in water purification and nuclear waste treatment.展开更多
航空发动机主轴中滚动轴承为了降低系统振动经常与弹性环式挤压油膜阻尼器(elastic ring squeeze film damper, ERSFD)联合使用。基于滚动轴承动力学理论和流体力学控制方程,采用变步长积分算法建立圆柱滚子轴承与ERSFD耦合的动力学分...航空发动机主轴中滚动轴承为了降低系统振动经常与弹性环式挤压油膜阻尼器(elastic ring squeeze film damper, ERSFD)联合使用。基于滚动轴承动力学理论和流体力学控制方程,采用变步长积分算法建立圆柱滚子轴承与ERSFD耦合的动力学分析模型,对外圈带ERSFD的圆柱滚子轴承保持架振动特性和打滑率进行研究。研究结果表明:与未装配ERSFD的圆柱滚子轴承相比,ERSFD可以提高圆柱滚子轴承保持架的稳定性。过大或过小的弹性环凸台数量与宽度都不利于圆柱滚子轴承保持架的稳定性,需要选择合适的凸台数量和宽度。径向载荷与转速对带弹性环的圆柱滚子轴承保持架稳定性影响显著,保持架涡动频率的谐波次数随着径向载荷的增加而减少,其对应的幅值也减小;保持架涡动频率的谐波次数随着转速的增加而增加,其对应幅值也增加。展开更多
基金supported by the National Natural Science Foundation of China(92061104,21771181,21935010)the Natural Science Foundation of Fujian Province(2021J06035)the Youth Innovation Promotion Association CAS(2017345,Y2018081)。
文摘Based on our discovery of neutral aluminum molecular rings,we herein introduce rare earth ions into the center of the ring and reveal their structural adaptability.The resulting yoyo-like cationic macrocycles are highly adaptive to guests,creating unusual supramolecular assemblies.The first category is stacked with singly oriented rhombohedral channels,which exhibit fast and reversible solvent-triggered molecular motions and structural rearrangements.The second type of assembly is that yoyo macrocycles and guest molecules form a nested host-guest sodalite cage supramolecular structure.It is uncommon for guest molecules to be well-defined within cages although caged structures have been well-documented.Their host-guest interaction discussion reveals the self-adaptation and flexibility of the yoyo macrocycles.Considering their good water stability,we investigated their anion exchange properties.The results show that they have significant exchange capacity for KI/I_(2),ReO_(4)^(-),and MnO_(4)^(-),revealing their potential application in water purification and nuclear waste treatment.
文摘航空发动机主轴中滚动轴承为了降低系统振动经常与弹性环式挤压油膜阻尼器(elastic ring squeeze film damper, ERSFD)联合使用。基于滚动轴承动力学理论和流体力学控制方程,采用变步长积分算法建立圆柱滚子轴承与ERSFD耦合的动力学分析模型,对外圈带ERSFD的圆柱滚子轴承保持架振动特性和打滑率进行研究。研究结果表明:与未装配ERSFD的圆柱滚子轴承相比,ERSFD可以提高圆柱滚子轴承保持架的稳定性。过大或过小的弹性环凸台数量与宽度都不利于圆柱滚子轴承保持架的稳定性,需要选择合适的凸台数量和宽度。径向载荷与转速对带弹性环的圆柱滚子轴承保持架稳定性影响显著,保持架涡动频率的谐波次数随着径向载荷的增加而减少,其对应的幅值也减小;保持架涡动频率的谐波次数随着转速的增加而增加,其对应幅值也增加。
