Red mud is a byproduct of alumina refining of bauxite ores,and is a significant source for extracting scandium.However,a large amount of iron in red mud makes it difficult to recover scandium because Fe(III) and Sc(Ⅲ...Red mud is a byproduct of alumina refining of bauxite ores,and is a significant source for extracting scandium.However,a large amount of iron in red mud makes it difficult to recover scandium because Fe(III) and Sc(Ⅲ) have similar physicochemical properties.In this study,a new method was developed for selective separation of iron and scandium in acid leachate of red mud using D201 resin.Theoretical calculations indicate that the ferric species mainly exists as FeCl3 or FeCl4-at chloride concentration above 6.65 mol/L,while scandium still exists as SCl2+,making it possible to selectively separate iron fro m scandium through anion resin adso rption.The factors affecting the adso rption of iron and scandium such as chloride conce ntratio n,resin dosage,adso rption time,and temperature were evaluated in batch experiments,The Langmuir model was successfully applied to both iron and scandium adsorption,and the maximum adsorption capacities of iron and scandium are 147.06 and 0.95 mg/g,respectively,indicating a significant difference between iron and scandium.Raman analysis further demonstrates that the iron is adsorbed onto D201 resin as FeCl4 anion.展开更多
基金Project supported by the Natural National Science Foundation of China(21707167)。
文摘Red mud is a byproduct of alumina refining of bauxite ores,and is a significant source for extracting scandium.However,a large amount of iron in red mud makes it difficult to recover scandium because Fe(III) and Sc(Ⅲ) have similar physicochemical properties.In this study,a new method was developed for selective separation of iron and scandium in acid leachate of red mud using D201 resin.Theoretical calculations indicate that the ferric species mainly exists as FeCl3 or FeCl4-at chloride concentration above 6.65 mol/L,while scandium still exists as SCl2+,making it possible to selectively separate iron fro m scandium through anion resin adso rption.The factors affecting the adso rption of iron and scandium such as chloride conce ntratio n,resin dosage,adso rption time,and temperature were evaluated in batch experiments,The Langmuir model was successfully applied to both iron and scandium adsorption,and the maximum adsorption capacities of iron and scandium are 147.06 and 0.95 mg/g,respectively,indicating a significant difference between iron and scandium.Raman analysis further demonstrates that the iron is adsorbed onto D201 resin as FeCl4 anion.
