在前期研究超声波辅助提取沙枣果总黄酮的工艺基础上,为探讨沙枣果总黄酮的纯化工艺,选择大孔树脂为吸附剂来分离纯化沙枣果总黄酮。先进行了大孔树脂的选择试验研究和大孔树脂静态吸附动力学研究,结果表明AB-8树脂的吸附量和解吸率都较...在前期研究超声波辅助提取沙枣果总黄酮的工艺基础上,为探讨沙枣果总黄酮的纯化工艺,选择大孔树脂为吸附剂来分离纯化沙枣果总黄酮。先进行了大孔树脂的选择试验研究和大孔树脂静态吸附动力学研究,结果表明AB-8树脂的吸附量和解吸率都较高,是适于吸附分离沙枣果总黄酮的理想树脂类型。在此基础上,通过AB-8大孔树脂对沙枣果总黄酮动态吸附试验、动态洗脱试验确定出沙枣果总黄酮的最佳纯化条件:上样量70 m L、上样浓度0.5 mg/m L、p H4.0、上样流速1.0 m L/min;使用4BV用量的90%乙醇作为洗脱剂进行洗脱,解析流速为1.5 m L/min;AB-8大孔树脂对沙枣果总黄酮的纯化效果较好,纯度为65.56%,是粗提黄酮纯度的2.84倍。并对纯化后的沙枣果总黄酮进行成分鉴定和抗氧化性能评价,结果表明,沙枣果总黄酮纯化物抗脂质过氧化能力明显强于VC和PG,3种自由基抗氧化能力均强于PG,弱于VC。展开更多
Mg-Gd-Y-Zr alloys were purified by filtering purification with and without vacuum. The type, morphology, size distribution and volume fraction of inclusion were analyzed with OM and SEM. The effect of inclusion in Mg-...Mg-Gd-Y-Zr alloys were purified by filtering purification with and without vacuum. The type, morphology, size distribution and volume fraction of inclusion were analyzed with OM and SEM. The effect of inclusion in Mg-Gd-Y-Zr alloys on anticorrosion ability was investigated with salt spray test and electrochemical test. The results show that the inclusions in the alloy can be removed effectively by filtering purification. The average size of inclusions in the alloys is decreased from 12.7 μm to 2.0 μm and the volume fraction of inclusions is reduced from 0.30% to 0.04%. With the decrease of the size of inclusions in the alloys, the corrosion rate of the alloys decreases dramatically from 38.8 g/（m 2 ·d） to 2.4 g/（m 2 ·d） in the salt spray test. The corrosion potential increases while the corrosion current decreases and the polarization resistance increases in the electrochemical tests, which indicates that the anticorrosion ability is improved.展开更多
Mg-Gd-Y-Zr alloy was purified by the method of filtering purification. The type, morphology, size distribution and volume fraction of inclusions in the alloy were analyzed using optical microscope and scanning electro...Mg-Gd-Y-Zr alloy was purified by the method of filtering purification. The type, morphology, size distribution and volume fraction of inclusions in the alloy were analyzed using optical microscope and scanning electron microscope, and the effects of the inclusions on the mechanical and corrosion properties of the alloy were investigated. The results indicate that the filtering purification method is effective to remove inclusions in the alloy. By the filtering purification method, the average size of inclusions in the alloy reduces from 12.7 μm to 4.3 μm and the average volume fraction of inclusions in the alloy reduces from 0.26% to 0.06%. The ultimate tensile strength, yield strength and elongation of the alloy are improved from 200 MPa, 156 MPa and 3.4% to 232 MPa, 167 MPa and 7.0%, respectively. The corrosion rate of the alloy decreases dramatically from 38.8g/（mLd） to 2.5 g/（mZ.d） in the salt spray test.展开更多
文摘在前期研究超声波辅助提取沙枣果总黄酮的工艺基础上,为探讨沙枣果总黄酮的纯化工艺,选择大孔树脂为吸附剂来分离纯化沙枣果总黄酮。先进行了大孔树脂的选择试验研究和大孔树脂静态吸附动力学研究,结果表明AB-8树脂的吸附量和解吸率都较高,是适于吸附分离沙枣果总黄酮的理想树脂类型。在此基础上,通过AB-8大孔树脂对沙枣果总黄酮动态吸附试验、动态洗脱试验确定出沙枣果总黄酮的最佳纯化条件:上样量70 m L、上样浓度0.5 mg/m L、p H4.0、上样流速1.0 m L/min;使用4BV用量的90%乙醇作为洗脱剂进行洗脱,解析流速为1.5 m L/min;AB-8大孔树脂对沙枣果总黄酮的纯化效果较好,纯度为65.56%,是粗提黄酮纯度的2.84倍。并对纯化后的沙枣果总黄酮进行成分鉴定和抗氧化性能评价,结果表明,沙枣果总黄酮纯化物抗脂质过氧化能力明显强于VC和PG,3种自由基抗氧化能力均强于PG,弱于VC。
基金Project(2007CB613700)supported by the National Basic Research Program of China
文摘Mg-Gd-Y-Zr alloys were purified by filtering purification with and without vacuum. The type, morphology, size distribution and volume fraction of inclusion were analyzed with OM and SEM. The effect of inclusion in Mg-Gd-Y-Zr alloys on anticorrosion ability was investigated with salt spray test and electrochemical test. The results show that the inclusions in the alloy can be removed effectively by filtering purification. The average size of inclusions in the alloys is decreased from 12.7 μm to 2.0 μm and the volume fraction of inclusions is reduced from 0.30% to 0.04%. With the decrease of the size of inclusions in the alloys, the corrosion rate of the alloys decreases dramatically from 38.8 g/（m 2 ·d） to 2.4 g/（m 2 ·d） in the salt spray test. The corrosion potential increases while the corrosion current decreases and the polarization resistance increases in the electrochemical tests, which indicates that the anticorrosion ability is improved.
基金Project(2007CB613705)supported by the National Basic Research Program of China
文摘Mg-Gd-Y-Zr alloy was purified by the method of filtering purification. The type, morphology, size distribution and volume fraction of inclusions in the alloy were analyzed using optical microscope and scanning electron microscope, and the effects of the inclusions on the mechanical and corrosion properties of the alloy were investigated. The results indicate that the filtering purification method is effective to remove inclusions in the alloy. By the filtering purification method, the average size of inclusions in the alloy reduces from 12.7 μm to 4.3 μm and the average volume fraction of inclusions in the alloy reduces from 0.26% to 0.06%. The ultimate tensile strength, yield strength and elongation of the alloy are improved from 200 MPa, 156 MPa and 3.4% to 232 MPa, 167 MPa and 7.0%, respectively. The corrosion rate of the alloy decreases dramatically from 38.8g/（mLd） to 2.5 g/（mZ.d） in the salt spray test.
