The chemical looping reforming of methane through the nonstoichiometric ceria redox cycle(CeO2/CeO2-δ) has been experimentally investigated in a directly irradiated solar reactor to convert both solar energy and meth...The chemical looping reforming of methane through the nonstoichiometric ceria redox cycle(CeO2/CeO2-δ) has been experimentally investigated in a directly irradiated solar reactor to convert both solar energy and methane to syngas in the temperature range 900–1050 °C. Experiments were carried out with different ceria shapes via two-step redox cycling composed of endothermic partial reduction of ceria with methane and complete exothermic re-oxidation of reduced ceria with H2 O/CO2 at the same operating temperature, thereby demonstrating the capability to operate the cycle isothermally. A parametric study considering different ceria macrostructure variants(ceria packed powder, ceria packed powder mixed with inert Al2 O3 particles, and ceria reticulated porous foam) and operating parameters(methane flow-rate, reduction temperature, or sintering temperature) was conducted in order to unravel their impact on the bed-averaged oxygen non-stoichiometry(δ), syngas yield, methane conversion, and solar reactor performance. The ceria cycling stability was also experimentally investigated to demonstrate repeatable syngas production by alternating the flow between CH4 and H2 O(or CO2). A decrease in sintering temperature of the ceria foam was beneficial for increasing syngas selectivity, methane conversion,and reactor performance. Increasing both CH4 concentration and reduction temperature enhanced δ with the maximum value up to 0.41 but concomitantly favored CH4 cracking reaction. The ceria reticulated porous foam showed better performance in terms of effective heat transfer, due to volumetric absorption of concentrated solar radiation and uniform heating with lower solar power consumption, thereby promoting the solar-to-fuel energy conversion efficiency that reached up to 5.60%. The energy upgrade factor achieved during cycle was up to 1.19. Stable patterns in the δ and syngas yield for consecutive cycles with the ceria foam validated material performance stability.展开更多
Coal-fired power is the main power source and the biggest contributor to energy conservation in the past several decades in China.It is generally believed that advanced technology should be counted on for energy conse...Coal-fired power is the main power source and the biggest contributor to energy conservation in the past several decades in China.It is generally believed that advanced technology should be counted on for energy conservation.However,a review of the decline in the national average net coal consumption rate(NCCR)of China's coal-fired power industry along with its development over the past few decades indicates that the upgradation of the national unit capacity structure(including installing advanced production and phasing out backward production)plays a more important role.A quantitative study on the effect of the unit capacity structure upgradation on the decline in the national average NCCR suggests that phasing out backward production is the leading factor for the decline in the NCCR in the past decade,followed by the new installation,whose sum contributes to approximately 80%of the decline in the national average NCCR.The new installation has an effective affecting period of about 8 years,during which it would gradually decline from a relatively high value.Since the effect of phasing out backward production may remain at a certain degree given a continual action of phasing out backward capacity,it is suggested that the organized action of phasing out backward production should be insisted on.展开更多
基金The King Mongkut’s Institute of Technology Ladkrabang(KMITL),Thailandthe Franco-Thai scholarship program。
文摘The chemical looping reforming of methane through the nonstoichiometric ceria redox cycle(CeO2/CeO2-δ) has been experimentally investigated in a directly irradiated solar reactor to convert both solar energy and methane to syngas in the temperature range 900–1050 °C. Experiments were carried out with different ceria shapes via two-step redox cycling composed of endothermic partial reduction of ceria with methane and complete exothermic re-oxidation of reduced ceria with H2 O/CO2 at the same operating temperature, thereby demonstrating the capability to operate the cycle isothermally. A parametric study considering different ceria macrostructure variants(ceria packed powder, ceria packed powder mixed with inert Al2 O3 particles, and ceria reticulated porous foam) and operating parameters(methane flow-rate, reduction temperature, or sintering temperature) was conducted in order to unravel their impact on the bed-averaged oxygen non-stoichiometry(δ), syngas yield, methane conversion, and solar reactor performance. The ceria cycling stability was also experimentally investigated to demonstrate repeatable syngas production by alternating the flow between CH4 and H2 O(or CO2). A decrease in sintering temperature of the ceria foam was beneficial for increasing syngas selectivity, methane conversion,and reactor performance. Increasing both CH4 concentration and reduction temperature enhanced δ with the maximum value up to 0.41 but concomitantly favored CH4 cracking reaction. The ceria reticulated porous foam showed better performance in terms of effective heat transfer, due to volumetric absorption of concentrated solar radiation and uniform heating with lower solar power consumption, thereby promoting the solar-to-fuel energy conversion efficiency that reached up to 5.60%. The energy upgrade factor achieved during cycle was up to 1.19. Stable patterns in the δ and syngas yield for consecutive cycles with the ceria foam validated material performance stability.
基金China Postdoctoral Science Foundation (No.2017M620758)Special Funds of the National Natural Science Foundation of China(Grant No.L1522032)the Consulting Project of Chinese Academy of Engineering(No.2015-ZCQ-06).
文摘Coal-fired power is the main power source and the biggest contributor to energy conservation in the past several decades in China.It is generally believed that advanced technology should be counted on for energy conservation.However,a review of the decline in the national average net coal consumption rate(NCCR)of China's coal-fired power industry along with its development over the past few decades indicates that the upgradation of the national unit capacity structure(including installing advanced production and phasing out backward production)plays a more important role.A quantitative study on the effect of the unit capacity structure upgradation on the decline in the national average NCCR suggests that phasing out backward production is the leading factor for the decline in the NCCR in the past decade,followed by the new installation,whose sum contributes to approximately 80%of the decline in the national average NCCR.The new installation has an effective affecting period of about 8 years,during which it would gradually decline from a relatively high value.Since the effect of phasing out backward production may remain at a certain degree given a continual action of phasing out backward capacity,it is suggested that the organized action of phasing out backward production should be insisted on.
