Heptafluoroisobutyrontrile(C_(3)F_(7)CN)performs well in dielectric properties and environmental protection,which has the potential to replace SF6 gas.The decomposition characteristics of C_(3)F_(7)CN mixture under fa...Heptafluoroisobutyrontrile(C_(3)F_(7)CN)performs well in dielectric properties and environmental protection,which has the potential to replace SF6 gas.The decomposition characteristics of C_(3)F_(7)CN mixture under fault conditions directly affect the possibility of its replacement for SF6 gas.However,the number of studies on the decomposition characteristics of C_(3)F_(7)CN mixture under overheating fault is less.In this paper,the decomposition characteristics of C_(3)F_(7)CN/CO_(2) mixture under an overheating fault are studied by gas chromatography-mass spectrometry(GC/MS)and quantum chemical calculations.Byproducts CO,C_(3)F_(6) and HF are detected at 200℃.At 550℃,the C_(3)F_(7)CN molecule begins to decompose and produces CHF_(3),C_(2)F_(4),CF_(3)CN and CNCN.Moreover,the results of GC/MS show that the insulation medium C_(3)F_(7)CN contains an impurity,which is C3HF7(HFC-227ea).Combined with the results of GC/MS and quantum chemistry calculations,it can be concluded that the decomposition by-product C_(3)F_(6) at 200℃ mainly comes from the decomposition of C_(3)HF_(7).C_(3)HF_(7) reduces the decomposition temperature of the C_(3)F_(7)CN/CO_(2) mixture.Therefore,it is very important to improve the purity of the insulation medium C_(3)F_(7)CN.展开更多
基金supported by the National Key R&D Program of China(2017YFB0902500)Science&Technology Project of State Corporation of China:The Environment-Friendly Gas-Insulated Transmission Line(GIL)and National Natural Science Foundation of China(51877203)。
文摘Heptafluoroisobutyrontrile(C_(3)F_(7)CN)performs well in dielectric properties and environmental protection,which has the potential to replace SF6 gas.The decomposition characteristics of C_(3)F_(7)CN mixture under fault conditions directly affect the possibility of its replacement for SF6 gas.However,the number of studies on the decomposition characteristics of C_(3)F_(7)CN mixture under overheating fault is less.In this paper,the decomposition characteristics of C_(3)F_(7)CN/CO_(2) mixture under an overheating fault are studied by gas chromatography-mass spectrometry(GC/MS)and quantum chemical calculations.Byproducts CO,C_(3)F_(6) and HF are detected at 200℃.At 550℃,the C_(3)F_(7)CN molecule begins to decompose and produces CHF_(3),C_(2)F_(4),CF_(3)CN and CNCN.Moreover,the results of GC/MS show that the insulation medium C_(3)F_(7)CN contains an impurity,which is C3HF7(HFC-227ea).Combined with the results of GC/MS and quantum chemistry calculations,it can be concluded that the decomposition by-product C_(3)F_(6) at 200℃ mainly comes from the decomposition of C_(3)HF_(7).C_(3)HF_(7) reduces the decomposition temperature of the C_(3)F_(7)CN/CO_(2) mixture.Therefore,it is very important to improve the purity of the insulation medium C_(3)F_(7)CN.
