In this paper, vanadium oxide thin film of TCR of -3.5%/K has been deposited by pulsed DC magnetron sputtering method. The property of this VOx has been investigated by X-ray diffractometer （XRD） and atomic force mi...In this paper, vanadium oxide thin film of TCR of -3.5%/K has been deposited by pulsed DC magnetron sputtering method. The property of this VOx has been investigated by X-ray diffractometer （XRD） and atomic force microscopy （AFM） in detail. XRD test indicates that this film is composed of V203, V305 and VO2.VOx microbolometer with infrared （IR） absorbing structure is fabricated based on porous silicon sacrificial layer technology. Optimized micro-bridge structure is designed and carried out to decrease thermal conductance and this structure shows good compatibility with micromachining technology. This kind of bolometer with 74% IR absorption of 8-14μm, has maximum detectivity of 1.09×109cm.Hz]/2/W at 24Hz frequency and 9.81aA bias current.展开更多
Amines have many atmospheric sources and their clusters play an important role in aerosol nucleation processes. Clusters of a typical amine, dimethylamine（DMA）, of different sizes were measured with matrix isolation...Amines have many atmospheric sources and their clusters play an important role in aerosol nucleation processes. Clusters of a typical amine, dimethylamine（DMA）, of different sizes were measured with matrix isolation IR（infrared） and NIR（near infrared）spectroscopy. The NIR vibrations are more separated and therefore it is easier to distinguish different sizes of clusters in this region. The DMA clusters, up to DMA tetramer, have been optimized using density functional methods, and the geometries, binding energies and thermodynamic properties of DMA clusters were obtained. The computed frequencies and intensities of NH-stretching vibrations in the DMA clusters were used to interpret the experimental spectra. We have identified the fundamental transitions of the bonded NH-stretching vibration and the first overtone transitions of the bonded and free NH-stretching vibration in the DMA clusters. Based on the changes in vibrational intensities during the annealing processes, the growth of clusters was clearly observed. The results of annealing processes indicate that DMA molecules tend to form larger clusters with lower energies under matrix temperatures, which is also supported by the calculated reaction energies of cluster formation.展开更多
The ρ(NH2) infrared(IR) frequencies and the corresponding full width at half maximum(FWHM) values for(CH3)2 NH2 FeⅢ M Ⅱ(HCOO)6(DMFe M, M = Ni, Zn, Cu, Fe, and Mg) are analyzed at various temperatures by using the e...The ρ(NH2) infrared(IR) frequencies and the corresponding full width at half maximum(FWHM) values for(CH3)2 NH2 FeⅢ M Ⅱ(HCOO)6(DMFe M, M = Ni, Zn, Cu, Fe, and Mg) are analyzed at various temperatures by using the experimental data from the literature. For the analysis of the IR frequencies of the ρ(NH2) mode which is associated with the structural phase transitions in those metal structures, the temperature dependence of the mode frequency is assumed as an order parameter and the IR frequencies are calculated by using the molecular field theory. Also, the temperature dependence of the IR frequencies and of the damping constant as calculated from the models of pseudospin(dynamic disorder of dimethylammonium(DMA+) cations)–phonon coupling(PS) and of the energy fluctuation(EF), is fitted to the observed data for the wavenumber and FWHM of the ρ(NH2) IR mode of the niccolites studied here. We find that the observed behavior of the IR frequencies and the FWHM of this mode can be described adequately by the models studied for the crystalline structures of interest. This method of calculating the frequencies(IR and Raman) and FWHM of modes which are responsible for the phase transitions can also be applied to some other metal organic frameworks.展开更多
For the past few decades,the internet of underwater things(IoUT)otained a lot of attention in mobile aquatic applications such as oceanography,diver network monitoring,unmanned underwater exploration,underwater survei...For the past few decades,the internet of underwater things(IoUT)otained a lot of attention in mobile aquatic applications such as oceanography,diver network monitoring,unmanned underwater exploration,underwater surveillance,location tracking system,etc.Most of the IoUT applications rely on acoustic medium.The current IoUT applications face difficulty in delivering a reliable communication system due to the various technical limitations of IoUT environment such as low data rate,attenuation,limited bandwidth,limited battery,limited memory,connectivity problem,etc.One of the significant applications of IoUT include monitoring underwater diver networks.In order to perform a reliable and energy-efficient communication system in the underwater diver networks,a smart underwater hybrid softwaredefined modem(UHSDM)for the mobile ad-hoc network was developed that is used for selecting the best channel/medium among acoustic,visible light communication(VLC),and infrared(IR)based on the criteria established within the system.However,due to the mobility of underwater divers,the developed UHSDMmeets the challenges such as connectivity errors,frequent link failure,transmission delay caused by re-routing,etc.During emergency,the divers are most at the risk of survival.To deal with diver mobility,connectivity,energy efficiency,and reducing the latency in ADN,a handover mechanism based on pre-built UHSDM is proposed in this paper.This paper focuses on(1)design of UHSDM for ADN(2)propose the channel selection mechanism in UHSDM for selecting the best medium for handover and(3)propose handover protocol inADN.The implementation result shows that the proposed mechanism can be used to find the new route for divers in advance and the latency can be reduced significantly.Additionally,this paper shows the real field experiment of air tests and underwater tests with various distances.This research will contribute much to the profit of researchers in underwater diver networks and underwater networks,for improving the quality of services(QoS)展开更多
文摘In this paper, vanadium oxide thin film of TCR of -3.5%/K has been deposited by pulsed DC magnetron sputtering method. The property of this VOx has been investigated by X-ray diffractometer （XRD） and atomic force microscopy （AFM） in detail. XRD test indicates that this film is composed of V203, V305 and VO2.VOx microbolometer with infrared （IR） absorbing structure is fabricated based on porous silicon sacrificial layer technology. Optimized micro-bridge structure is designed and carried out to decrease thermal conductance and this structure shows good compatibility with micromachining technology. This kind of bolometer with 74% IR absorption of 8-14μm, has maximum detectivity of 1.09×109cm.Hz]/2/W at 24Hz frequency and 9.81aA bias current.
基金supported by the Danish Council for Independent Research-Natural Sciences,the Danish Center for Scientific Computing (DCSC)National Natural Science Foundation of China (Nos.21407095,21577080)Shandong Provincial Natural Science Foundation,China (No.ZR2014BQ013)
文摘Amines have many atmospheric sources and their clusters play an important role in aerosol nucleation processes. Clusters of a typical amine, dimethylamine（DMA）, of different sizes were measured with matrix isolation IR（infrared） and NIR（near infrared）spectroscopy. The NIR vibrations are more separated and therefore it is easier to distinguish different sizes of clusters in this region. The DMA clusters, up to DMA tetramer, have been optimized using density functional methods, and the geometries, binding energies and thermodynamic properties of DMA clusters were obtained. The computed frequencies and intensities of NH-stretching vibrations in the DMA clusters were used to interpret the experimental spectra. We have identified the fundamental transitions of the bonded NH-stretching vibration and the first overtone transitions of the bonded and free NH-stretching vibration in the DMA clusters. Based on the changes in vibrational intensities during the annealing processes, the growth of clusters was clearly observed. The results of annealing processes indicate that DMA molecules tend to form larger clusters with lower energies under matrix temperatures, which is also supported by the calculated reaction energies of cluster formation.
文摘The ρ(NH2) infrared(IR) frequencies and the corresponding full width at half maximum(FWHM) values for(CH3)2 NH2 FeⅢ M Ⅱ(HCOO)6(DMFe M, M = Ni, Zn, Cu, Fe, and Mg) are analyzed at various temperatures by using the experimental data from the literature. For the analysis of the IR frequencies of the ρ(NH2) mode which is associated with the structural phase transitions in those metal structures, the temperature dependence of the mode frequency is assumed as an order parameter and the IR frequencies are calculated by using the molecular field theory. Also, the temperature dependence of the IR frequencies and of the damping constant as calculated from the models of pseudospin(dynamic disorder of dimethylammonium(DMA+) cations)–phonon coupling(PS) and of the energy fluctuation(EF), is fitted to the observed data for the wavenumber and FWHM of the ρ(NH2) IR mode of the niccolites studied here. We find that the observed behavior of the IR frequencies and the FWHM of this mode can be described adequately by the models studied for the crystalline structures of interest. This method of calculating the frequencies(IR and Raman) and FWHM of modes which are responsible for the phase transitions can also be applied to some other metal organic frameworks.
基金This research was a part of the project titled“Development of the wide-area underwater mobile communication systems”funded by the Ministry of Oceans and Fisheries,Korea.
文摘For the past few decades,the internet of underwater things(IoUT)otained a lot of attention in mobile aquatic applications such as oceanography,diver network monitoring,unmanned underwater exploration,underwater surveillance,location tracking system,etc.Most of the IoUT applications rely on acoustic medium.The current IoUT applications face difficulty in delivering a reliable communication system due to the various technical limitations of IoUT environment such as low data rate,attenuation,limited bandwidth,limited battery,limited memory,connectivity problem,etc.One of the significant applications of IoUT include monitoring underwater diver networks.In order to perform a reliable and energy-efficient communication system in the underwater diver networks,a smart underwater hybrid softwaredefined modem(UHSDM)for the mobile ad-hoc network was developed that is used for selecting the best channel/medium among acoustic,visible light communication(VLC),and infrared(IR)based on the criteria established within the system.However,due to the mobility of underwater divers,the developed UHSDMmeets the challenges such as connectivity errors,frequent link failure,transmission delay caused by re-routing,etc.During emergency,the divers are most at the risk of survival.To deal with diver mobility,connectivity,energy efficiency,and reducing the latency in ADN,a handover mechanism based on pre-built UHSDM is proposed in this paper.This paper focuses on(1)design of UHSDM for ADN(2)propose the channel selection mechanism in UHSDM for selecting the best medium for handover and(3)propose handover protocol inADN.The implementation result shows that the proposed mechanism can be used to find the new route for divers in advance and the latency can be reduced significantly.Additionally,this paper shows the real field experiment of air tests and underwater tests with various distances.This research will contribute much to the profit of researchers in underwater diver networks and underwater networks,for improving the quality of services(QoS)
