Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a novel Zn（II）-thiourea complex has been developed. The remarkable advantages of this reaction are mild reaction conditions, simple workup procedur...Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a novel Zn（II）-thiourea complex has been developed. The remarkable advantages of this reaction are mild reaction conditions, simple workup procedure, high yield of products and the use of ethanol as acceptable solvent.展开更多
p-1, 1, 3, 3-Tetramethylbutylphenol was prepared by the alkylation of the phenol with Nafion catalyst in extremely high yield. Various reaction conditions were investigated, including the reaction temperature, reac...p-1, 1, 3, 3-Tetramethylbutylphenol was prepared by the alkylation of the phenol with Nafion catalyst in extremely high yield. Various reaction conditions were investigated, including the reaction temperature, reaction time, ratio of the starting material, amount of the Nafion catalyst and the recycle times of the catalyst.展开更多
基金This work was supported by the National Natural Science Foundation of China （Nos. 20962018, 20862015, 20762009 and 20562011）.
文摘Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a novel Zn（II）-thiourea complex has been developed. The remarkable advantages of this reaction are mild reaction conditions, simple workup procedure, high yield of products and the use of ethanol as acceptable solvent.
基金the National Natural Science Foundation of China for financial support(20074032)
文摘p-1, 1, 3, 3-Tetramethylbutylphenol was prepared by the alkylation of the phenol with Nafion catalyst in extremely high yield. Various reaction conditions were investigated, including the reaction temperature, reaction time, ratio of the starting material, amount of the Nafion catalyst and the recycle times of the catalyst.
