粗头直径≥10cm,长度通常≥1m,倾斜度超过45°的死木质残体称为倒木（Harmon et al.,1996）。倒木是森林生态系统的重要组成部分,在森林生态系统中倒木与生产者、消费者、分解者之间都有着密切的营养关系,其结构与功能相互制约,相...粗头直径≥10cm,长度通常≥1m,倾斜度超过45°的死木质残体称为倒木（Harmon et al.,1996）。倒木是森林生态系统的重要组成部分,在森林生态系统中倒木与生产者、消费者、分解者之间都有着密切的营养关系,其结构与功能相互制约,相互影响。倒木对森林中生产者的更新有着不容忽视的作用,为各类植物提供了生境,而且还对森林生态系统的演替起着重要的作用（侯平等,2001）;展开更多
The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic expo...The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen. It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d = 1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism.展开更多
Research on heat and mass flux yielded by modern seafloor hydrothermal activity is very important, because it is involved not only in the base of ocean environment research, but also in the historical evolution of sea...Research on heat and mass flux yielded by modern seafloor hydrothermal activity is very important, because it is involved not only in the base of ocean environment research, but also in the historical evolution of seawater properties. Currently, estimating heat flux is based on the observation data of hydrothermal smokers, low-temperature diffusive flow and mid-ocean ridge mainly. But there are some faults, for example, there is lack of a concurrent conductive item in estimating the heat flux by smokers and the error between the half-space cooling model and the observation data is too large. So, three kinds of methods are applied to re-estimating the heat flux of hydrothermal activity resepectively, corresponding estimation is 97. 359 GW by hydrothermal smoker and diffusive flow, 84.895 GW by hydrothermal plume, and 4. 11 TW by exponential attenuation method put forward by this paper. Research on mass flux estimation is relatively rare, the main reason for this is insufficient field observation data. Mass fluxes of different elements are calculated using hydrothermal vent fluid data from the TAG hydrothermal area on the Mid-Atlantic Ridge for the first time. Difference of estimations by different methods reflects the researching extent of hydrothermal activity, and systematically in - situ observation will help to estimate the contribution of hydrothermal activity to ocean chemical environment, ocean circulation and global climate precisely.展开更多
文摘粗头直径≥10cm,长度通常≥1m,倾斜度超过45°的死木质残体称为倒木（Harmon et al.,1996）。倒木是森林生态系统的重要组成部分,在森林生态系统中倒木与生产者、消费者、分解者之间都有着密切的营养关系,其结构与功能相互制约,相互影响。倒木对森林中生产者的更新有着不容忽视的作用,为各类植物提供了生境,而且还对森林生态系统的演替起着重要的作用（侯平等,2001）;
基金the National Natural Science Foundation of China(No.20274023)key project foundation of National Ministry of Education(No.02114)Guangdong Province Natural Science Foundation of China(No.021241)for supporting this work.
文摘The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen. It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d = 1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism.
基金This study was supported by the Major State Basic Research Program of China under contract No.G2000078503the National Natural Science Foundation of China under contract No.40246024.
文摘Research on heat and mass flux yielded by modern seafloor hydrothermal activity is very important, because it is involved not only in the base of ocean environment research, but also in the historical evolution of seawater properties. Currently, estimating heat flux is based on the observation data of hydrothermal smokers, low-temperature diffusive flow and mid-ocean ridge mainly. But there are some faults, for example, there is lack of a concurrent conductive item in estimating the heat flux by smokers and the error between the half-space cooling model and the observation data is too large. So, three kinds of methods are applied to re-estimating the heat flux of hydrothermal activity resepectively, corresponding estimation is 97. 359 GW by hydrothermal smoker and diffusive flow, 84.895 GW by hydrothermal plume, and 4. 11 TW by exponential attenuation method put forward by this paper. Research on mass flux estimation is relatively rare, the main reason for this is insufficient field observation data. Mass fluxes of different elements are calculated using hydrothermal vent fluid data from the TAG hydrothermal area on the Mid-Atlantic Ridge for the first time. Difference of estimations by different methods reflects the researching extent of hydrothermal activity, and systematically in - situ observation will help to estimate the contribution of hydrothermal activity to ocean chemical environment, ocean circulation and global climate precisely.
