In order to investigate the general reliability assessment methods based on performance degradation data,two commonly used stochastic process approaches,bilinear process method and random-effect model were studied.Ana...In order to investigate the general reliability assessment methods based on performance degradation data,two commonly used stochastic process approaches,bilinear process method and random-effect model were studied.Analyzing procedure and effectiveness of these two methodologies were studied and compared.Meanwhile,the two approaches were illustrated through practical applications.The residual plots and the 10th percentile curves of the two methods were presented to demonstrate the comparative results.The randomeffect model yielded more volatile residuals and a lower and unsafe 10th percentile curve.Consequently the bilinear process model can be concluded to derive more reasonable results due to its one-stage estimation property.展开更多
The results indicate that during charge and discharge, the expansion of Ni（OH）2 crystal, pulverization of MH alloy particles and falling off from current collector are identified as the main causes for deterioration...The results indicate that during charge and discharge, the expansion of Ni（OH）2 crystal, pulverization of MH alloy particles and falling off from current collector are identified as the main causes for deterioration of Ni/MH batteries. Meanwhile, the contact resistance of inner battery increases due to the deterioration of the negative and positive electrode, and these changes lead to increasing battery body temperature and damaging its electrode and separator. The fibre’s expansion and hole’s diminishment of battery’s separator after degradation will affect the electrochemical performance and cycle life of Ni/MH batteries.展开更多
基金National Natural Science Foundation of China(11202011)Beijing Natural Science Foundation(3154034)+1 种基金Fundamental Research Funds for the Central Universities(YWK13HK11)National Basic Research Program of China(2012CB720000)
文摘In order to investigate the general reliability assessment methods based on performance degradation data,two commonly used stochastic process approaches,bilinear process method and random-effect model were studied.Analyzing procedure and effectiveness of these two methodologies were studied and compared.Meanwhile,the two approaches were illustrated through practical applications.The residual plots and the 10th percentile curves of the two methods were presented to demonstrate the comparative results.The randomeffect model yielded more volatile residuals and a lower and unsafe 10th percentile curve.Consequently the bilinear process model can be concluded to derive more reasonable results due to its one-stage estimation property.
文摘The results indicate that during charge and discharge, the expansion of Ni（OH）2 crystal, pulverization of MH alloy particles and falling off from current collector are identified as the main causes for deterioration of Ni/MH batteries. Meanwhile, the contact resistance of inner battery increases due to the deterioration of the negative and positive electrode, and these changes lead to increasing battery body temperature and damaging its electrode and separator. The fibre’s expansion and hole’s diminishment of battery’s separator after degradation will affect the electrochemical performance and cycle life of Ni/MH batteries.
