To save energy and raise molding and coremaking productivity, the synthetic procedure of novolaks for the shell process was investigated. The study indicated that it was difficult to obtain fast curing novolaks under ...To save energy and raise molding and coremaking productivity, the synthetic procedure of novolaks for the shell process was investigated. The study indicated that it was difficult to obtain fast curing novolaks under strongly acidic conditions alone. A novel synthetic procedure was proposed for preparing novolaks in a two-step manner, a divalent metal salt catalyzed novolak preparation followed by a strong acid catalyzed novolak preparation. The optimum conditions for the two-step procedure were determined by orthogonal experiment design. The results showed that it was easy to prepare fast curing novolaks with cure time in the range of 20 s to 30 s and softening point in the range of 80℃ to 90℃ under complex catalysis conditions.展开更多
For detailed study of complex chemical reactions mechanisms experiment is conducted for selected private reactions. This causes a problem of kinetic parameters getting--the same set of rate constants must describe bot...For detailed study of complex chemical reactions mechanisms experiment is conducted for selected private reactions. This causes a problem of kinetic parameters getting--the same set of rate constants must describe both public and private reaction stages, and also a general mechanism. In this paper, solution of this problem for a reaction of olefins hydroalumination is proposed. To optimize the computational process a methodology of parallelization is elaborated. On the base of parallel computations, a kinetic model for the reaction assigned is constructed, and on its base, the physical and chemical conclusions about reaction mechanism are done.展开更多
文摘To save energy and raise molding and coremaking productivity, the synthetic procedure of novolaks for the shell process was investigated. The study indicated that it was difficult to obtain fast curing novolaks under strongly acidic conditions alone. A novel synthetic procedure was proposed for preparing novolaks in a two-step manner, a divalent metal salt catalyzed novolak preparation followed by a strong acid catalyzed novolak preparation. The optimum conditions for the two-step procedure were determined by orthogonal experiment design. The results showed that it was easy to prepare fast curing novolaks with cure time in the range of 20 s to 30 s and softening point in the range of 80℃ to 90℃ under complex catalysis conditions.
文摘For detailed study of complex chemical reactions mechanisms experiment is conducted for selected private reactions. This causes a problem of kinetic parameters getting--the same set of rate constants must describe both public and private reaction stages, and also a general mechanism. In this paper, solution of this problem for a reaction of olefins hydroalumination is proposed. To optimize the computational process a methodology of parallelization is elaborated. On the base of parallel computations, a kinetic model for the reaction assigned is constructed, and on its base, the physical and chemical conclusions about reaction mechanism are done.
