FELiChEM is an infrared free electron laser（FEL） facility currently under construction, which consists of two oscillators generating middle-infrared and far-infrared laser covering the spectral range of 2.5–200 μm...FELiChEM is an infrared free electron laser（FEL） facility currently under construction, which consists of two oscillators generating middle-infrared and far-infrared laser covering the spectral range of 2.5–200 μm. In this paper, we numerically study the output characteristics of the middle-infrared oscillator with accurate cavity length detuning. Emphasis is put on the temporal structure of the micropulse and the corresponding spectral bandwidth.Taking the radiation wavelengths of 50 μm and 5 μm as examples, we show that the output pulse duration can be tuned in the range of 1–6 ps with corresponding bandwidth of 13%–0.2% by adjusting the cavity length detuning.In addition, a special discussion on the comb structure is presented, and it is indicated that the comb structure may arise in the output optical pulse when the normalized slippage length is much smaller than unity. This work has reference value for the operation of FELiChEM and other FEL oscillators.展开更多
采用原子转移自由基聚合(ATRP)法聚合甲基烯丙基聚氧乙烯醚(HPEG)和丙烯酸甲酯(PMA),生成低分子量梳形结构的低聚物HPEG/PMA.经Fourier红外光谱(FT-IR)和核磁共振氢谱(1 H NMR)对其结构特征基团进行分析,确认合成了目标产物.对HPEG/PMA...采用原子转移自由基聚合(ATRP)法聚合甲基烯丙基聚氧乙烯醚(HPEG)和丙烯酸甲酯(PMA),生成低分子量梳形结构的低聚物HPEG/PMA.经Fourier红外光谱(FT-IR)和核磁共振氢谱(1 H NMR)对其结构特征基团进行分析,确认合成了目标产物.对HPEG/PMA进行凝胶渗透色谱(GPC)测试,结果表明,ATRP法制备的梳形HPEG/PMA分子量为7.7×103,分布系数为1.11,具有优异的可控性.梳形HPEG/PMA经V(乙醇)∶V(水)=1的NaOH溶液水解,得到梳形结构甲基烯丙基聚氧乙烯醚和丙烯酸(HPEG/PAA)低聚物.展开更多
Poly (oligoether methacrylate-co-acrylonitrile) s, P (MEOn- AN), with oligoether pendants of different lengths were synthesized and the ion conduction property of their Li-salt complexes was studied as the function of...Poly (oligoether methacrylate-co-acrylonitrile) s, P (MEOn- AN), with oligoether pendants of different lengths were synthesized and the ion conduction property of their Li-salt complexes was studied as the function of polymer structure. At proper copolymer composition, lithium concentration and pendant length, the ion conductivity reaches 7.0×10^(-5)S/cm at ambient temperature, together with improved mechanical strength. The ion transport in the polymer media is assisted by segmental relaxation, which is confirmed both by the consistency between ion conductivity and T_g and by the study of TSC.展开更多
A MEMS compressed period-tunable grating device with a wide tuning range has been designed, fabricated and characterized. To increase the tuning range, avoid instability with tuning and improve the performance, we pro...A MEMS compressed period-tunable grating device with a wide tuning range has been designed, fabricated and characterized. To increase the tuning range, avoid instability with tuning and improve the performance, we propose in this paper a period-tunable grating which is compressed by large-displacement comb actuators with tilted folded beams. The experimental results show that the designed grating device has a compression range of up to 144μm within 37 V driving voltage. The period of the grating can be adjusted continuously from 16 to 14 μm with a tuning range of 12.5%. The maximum tuning range of the first-order diffraction angle is 0.34° at 632.8 nm and the reflectivity of the grating is more than 92.6% in the mid-infrared region. The grating device can be fabricated by simple processes and finds applications in mid-infrared spectrometers.展开更多
基金Supported by National Natural Science Foundation of China(21327901,11205156)
文摘FELiChEM is an infrared free electron laser（FEL） facility currently under construction, which consists of two oscillators generating middle-infrared and far-infrared laser covering the spectral range of 2.5–200 μm. In this paper, we numerically study the output characteristics of the middle-infrared oscillator with accurate cavity length detuning. Emphasis is put on the temporal structure of the micropulse and the corresponding spectral bandwidth.Taking the radiation wavelengths of 50 μm and 5 μm as examples, we show that the output pulse duration can be tuned in the range of 1–6 ps with corresponding bandwidth of 13%–0.2% by adjusting the cavity length detuning.In addition, a special discussion on the comb structure is presented, and it is indicated that the comb structure may arise in the output optical pulse when the normalized slippage length is much smaller than unity. This work has reference value for the operation of FELiChEM and other FEL oscillators.
文摘采用原子转移自由基聚合(ATRP)法聚合甲基烯丙基聚氧乙烯醚(HPEG)和丙烯酸甲酯(PMA),生成低分子量梳形结构的低聚物HPEG/PMA.经Fourier红外光谱(FT-IR)和核磁共振氢谱(1 H NMR)对其结构特征基团进行分析,确认合成了目标产物.对HPEG/PMA进行凝胶渗透色谱(GPC)测试,结果表明,ATRP法制备的梳形HPEG/PMA分子量为7.7×103,分布系数为1.11,具有优异的可控性.梳形HPEG/PMA经V(乙醇)∶V(水)=1的NaOH溶液水解,得到梳形结构甲基烯丙基聚氧乙烯醚和丙烯酸(HPEG/PAA)低聚物.
文摘Poly (oligoether methacrylate-co-acrylonitrile) s, P (MEOn- AN), with oligoether pendants of different lengths were synthesized and the ion conduction property of their Li-salt complexes was studied as the function of polymer structure. At proper copolymer composition, lithium concentration and pendant length, the ion conductivity reaches 7.0×10^(-5)S/cm at ambient temperature, together with improved mechanical strength. The ion transport in the polymer media is assisted by segmental relaxation, which is confirmed both by the consistency between ion conductivity and T_g and by the study of TSC.
基金Project supported by the State Key Development Program for Basic Research of China(No.2006CB30040)
文摘A MEMS compressed period-tunable grating device with a wide tuning range has been designed, fabricated and characterized. To increase the tuning range, avoid instability with tuning and improve the performance, we propose in this paper a period-tunable grating which is compressed by large-displacement comb actuators with tilted folded beams. The experimental results show that the designed grating device has a compression range of up to 144μm within 37 V driving voltage. The period of the grating can be adjusted continuously from 16 to 14 μm with a tuning range of 12.5%. The maximum tuning range of the first-order diffraction angle is 0.34° at 632.8 nm and the reflectivity of the grating is more than 92.6% in the mid-infrared region. The grating device can be fabricated by simple processes and finds applications in mid-infrared spectrometers.
