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氨改性介孔SiO_2用于CO_2/N_2变压吸附分离
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作者 胡智辉 聂新宇 +1 位作者 王纪孝 张东辉 《天津大学学报》 EI CAS CSCD 北大核心 2012年第11期1020-1023,共4页
在323.15,K下,以月桂酸为结构导向剂(SDA)、γ-氨丙基三乙氧基硅烷为助结构导向剂和硅酸乙酯为硅源,采用阴离子表面活性剂法直接合成氨改性介孔SiO2(AMS)用于CO2/N2变压吸附分离.对样品进行低温N2吸附脱附、X射线衍射(XRD)和透射电镜(T... 在323.15,K下,以月桂酸为结构导向剂(SDA)、γ-氨丙基三乙氧基硅烷为助结构导向剂和硅酸乙酯为硅源,采用阴离子表面活性剂法直接合成氨改性介孔SiO2(AMS)用于CO2/N2变压吸附分离.对样品进行低温N2吸附脱附、X射线衍射(XRD)和透射电镜(TEM)表征,然后用动态法测量其CO2、N2穿透曲线并计算吸附量.结果发现,在323.15,K、常压下合成吸附剂AMS对CO2/N2的吸附量分别为0.60,mmol/g和0.03,mmol/g.采用抽真空的方法对吸附剂进行再生,发现75%以上的吸附态CO2能够解吸,经过多次吸附/解吸循环CO2吸附特性不变.同时利用Aspen adsim软件对吸附过程进行模拟,模拟结果与实验数据吻合良好. 展开更多
关键词 氨改性介孔SiO2 CO2吸附 N2吸附 分离 ASPEN adsim
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Recycle Adsorption of Cu2+ on Amine-functionalized Mesoporous Silica Monolithic 被引量:1
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作者 ZHAO Da-zhou JING Shu-bo XU Jia-ning YANG Hong ZHENG Wei SONG Tian-you ZHANG Ping 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2013年第4期793-797,共5页
3-Aminopropyltriethoxysilane functionalized worm-like mesoporous silica monolithic(WMSM-NH2) was prepared and used as a new regenerable adsorbent for the removal of Cu2+ ions. The analysis results show that the WMS... 3-Aminopropyltriethoxysilane functionalized worm-like mesoporous silica monolithic(WMSM-NH2) was prepared and used as a new regenerable adsorbent for the removal of Cu2+ ions. The analysis results show that the WMSM-NH2 monolithic had a high efficiency value of 99.3% for Cu2+ remediation when the Cu2+ solution was at an initial concentration of 10.32 mg/L. The regeneration study of the WMSM-NH2 monolithic presented that the adsorp- tion efficiency of 89.0% was remained and a mass of 92.0% was left after seven adsorption-desorption cycles were executed. The monolithic material with high resistance to the acid and good mechanical stability can facilitate the operations of adsorption and regeneration of the adsorbent. 展开更多
关键词 amine-functionalized mesoporous silica monolithic(WMSM-NH2) Cu2+ removal Multiple cycle Adsorp- tion Easy operation
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