Rational design and exploration of low-cost and robust bifunctional oxygen electrocatalysts are vitally important for developing high-performance zinc-air batteries(ZABs).Herein,we reported a facile yet cost-efficient...Rational design and exploration of low-cost and robust bifunctional oxygen electrocatalysts are vitally important for developing high-performance zinc-air batteries(ZABs).Herein,we reported a facile yet cost-efficient approach to construct a bifunctional oxygen reduction reaction(ORR)/oxygen evolution reaction(OER)electrocatalyst composed of N-doped porous carbon nanosheet flowers decorated with Fe Co nanoparticles(Fe Co/N-CF).Rational design of this catalyst is achieved by designing Schiff-base polymer with unique molecular structure via hydrogen bonding of cyanuramide and terephthalaldehyde polycondensate in the presence of metal cations.It exhibits excellent activity and stability for electrocatalysis of ORR/OER,enabling ZAB with a high peak power density of 172 m W cm^(-2)and a large specific capacity of 811 m A h g^(-1)Znat large current.The rechargeable ZAB demonstrates excellent durability for 1000 h with slight voltage decay,far outperforming a couple of precious Pt/Ir-based catalysts.Density functional theory(DFT)calculations reveal that high activity of bimetallic Fe Co stems from enhanced O_(2)and OH-adsorption and accelerated O_(2)dissociation by OAO bond activation.展开更多
Background Nineteen undulators of various types are being fabricated for high-energy photon source(HEPS).In order to ensure the optical performance of the undulators,the girder deformation is usually carefully optimiz...Background Nineteen undulators of various types are being fabricated for high-energy photon source(HEPS).In order to ensure the optical performance of the undulators,the girder deformation is usually carefully optimized during the structural design stage.Purpose Optimization of magnet girder deformation is one of the key points to ensure undulator magneticfield performance.To reduce magnet girder deformation,base plate,feet and strong back should be designed carefully.In the HEPS undulator design and manufacturing stage,it is found that under special circumstances,such as after the height of the feet is adjusted,or after the undulator is lifted to other place,the base plate and girder may deform more than expected.Methods Therefore based on ANSYS simulation and experimental test results,the factors causing the deformation of the girders are carefully analyzed.Base plate and feet were optimized for different types of undulators to avoid girder deformation.Related simulation and laser tracker measurement were performed tofind out the reason in this paper.Results and conclusion Results show that the base plate of C-frame undulators will collapse and deform under the action of magnetic force.Asymmetric sagged base plate is the main reason of girder deformation.Increasing the thickness of the base plate and increasing the number of feet can both reduce that deformation.Optimization of magnet girder deformation is one of the key points to ensure undulator magneticfield performance.To reduce magnet girder deformation,base plate,feet and strong back should be designed carefully.展开更多
The knowledge representation mode and inference control strategy were analyzed according to the specialties of air-conditioning cooling/heating sources selection. The constructing idea and working procedure for knowle...The knowledge representation mode and inference control strategy were analyzed according to the specialties of air-conditioning cooling/heating sources selection. The constructing idea and working procedure for knowledge base and inference engine were proposed while the realization technique of the C language was discussed. An intelligent decision support system (IDSS) model based on such knowledge representation and inference mechanism was developed by domain engineers. The model was verified to have a small kernel and powerful capability in list processing and data driving, which was successfully used in the design of a cooling/heating sources system for a large-sized office building.展开更多
基金supported by the National Science Foundation of China(21805235)the Opening Foundation of Creative Platform of the Key Laboratory of the Education Department of Hunan Province(20K131)the Construct Program of the Key Discipline in Hunan Province。
文摘Rational design and exploration of low-cost and robust bifunctional oxygen electrocatalysts are vitally important for developing high-performance zinc-air batteries(ZABs).Herein,we reported a facile yet cost-efficient approach to construct a bifunctional oxygen reduction reaction(ORR)/oxygen evolution reaction(OER)electrocatalyst composed of N-doped porous carbon nanosheet flowers decorated with Fe Co nanoparticles(Fe Co/N-CF).Rational design of this catalyst is achieved by designing Schiff-base polymer with unique molecular structure via hydrogen bonding of cyanuramide and terephthalaldehyde polycondensate in the presence of metal cations.It exhibits excellent activity and stability for electrocatalysis of ORR/OER,enabling ZAB with a high peak power density of 172 m W cm^(-2)and a large specific capacity of 811 m A h g^(-1)Znat large current.The rechargeable ZAB demonstrates excellent durability for 1000 h with slight voltage decay,far outperforming a couple of precious Pt/Ir-based catalysts.Density functional theory(DFT)calculations reveal that high activity of bimetallic Fe Co stems from enhanced O_(2)and OH-adsorption and accelerated O_(2)dissociation by OAO bond activation.
文摘Background Nineteen undulators of various types are being fabricated for high-energy photon source(HEPS).In order to ensure the optical performance of the undulators,the girder deformation is usually carefully optimized during the structural design stage.Purpose Optimization of magnet girder deformation is one of the key points to ensure undulator magneticfield performance.To reduce magnet girder deformation,base plate,feet and strong back should be designed carefully.In the HEPS undulator design and manufacturing stage,it is found that under special circumstances,such as after the height of the feet is adjusted,or after the undulator is lifted to other place,the base plate and girder may deform more than expected.Methods Therefore based on ANSYS simulation and experimental test results,the factors causing the deformation of the girders are carefully analyzed.Base plate and feet were optimized for different types of undulators to avoid girder deformation.Related simulation and laser tracker measurement were performed tofind out the reason in this paper.Results and conclusion Results show that the base plate of C-frame undulators will collapse and deform under the action of magnetic force.Asymmetric sagged base plate is the main reason of girder deformation.Increasing the thickness of the base plate and increasing the number of feet can both reduce that deformation.Optimization of magnet girder deformation is one of the key points to ensure undulator magneticfield performance.To reduce magnet girder deformation,base plate,feet and strong back should be designed carefully.
文摘The knowledge representation mode and inference control strategy were analyzed according to the specialties of air-conditioning cooling/heating sources selection. The constructing idea and working procedure for knowledge base and inference engine were proposed while the realization technique of the C language was discussed. An intelligent decision support system (IDSS) model based on such knowledge representation and inference mechanism was developed by domain engineers. The model was verified to have a small kernel and powerful capability in list processing and data driving, which was successfully used in the design of a cooling/heating sources system for a large-sized office building.
