Using viscose fiber (VF) as starting material and common steam as activating agent, formation of oxygen structures in activated carbon fiber is investigated. In the preparation of samples, VF was first heated at tempe...Using viscose fiber (VF) as starting material and common steam as activating agent, formation of oxygen structures in activated carbon fiber is investigated. In the preparation of samples, VF was first heated at temperatures between 450℃ and 900℃ in N_2 artmosphere. Then, in a successive activation stage, the product carbonized at 600℃ was activated in steam at 450-900℃ for 30 min, and at 600℃ for 5-30 min. The other carbonization products were activated at 600 and 900℃ for 30 min respectively. The products activated at 900℃ were then activated at 450℃ for 30 min again. The starting materiah carbonized products and all activation products were examined by FT-IR spectroscopy and some products were examined by X-ray photoelectron spectroscope (XPS). And the yields of the carbonized and activated products were calculated. By analysing these spectra, the amount of oxygen-containing functional groups of the activated products attained under various activation time, various activation temperature and various previous carbonization temperature was determined.展开更多
In this research, the flame retardancy of neat alginate fiber, flame retardant viscose fiber （FRV） and alginate/FRV （50/50） blending fibers were investigated by vertical burning and cone calorimeter tests. The ver...In this research, the flame retardancy of neat alginate fiber, flame retardant viscose fiber （FRV） and alginate/FRV （50/50） blending fibers were investigated by vertical burning and cone calorimeter tests. The vertical burning test showed that the afterflame time of alginate fiber was 0 s, but alginate presented serious smoldering behavior with the afterglow time of 605 s and damaged length of 85 mm, while the afterglow time of FRV was 0 s. When the FRV was incorporated into alginate with the weight ratio of 50/ 50, the afterglow time and damaged length were significantly reduced to 85 s and 35 mm, indicating the smoldering of alginate can be effectively decreased. The morphology and chemical structure of the alginate residual demonstrated that it was seriously destroyed during smoldering process, which was ascribed to its relative low initial thermal degradation temperature. Based on the thermal properties analysis, alginate and FRV fibers shared the concurrence of rapid degradation in the same temperature region of 250-300 ℃, through which, the compact and stable char formed by FRV can prevent the heat transmission and suppress the smoldering of alginate. Further, the cone calorimeter results demonstrated that the time to ignition （TTI） significantly increased and peak heat release rate （PHRR） decreased for alginate/FRV （50/50） compared with FRV. With this research, a new method to overcome the smoldering of alginate was proposed by blending with FRV展开更多
文摘Using viscose fiber (VF) as starting material and common steam as activating agent, formation of oxygen structures in activated carbon fiber is investigated. In the preparation of samples, VF was first heated at temperatures between 450℃ and 900℃ in N_2 artmosphere. Then, in a successive activation stage, the product carbonized at 600℃ was activated in steam at 450-900℃ for 30 min, and at 600℃ for 5-30 min. The other carbonization products were activated at 600 and 900℃ for 30 min respectively. The products activated at 900℃ were then activated at 450℃ for 30 min again. The starting materiah carbonized products and all activation products were examined by FT-IR spectroscopy and some products were examined by X-ray photoelectron spectroscope (XPS). And the yields of the carbonized and activated products were calculated. By analysing these spectra, the amount of oxygen-containing functional groups of the activated products attained under various activation time, various activation temperature and various previous carbonization temperature was determined.
基金supported by the Fundamental Research Funds for the Central Universities(No. CUSF-DH-D2016012)
文摘In this research, the flame retardancy of neat alginate fiber, flame retardant viscose fiber （FRV） and alginate/FRV （50/50） blending fibers were investigated by vertical burning and cone calorimeter tests. The vertical burning test showed that the afterflame time of alginate fiber was 0 s, but alginate presented serious smoldering behavior with the afterglow time of 605 s and damaged length of 85 mm, while the afterglow time of FRV was 0 s. When the FRV was incorporated into alginate with the weight ratio of 50/ 50, the afterglow time and damaged length were significantly reduced to 85 s and 35 mm, indicating the smoldering of alginate can be effectively decreased. The morphology and chemical structure of the alginate residual demonstrated that it was seriously destroyed during smoldering process, which was ascribed to its relative low initial thermal degradation temperature. Based on the thermal properties analysis, alginate and FRV fibers shared the concurrence of rapid degradation in the same temperature region of 250-300 ℃, through which, the compact and stable char formed by FRV can prevent the heat transmission and suppress the smoldering of alginate. Further, the cone calorimeter results demonstrated that the time to ignition （TTI） significantly increased and peak heat release rate （PHRR） decreased for alginate/FRV （50/50） compared with FRV. With this research, a new method to overcome the smoldering of alginate was proposed by blending with FRV
