We have systematically investigated the microstructures of as-cast Mg_(97.49)Ho_(1.99)Cu_(0.43)Zr_(0.09)alloy by atomic resolution high-angle annular dark field scanning transmission electron microscopy(HAADF-STEM), r...We have systematically investigated the microstructures of as-cast Mg_(97.49)Ho_(1.99)Cu_(0.43)Zr_(0.09)alloy by atomic resolution high-angle annular dark field scanning transmission electron microscopy(HAADF-STEM), revealing the coexistence of 18R, 14H and 24R long period stacking/order(LPSO) phases with fully coherent interfaces along step-like composition gradient in a blocky intermetallic compound distributed at grain boundary. The short-range order(SRO) L1_(2)-type Cu_(6)Ho_(8)clusters embedded across AB’C’A-stacking fault layers are directly revealed at atomic scale. Importantly, the order degree of SRO clusters in the present dilute alloy is significant lower than previous 6M and 7M in-plane order reported in ternary Mg-TM(transition metal)-RE(rare earth) alloys, which can be well matched by 9M in-plane order. This directly demonstrates that SRO in-plane L1_(2)-type clusters can be expanded into more dilute composition regions bounded along the definite TM/RE ratio of 3/4. In addition, the estimated chemical compositions of solute enriched stacking fault(SESF) in all LPSO variants are almost identical with the ideal SESF composition of 9M in-plane order, regardless of the type of LPSO phases. The results further support the viewpoint that robust L1_(2)-type TM_(6)RE_(8)clusters play an important role in governing LPSO phase formation.展开更多
A long-range sound propagation experiment was conducted in the West Pacific Ocean in July 2013. Linear frequency-modulated signals with a frequency band of 260-360Hz were transmitted by a transducer hung on a floating...A long-range sound propagation experiment was conducted in the West Pacific Ocean in July 2013. Linear frequency-modulated signals with a frequency band of 260-360Hz were transmitted by a transducer hung on a floating ship during the experiment and were received by a horizontal line array towed by another ship sailing away from the transducer. The maximum distance between the two ships was 1029km. Signals were received at the distances 34-220 kin, 612-635 km and 926-1029 kin. Transmission loss versus distance between source and receiver was obtained and compared with the theoretical results predicted by the parabolic equation method program RAM. It is shown that RAM is adequate for estimating the transmission loss for distances up to 1029km. When the water depth is larger than the surface conjugate depth, the ocean bottom rarely influences the transmission loss in the convergence zones. However, in the opposite situation, the ocean bottom contributes significantly to the transmission loss.展开更多
基金supported by JSPS KAKENHI for Scientific Research on Innovative Areas “Materials Science of a Millefeuille Structure (Grant Nos. JP18H05475, JP18H05479)”“Nanotechnology Platform” of the MEXT, Japan+1 种基金supported by Grant-in-Aid for JSPS Fellows (JP19F19775)the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization (RERU2020012)。
文摘We have systematically investigated the microstructures of as-cast Mg_(97.49)Ho_(1.99)Cu_(0.43)Zr_(0.09)alloy by atomic resolution high-angle annular dark field scanning transmission electron microscopy(HAADF-STEM), revealing the coexistence of 18R, 14H and 24R long period stacking/order(LPSO) phases with fully coherent interfaces along step-like composition gradient in a blocky intermetallic compound distributed at grain boundary. The short-range order(SRO) L1_(2)-type Cu_(6)Ho_(8)clusters embedded across AB’C’A-stacking fault layers are directly revealed at atomic scale. Importantly, the order degree of SRO clusters in the present dilute alloy is significant lower than previous 6M and 7M in-plane order reported in ternary Mg-TM(transition metal)-RE(rare earth) alloys, which can be well matched by 9M in-plane order. This directly demonstrates that SRO in-plane L1_(2)-type clusters can be expanded into more dilute composition regions bounded along the definite TM/RE ratio of 3/4. In addition, the estimated chemical compositions of solute enriched stacking fault(SESF) in all LPSO variants are almost identical with the ideal SESF composition of 9M in-plane order, regardless of the type of LPSO phases. The results further support the viewpoint that robust L1_(2)-type TM_(6)RE_(8)clusters play an important role in governing LPSO phase formation.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11174312 and 11434012the Public Science and Technology Research Project of Ocean under Grant No 201405032
文摘A long-range sound propagation experiment was conducted in the West Pacific Ocean in July 2013. Linear frequency-modulated signals with a frequency band of 260-360Hz were transmitted by a transducer hung on a floating ship during the experiment and were received by a horizontal line array towed by another ship sailing away from the transducer. The maximum distance between the two ships was 1029km. Signals were received at the distances 34-220 kin, 612-635 km and 926-1029 kin. Transmission loss versus distance between source and receiver was obtained and compared with the theoretical results predicted by the parabolic equation method program RAM. It is shown that RAM is adequate for estimating the transmission loss for distances up to 1029km. When the water depth is larger than the surface conjugate depth, the ocean bottom rarely influences the transmission loss in the convergence zones. However, in the opposite situation, the ocean bottom contributes significantly to the transmission loss.
