A white long-lasting phosphor Ca2MgSi2O7:Dy3+ was prepared by the solid-state reaction. A strong band peaked at 260 nm was shown in the excitation spectrum of 578 nm emission, which might be attributed to the oxygen d...A white long-lasting phosphor Ca2MgSi2O7:Dy3+ was prepared by the solid-state reaction. A strong band peaked at 260 nm was shown in the excitation spectrum of 578 nm emission, which might be attributed to the oxygen deficiency of the host. After irradiated with 254 nm for 4 min, the white afterglow of the sample could be seen for 3 h. Moreover, the depths and frequency factors of trap centers were calculated from the thermo-luminescence curve of the sample, which indicated that the trap centers corresponding to the 414 K band were more helpful to the long-lasting phosphorescence.展开更多
The mainly characteristic of trapping materials is the trap depth. So it is significant to calculate the trap depth for the trapping materials. A new method of calculating trap depth, which is based on energy band and...The mainly characteristic of trapping materials is the trap depth. So it is significant to calculate the trap depth for the trapping materials. A new method of calculating trap depth, which is based on energy band and using rate equations to analyze thermoluminescence, was brought forward. This method which uses the rate equations of the process and the thermoluminescence curve can replace traditional methods such as first order or second order kinetics. The trap depth of SrAl2O4：Eu^2＋ , Dy^3＋ and Sr4Al14O25：Eu^2＋ , Dy^3＋ was estimated from the glow curve. Then the numerical solution of the trap depth can be obtained. From the results of experiments and calculations, this method can accurately indicate the whole process.展开更多
The polycrystalline Eu^2＋ and Dy ^3＋ co-doped strontium aluminates SrAl2O4： Eu^2＋, Dy^3＋ with different compositions were prepared by solid state reactions. The UV-excited photoluminescence, persistent luminescen...The polycrystalline Eu^2＋ and Dy ^3＋ co-doped strontium aluminates SrAl2O4： Eu^2＋, Dy^3＋ with different compositions were prepared by solid state reactions. The UV-excited photoluminescence, persistent luminescence and thermo-luminescence were studied and compared. Results show that the doped Eu^2＋ ion in SrAl2O4： Eu^2＋, Dy^3＋ phosphors works as not only the UV-excited luminescent center but also the persistent luminescent center. The doped Dy^3＋ ion can hardly yield any luminescence under UV-excitation, but effectively enhance the persistent luminescence and thermo-luminescence of SrAl2O4： Eu^2＋. Dy^3＋ co-doping can help form electron traps with appropriate depth due to its suitable electro-negativity, and increase the density and depth of electron traps. Based on above observations, a persistent luminescence mechanism, electron transfer model, is proposed and illustrated.展开更多
Much important information referring to fault motion （e.g., fault activities period, intensity, frequency, and even dynamic background） can be revealed by resolving fault gouge, which is the result of fault motion w...Much important information referring to fault motion （e.g., fault activities period, intensity, frequency, and even dynamic background） can be revealed by resolving fault gouge, which is the result of fault motion while extruding or grinding. The field investigation encompassed sample collecting from the Bailong River fault system of the western segment of the Qinling Orogenic Belt （QOB）; 44 samples of fault gouges were collected for quartz micro-morphology analysis. These samples were analyzed using field emission scanning electron microscopy. In addition, 14 samples were tested for thermo-luminescence dating. The results showed that most of the surface textures of quartz grains are characterized by fish scale, moss-like texture, and stalactite. However, a small amount of orange peel-like fractures and worm-hole-like shaped surface texture were observed. Moreover, a few typical conchoids or subconchoidal fractures in quartz grains can be seen. This implies that the Bailong River Fault was active repeatedly during the Quaternary period, but the main motion period is the Pleistocene. The 14 thermo-luminescence dating values showed two age groups： 343.29-184.06 ka and 92.18-13.87 ka. These study data reveal that fault movement started during the Pliocene, occurred frequently in the early-middle period of the Pleistocene, and the peak frequency of the motion was reached in the early Pleistocene. The fault motions were stopped terminated in the early Holocene. The results are significant for the natural disaster risk evaluation in the western segment of the QOB.展开更多
The KCI：Eu2＋ system response to UV-C was investigated by analyzing the optically stimulated luminescence （OSL） and ther- mo-luminescence （TL） signal produced by ultraviolet light exposure at room temperature. It...The KCI：Eu2＋ system response to UV-C was investigated by analyzing the optically stimulated luminescence （OSL） and ther- mo-luminescence （TL） signal produced by ultraviolet light exposure at room temperature. It was found that after UV-C irra.diation, OSL was produced on a wide band of visible wavelengths with decay time that varied by several orders of magnitude depending on the Eu2＋ aggregation state. In spite of the low intensity of solar UV-C reaching the Earth＇s surface in Madrid （40° N, 700 m a.s.1.）, it was possible to measure the UV-C radiation dose at 6：48 solar time by using the TL response of the KCI：Eu2＋ system and differentiate it from the ambient beta radiation dose.展开更多
Thermo-luminescence （TL） is a kind of luminescence decay measured with varying temperature. In the process of TL the decay parameter itself involves the temperature effect of traps. Thus the trap depth is inseparabl...Thermo-luminescence （TL） is a kind of luminescence decay measured with varying temperature. In the process of TL the decay parameter itself involves the temperature effect of traps. Thus the trap depth is inseparable from the decay parameter. There are two separate peaks in the TL curve of ZnS：Cu,Co if the measurement starts from liquid nitrogen temperature. In the experiment we started from zero Celsius temperature to isolate the deeper traps. We have proposed and realized three methods for simultaneous determination of trap depth and decay parameter based on the quasi-equilibrium model and experimental data. If we treat the case of kinetic order a = 1 as a = 2, the error might be as large as 100%.展开更多
The ZnO and Zn1-xMnxO minicrystal were synthesized by chemical vapor transport (CVT). The electron trap structure (donor level) and process on the temporal behavior of photoelectrons of materials were respectively stu...The ZnO and Zn1-xMnxO minicrystal were synthesized by chemical vapor transport (CVT). The electron trap structure (donor level) and process on the temporal behavior of photoelectrons of materials were respectively studied by thermo-luminescence and microwave absorption dielectric spectrometry. There are two peaks in the thermo-luminescence spectra in pure ZnO, one is -183 ℃ and the other is -127 ℃, which shows two kinds of electron trap energy level produced by the intrinsic defects in ZnO;but obtain very low thermo-luminescence that only equals to ten percent of pure ZnO in Zn1-xMnxO, which shows that its intensity of electron trap is less. The studies of microwave absorption dielectric spectrometry show that conduction band photoelectrons are two-step exponential decay process in ZnO, the lifetime of rapid process is 83 ns, while slow process is 828 ns, the reason of delay is relaxation effects of electron trap to conduction band photoelectrons. The intensity of electron trap is less in Zn1-xMnxO minicrystal, the relaxation effects of conduction band photoelectrons from electron trap is little, so electrons disappeared quickly at conduction band, and the decay process of photoelectrons is only 10～20 ns.展开更多
基金Project supported by the Young Scientists' Innovation Foundation of Fujian Province (2007F3027)the Natural Science Foundation of Fujian Province of China (A0510014)+2 种基金the Science Foundation of the Department of Science and Technology of Fujian Province of China (2006F5025)the Science Foundation of the Educational Department of Fujian Province of China (JB08063)the Special Science Foundation for Key Research of Fujian Province (2007HJ0004-2)
文摘A white long-lasting phosphor Ca2MgSi2O7:Dy3+ was prepared by the solid-state reaction. A strong band peaked at 260 nm was shown in the excitation spectrum of 578 nm emission, which might be attributed to the oxygen deficiency of the host. After irradiated with 254 nm for 4 min, the white afterglow of the sample could be seen for 3 h. Moreover, the depths and frequency factors of trap centers were calculated from the thermo-luminescence curve of the sample, which indicated that the trap centers corresponding to the 414 K band were more helpful to the long-lasting phosphorescence.
文摘The mainly characteristic of trapping materials is the trap depth. So it is significant to calculate the trap depth for the trapping materials. A new method of calculating trap depth, which is based on energy band and using rate equations to analyze thermoluminescence, was brought forward. This method which uses the rate equations of the process and the thermoluminescence curve can replace traditional methods such as first order or second order kinetics. The trap depth of SrAl2O4：Eu^2＋ , Dy^3＋ and Sr4Al14O25：Eu^2＋ , Dy^3＋ was estimated from the glow curve. Then the numerical solution of the trap depth can be obtained. From the results of experiments and calculations, this method can accurately indicate the whole process.
基金Jiangxi University of Finance and Economy and Jiangxi Provin-cial Department of Education (No.[2007]260)
文摘The polycrystalline Eu^2＋ and Dy ^3＋ co-doped strontium aluminates SrAl2O4： Eu^2＋, Dy^3＋ with different compositions were prepared by solid state reactions. The UV-excited photoluminescence, persistent luminescence and thermo-luminescence were studied and compared. Results show that the doped Eu^2＋ ion in SrAl2O4： Eu^2＋, Dy^3＋ phosphors works as not only the UV-excited luminescent center but also the persistent luminescent center. The doped Dy^3＋ ion can hardly yield any luminescence under UV-excitation, but effectively enhance the persistent luminescence and thermo-luminescence of SrAl2O4： Eu^2＋. Dy^3＋ co-doping can help form electron traps with appropriate depth due to its suitable electro-negativity, and increase the density and depth of electron traps. Based on above observations, a persistent luminescence mechanism, electron transfer model, is proposed and illustrated.
基金granted by Geological Survey Project(Grant No.1212011120072)the Project of the National Key Technology R&D Program(Grant No.2011BAK12B09)the Project of the National Natural Science Foundation of China(Grant No.41072269)
文摘Much important information referring to fault motion （e.g., fault activities period, intensity, frequency, and even dynamic background） can be revealed by resolving fault gouge, which is the result of fault motion while extruding or grinding. The field investigation encompassed sample collecting from the Bailong River fault system of the western segment of the Qinling Orogenic Belt （QOB）; 44 samples of fault gouges were collected for quartz micro-morphology analysis. These samples were analyzed using field emission scanning electron microscopy. In addition, 14 samples were tested for thermo-luminescence dating. The results showed that most of the surface textures of quartz grains are characterized by fish scale, moss-like texture, and stalactite. However, a small amount of orange peel-like fractures and worm-hole-like shaped surface texture were observed. Moreover, a few typical conchoids or subconchoidal fractures in quartz grains can be seen. This implies that the Bailong River Fault was active repeatedly during the Quaternary period, but the main motion period is the Pleistocene. The 14 thermo-luminescence dating values showed two age groups： 343.29-184.06 ka and 92.18-13.87 ka. These study data reveal that fault movement started during the Pliocene, occurred frequently in the early-middle period of the Pleistocene, and the peak frequency of the motion was reached in the early Pleistocene. The fault motions were stopped terminated in the early Holocene. The results are significant for the natural disaster risk evaluation in the western segment of the QOB.
文摘The KCI：Eu2＋ system response to UV-C was investigated by analyzing the optically stimulated luminescence （OSL） and ther- mo-luminescence （TL） signal produced by ultraviolet light exposure at room temperature. It was found that after UV-C irra.diation, OSL was produced on a wide band of visible wavelengths with decay time that varied by several orders of magnitude depending on the Eu2＋ aggregation state. In spite of the low intensity of solar UV-C reaching the Earth＇s surface in Madrid （40° N, 700 m a.s.1.）, it was possible to measure the UV-C radiation dose at 6：48 solar time by using the TL response of the KCI：Eu2＋ system and differentiate it from the ambient beta radiation dose.
基金Project supported by the National Natural Science Foundation of China （Grant Nos 10374001, 10434030 and 60576016）, the State Key Development Program for Basic Research of China （Grant No 2003CB314707）, the Excellent Doctor＇s Science and Technology Innovation Foundation of Beijing Jiaotong University （Grant No 48011）, Russian Foundation of Basic Research （Grant Nos 04-02- 16942 and 02-02-39007）.
文摘Thermo-luminescence （TL） is a kind of luminescence decay measured with varying temperature. In the process of TL the decay parameter itself involves the temperature effect of traps. Thus the trap depth is inseparable from the decay parameter. There are two separate peaks in the TL curve of ZnS：Cu,Co if the measurement starts from liquid nitrogen temperature. In the experiment we started from zero Celsius temperature to isolate the deeper traps. We have proposed and realized three methods for simultaneous determination of trap depth and decay parameter based on the quasi-equilibrium model and experimental data. If we treat the case of kinetic order a = 1 as a = 2, the error might be as large as 100%.
基金Project supported by the National Natural Science Foundation of China (50472037) the Natural Science Foundation of Hebei Province (E2004000117 and F2004000130) the Science and Technology Research Program from the Bureau of Science and Technology of Hebei Province (2002158)
文摘The ZnO and Zn1-xMnxO minicrystal were synthesized by chemical vapor transport (CVT). The electron trap structure (donor level) and process on the temporal behavior of photoelectrons of materials were respectively studied by thermo-luminescence and microwave absorption dielectric spectrometry. There are two peaks in the thermo-luminescence spectra in pure ZnO, one is -183 ℃ and the other is -127 ℃, which shows two kinds of electron trap energy level produced by the intrinsic defects in ZnO;but obtain very low thermo-luminescence that only equals to ten percent of pure ZnO in Zn1-xMnxO, which shows that its intensity of electron trap is less. The studies of microwave absorption dielectric spectrometry show that conduction band photoelectrons are two-step exponential decay process in ZnO, the lifetime of rapid process is 83 ns, while slow process is 828 ns, the reason of delay is relaxation effects of electron trap to conduction band photoelectrons. The intensity of electron trap is less in Zn1-xMnxO minicrystal, the relaxation effects of conduction band photoelectrons from electron trap is little, so electrons disappeared quickly at conduction band, and the decay process of photoelectrons is only 10～20 ns.
