The Sr3SiO5:Eu2+ phosphor was synthesized by high temperature solid-state reaction. The emission spectrum of Sr3SiO5:Eu2+ shows two bands centered at 487 and 575 nm, which well agree with the theoretic values of emiss...The Sr3SiO5:Eu2+ phosphor was synthesized by high temperature solid-state reaction. The emission spectrum of Sr3SiO5:Eu2+ shows two bands centered at 487 and 575 nm, which well agree with the theoretic values of emission spectrum. The excitation spectrum for 575 nm emission center has several excitation bands at 365, 418, 458 and 473 nm. And the results show that the emission spectrum of Sr3SiO5:Eu2+ is influenced by the Eu2+ concentration. The relative emission spectra of the white-emitting InGaN-based YAG:Ce3+ LED and Sr3SiO5:Eu2+ LED were investigated. The results show that the color development of InGaN-based Sr3SiO5:Eu2+ is better than that of InGaN-based YAG:Ce3+, and the CIE chromaticity of InGaN-based Sr3SiO5:Eu2+ is (x=0.348, y=0.326).展开更多
Sr3SiO5:Eu2+ yellow phosphors for white LEDs were synthesized by high temperature solid state reaction method under a reductive atmosphere. The crystalline phases were examined with X-ray diffraction (XRD). Luminescen...Sr3SiO5:Eu2+ yellow phosphors for white LEDs were synthesized by high temperature solid state reaction method under a reductive atmosphere. The crystalline phases were examined with X-ray diffraction (XRD). Luminescence properties were studied, and effects of various fluxing agents BaCl2, MgF2, CaF2 and BaF2 on the emission spectra were also studied. The optimal Eu2+ concentration and flux were determined. Sr3SiO5: Eu2+ was obtained by firing the sample on optimal composition and fabrication process. The sa...展开更多
This paper synthesizes the Sr2SiO4：Eu^2＋ phosphor by high temperature solid-state reaction. The emission spectrum of Sr2SiO4 ： Eu^2＋ shows two bands centred at 480 and 547 nm, which agree well with the calculation...This paper synthesizes the Sr2SiO4：Eu^2＋ phosphor by high temperature solid-state reaction. The emission spectrum of Sr2SiO4 ： Eu^2＋ shows two bands centred at 480 and 547 nm, which agree well with the calculation values of emission spectrum, and the location of yellow emission of Sr2SiO4 ： Eu^2＋ is influenced by the Eu^2＋ concentration. The excitation spectrum for 547 nm emission has two bands at 363 and 402 nm. The emission spectrum of white light emitting diodes （w-LEDs） based on Sr2SiO4 ： Eu^2＋ phosphor ＋ InGaN LED was investigated.展开更多
A series of Sr2A12SiO7 phosphors with fixed Eu2＋ concentration and various Tm3＋ concentrations were synthesized via a high temperature solid state reaction. The structure and luminescence properties of the samples w...A series of Sr2A12SiO7 phosphors with fixed Eu2＋ concentration and various Tm3＋ concentrations were synthesized via a high temperature solid state reaction. The structure and luminescence properties of the samples were characterized by X-ray powder diffraction （XRD）, photoluminescence （PL） spectra, decay curves, thermoluminescence （TL） glow curves as well as the photostimu- lated luminescence （PSL） spectra. Sr2A12SiO7：Eu2＋,Tm3＋ phosphors exhibited strong green phosphorescence and photostimulated lu- minescence originating from 4f65d1-4f7 transition of Eu2＋ after ultraviolet light stimulation. Deep traps were found by analyses on the phosphorescence decays and thermoluminescence spectra. It was also found that with increasing the time interval between UV excita- tion turn-off and stimulation turn-on, the photostimulated luminescence became stronger. This phenomenon resulted from the fact that the captured electron was retrapped by the deep traps. Compared with the Tm3＋-free sample, it was found that the PSL intensity was strongly enhanced in Tm3＋ eodoping samples.展开更多
基金Hebei Provincial Technology Development Foundation (Grant No. 51215103b)
文摘The Sr3SiO5:Eu2+ phosphor was synthesized by high temperature solid-state reaction. The emission spectrum of Sr3SiO5:Eu2+ shows two bands centered at 487 and 575 nm, which well agree with the theoretic values of emission spectrum. The excitation spectrum for 575 nm emission center has several excitation bands at 365, 418, 458 and 473 nm. And the results show that the emission spectrum of Sr3SiO5:Eu2+ is influenced by the Eu2+ concentration. The relative emission spectra of the white-emitting InGaN-based YAG:Ce3+ LED and Sr3SiO5:Eu2+ LED were investigated. The results show that the color development of InGaN-based Sr3SiO5:Eu2+ is better than that of InGaN-based YAG:Ce3+, and the CIE chromaticity of InGaN-based Sr3SiO5:Eu2+ is (x=0.348, y=0.326).
基金Project Supported by the Jilin Province Science and Technology Development Projects (20090348 and 20080511)
文摘Sr3SiO5:Eu2+ yellow phosphors for white LEDs were synthesized by high temperature solid state reaction method under a reductive atmosphere. The crystalline phases were examined with X-ray diffraction (XRD). Luminescence properties were studied, and effects of various fluxing agents BaCl2, MgF2, CaF2 and BaF2 on the emission spectra were also studied. The optimal Eu2+ concentration and flux were determined. Sr3SiO5: Eu2+ was obtained by firing the sample on optimal composition and fabrication process. The sa...
基金Project supported by Hebei Provincial Technology Development Foundation of China(Grant No51215103b)
文摘This paper synthesizes the Sr2SiO4：Eu^2＋ phosphor by high temperature solid-state reaction. The emission spectrum of Sr2SiO4 ： Eu^2＋ shows two bands centred at 480 and 547 nm, which agree well with the calculation values of emission spectrum, and the location of yellow emission of Sr2SiO4 ： Eu^2＋ is influenced by the Eu^2＋ concentration. The excitation spectrum for 547 nm emission has two bands at 363 and 402 nm. The emission spectrum of white light emitting diodes （w-LEDs） based on Sr2SiO4 ： Eu^2＋ phosphor ＋ InGaN LED was investigated.
基金supported by the National Natural Science Foundation of China(1137404411104024)+2 种基金Natural Science Foundation of Liaoning Province(2014025010)Fundamental Research Funds for the Central Universities(31320143273132015143)
文摘A series of Sr2A12SiO7 phosphors with fixed Eu2＋ concentration and various Tm3＋ concentrations were synthesized via a high temperature solid state reaction. The structure and luminescence properties of the samples were characterized by X-ray powder diffraction （XRD）, photoluminescence （PL） spectra, decay curves, thermoluminescence （TL） glow curves as well as the photostimu- lated luminescence （PSL） spectra. Sr2A12SiO7：Eu2＋,Tm3＋ phosphors exhibited strong green phosphorescence and photostimulated lu- minescence originating from 4f65d1-4f7 transition of Eu2＋ after ultraviolet light stimulation. Deep traps were found by analyses on the phosphorescence decays and thermoluminescence spectra. It was also found that with increasing the time interval between UV excita- tion turn-off and stimulation turn-on, the photostimulated luminescence became stronger. This phenomenon resulted from the fact that the captured electron was retrapped by the deep traps. Compared with the Tm3＋-free sample, it was found that the PSL intensity was strongly enhanced in Tm3＋ eodoping samples.
