A kind of surface instability,basin-like depression defect companied by mixed grain structure at the bottom of large-scale valve during electric upsetting process,would significantly influence the microstructures and ...A kind of surface instability,basin-like depression defect companied by mixed grain structure at the bottom of large-scale valve during electric upsetting process,would significantly influence the microstructures and mechanical properties of components.In order to analyze the forming process of the basin-like depression defect,a finite element model for the electric upsetting process of Ni80A superalloy was developed using multi-field and multi-scale coupling analysis method.Subsequently,a series of parameters loading path schemes for force and current were designed by varying the initial value,peak value and value level,and their effects on basin-like depression and mixed grain structure were simulated and uncovered.It is concluded that the changes of heating speed and pressurization speed result in the different flow velocities between the inner and outer layers of billet,thus exerting the basin-like depression.Simulation results also indicate that these defects can be optimized through the parameter coordination between force and current.Finally,the validity and reliability of the finite element model were verified by physical experiments in electric upsetting process.展开更多
A series of clusters Ni4P are designed to simulate the amorphous alloy Ni80P20. After the cluster models are computed by DFT, several stable structures are gained. Their geometric, electronic and catalytic properties ...A series of clusters Ni4P are designed to simulate the amorphous alloy Ni80P20. After the cluster models are computed by DFT, several stable structures are gained. Their geometric, electronic and catalytic properties have been analyzed and discussed. It is proved that cluster Ni4P can reflect the amorphous alloy Ni80P20 very well from the geometry parameters. We find the deformed triangle dipyramid with quadruplet state （configuration 1^（4）） is the most stable structure for cluster Ni4P, which is the most possible local structure in amorphous alloy Ni80P20. And the transition energy between two isomers with the same multiple state is higher than the one with the different. Bond Ni-P plays a very important role in offering the system stability for cluster Ni4E P is the electron donor, and Ni is the accepter in cluster Ni4P, which is in accordance with the experiment results. The 3d orbital populations and Fermi levels of clusters Ni4 have been decreased with the addition of atom E Based on the research of Fermi levels of clusters Ni4P to approach the Fermi level of H2 and their density of state （DOS）, the highest catalytic active property in cluster Ni4P is owned to configuration 1^（4）.展开更多
基金support from the National Natural Science Foundation of China(No.52175287)Open Fund of State Key Laboratory of Materials Processing and Die&Mould Technology,China(No.P2020-001).
文摘A kind of surface instability,basin-like depression defect companied by mixed grain structure at the bottom of large-scale valve during electric upsetting process,would significantly influence the microstructures and mechanical properties of components.In order to analyze the forming process of the basin-like depression defect,a finite element model for the electric upsetting process of Ni80A superalloy was developed using multi-field and multi-scale coupling analysis method.Subsequently,a series of parameters loading path schemes for force and current were designed by varying the initial value,peak value and value level,and their effects on basin-like depression and mixed grain structure were simulated and uncovered.It is concluded that the changes of heating speed and pressurization speed result in the different flow velocities between the inner and outer layers of billet,thus exerting the basin-like depression.Simulation results also indicate that these defects can be optimized through the parameter coordination between force and current.Finally,the validity and reliability of the finite element model were verified by physical experiments in electric upsetting process.
文摘A series of clusters Ni4P are designed to simulate the amorphous alloy Ni80P20. After the cluster models are computed by DFT, several stable structures are gained. Their geometric, electronic and catalytic properties have been analyzed and discussed. It is proved that cluster Ni4P can reflect the amorphous alloy Ni80P20 very well from the geometry parameters. We find the deformed triangle dipyramid with quadruplet state （configuration 1^（4）） is the most stable structure for cluster Ni4P, which is the most possible local structure in amorphous alloy Ni80P20. And the transition energy between two isomers with the same multiple state is higher than the one with the different. Bond Ni-P plays a very important role in offering the system stability for cluster Ni4E P is the electron donor, and Ni is the accepter in cluster Ni4P, which is in accordance with the experiment results. The 3d orbital populations and Fermi levels of clusters Ni4 have been decreased with the addition of atom E Based on the research of Fermi levels of clusters Ni4P to approach the Fermi level of H2 and their density of state （DOS）, the highest catalytic active property in cluster Ni4P is owned to configuration 1^（4）.
