On the basis of the experimental data of phase equilibria and thermochemical properties available from literatures, a critical assessment for the Ni?Yb binary system was carried out using the CALPHAD (calculation of p...On the basis of the experimental data of phase equilibria and thermochemical properties available from literatures, a critical assessment for the Ni?Yb binary system was carried out using the CALPHAD (calculation of phase diagrams) method. The liquid phase is modeled as the associate model with the constituent species Ni, Yb and YbNi3, owing to the sharp change of the enthalpy of mixing of liquid phase at the composition of around 25% Yb (mole fraction). The terminal solid solutions FCC_A1 (Ni/Yb) and BCC_A2 (Yb) are described by the substitutional solution model with the Redlich?Kister polynomial. The intermetallic compounds, Yb2Ni17, YbNi5, YbNi3, YbNi2, α-YbNi and β-YbNi, are treated as strict stoichiometric compounds, since there are no noticeable homogeneity ranges reported for these compounds. A set of self-consistent thermodynamic parameters for the Ni?Yb binary system are obtained. According to the presently assessed results, the thermochemical properties and the phase boundary data can be well reproduced.展开更多
In this paper, Ni/Zr–Yb–O catalysts with different sodium contents are prepared by a co-precipitation method, using aqueous Na2CO3 solution as a precipitant, and the effect of sodium on the catalyst structure and ca...In this paper, Ni/Zr–Yb–O catalysts with different sodium contents are prepared by a co-precipitation method, using aqueous Na2CO3 solution as a precipitant, and the effect of sodium on the catalyst structure and catalytic performance for syngas methanation is extensively investigated using five Ni/Zr–Yb–O catalysts, containing 0, 0.5, 1.5,4.5 and 13.5 wt% Na^+, those are denoted as Cat-1, Cat-2, Cat-3, Cat-4 and Cat-5 respectively. It is found that the interaction between Ni and support determines the catalytic performance of Ni/Zr–Yb–O and the residual sodium content negatively affects the interaction between Ni and support. Cat-1 exhibits an excellent catalytic performance.During a long run time of 380 h, no deactivation is observed and both CO conversion and CH4 selectivity maintain a level above 90%. However, Cat-3 and Cat-5 suffer rapid deactivation under the same reaction condition. The characterization results indicate the strong interaction between Ni and support enables Cat-1 to possess well dispersed Ni species, resistance to sintering and carbon deposition and thus the excellent catalytic performance. However, the presence of sodium ions over Ni/Zr–Yb–O degrades the interaction between Ni and support and the catalytic performance, especially for the stability. The relative weak interaction between Ni and support results in severe sintering of both ZrO2 and Ni under the reaction condition, carbon deposition and the poor catalytic performance.展开更多
基金Project(51271027)supported by the National Natural Science Foundation of ChinaProject(T201308)supported by Shenzhen Key Laboratory of Special Functional Materials of Shenzhen University,China
文摘On the basis of the experimental data of phase equilibria and thermochemical properties available from literatures, a critical assessment for the Ni?Yb binary system was carried out using the CALPHAD (calculation of phase diagrams) method. The liquid phase is modeled as the associate model with the constituent species Ni, Yb and YbNi3, owing to the sharp change of the enthalpy of mixing of liquid phase at the composition of around 25% Yb (mole fraction). The terminal solid solutions FCC_A1 (Ni/Yb) and BCC_A2 (Yb) are described by the substitutional solution model with the Redlich?Kister polynomial. The intermetallic compounds, Yb2Ni17, YbNi5, YbNi3, YbNi2, α-YbNi and β-YbNi, are treated as strict stoichiometric compounds, since there are no noticeable homogeneity ranges reported for these compounds. A set of self-consistent thermodynamic parameters for the Ni?Yb binary system are obtained. According to the presently assessed results, the thermochemical properties and the phase boundary data can be well reproduced.
文摘在熔盐电解制备Ni-Yb合金过程中,掌握LiF-YbF_(3)-Yb_(2)O_(3)熔融盐体系的粘度性质是优化系统和结构解析的关键之一。本文采用等温饱和法确定Yb_(2)O_(3)溶解度,利用旋转法测定温度1173~1473 K范围内LiF-YbF_(3)-Yb_(2)O_(3)体系粘度并分析其变化规律,确定其计算模型,通过优化的数学模型估算Ni-Yb合金的粘度值,并确定与LiF-YbF_(3)-Yb_(2)O_(3)体系匹配性;结果表明:1173~1473 K范围内Yb_(2)O_(3)在LiF-YbF_(3)中的溶解度约为2.5%~3.05%;随温度升高,LiF-YbF_(3)-Yb_(2)O_(3)体系的粘度非线性降低;随Yb_(2)O_(3)的浓度提高,LiF-YbF_(3)-Yb_(2)O_(3)体系的粘度非线性升高;不同配比的熔融Yb-Ni合金粘度均小于LiF-YbF_(3)-Yb_(2)O_(3)熔盐体系的平均粘度(2.2 m Pa·s);当Yb含量为80%或0~10%(摩尔分数)范围内的Yb-Ni合金的粘度值较低,液态合金容易与LiF-YbF_(3)-Yb_(2)O_(3)熔盐分离。
基金Supported by the National Natural Science Foundation of China(21673187,21336009,21576228)National Key Technology Support Program of China(2014BAC10B01).
文摘In this paper, Ni/Zr–Yb–O catalysts with different sodium contents are prepared by a co-precipitation method, using aqueous Na2CO3 solution as a precipitant, and the effect of sodium on the catalyst structure and catalytic performance for syngas methanation is extensively investigated using five Ni/Zr–Yb–O catalysts, containing 0, 0.5, 1.5,4.5 and 13.5 wt% Na^+, those are denoted as Cat-1, Cat-2, Cat-3, Cat-4 and Cat-5 respectively. It is found that the interaction between Ni and support determines the catalytic performance of Ni/Zr–Yb–O and the residual sodium content negatively affects the interaction between Ni and support. Cat-1 exhibits an excellent catalytic performance.During a long run time of 380 h, no deactivation is observed and both CO conversion and CH4 selectivity maintain a level above 90%. However, Cat-3 and Cat-5 suffer rapid deactivation under the same reaction condition. The characterization results indicate the strong interaction between Ni and support enables Cat-1 to possess well dispersed Ni species, resistance to sintering and carbon deposition and thus the excellent catalytic performance. However, the presence of sodium ions over Ni/Zr–Yb–O degrades the interaction between Ni and support and the catalytic performance, especially for the stability. The relative weak interaction between Ni and support results in severe sintering of both ZrO2 and Ni under the reaction condition, carbon deposition and the poor catalytic performance.
