The initial decomposition of methylamine on Mo（100） surface has been investigated by self-consistent （GGA-PW91） density functional theory combined with periodic slab model. The adsorption energies of possible spec...The initial decomposition of methylamine on Mo（100） surface has been investigated by self-consistent （GGA-PW91） density functional theory combined with periodic slab model. The adsorption energies of possible species and the activation energies for possible elementary reactions involved are obtained in the present work. Our results indicate that the barriers decreased with the order of C-NN-HC-H. In addition, metastable adsorption of the abstracted hydrogen atom on the hollow site in the final state is also considered for the N-H and C-H bond breaking. For the C-H bond cleavage, the reaction barrier that the abstracted hydrogen located on the hollow site in the final state is lower than that on the bridge site. However, for the N H bond breaking, the barriers are alike for the abstracted hydrogen on both hollow and bridge sites in the final state.展开更多
基于200 t BOF-LF-RH-板坯连铸的10CrNi3Mo钢冶金生产流程,分别通过向钢液喂入硅钙包芯线和钙镁复合包芯线,对夹杂物进行变性处理,之后通过4300厚板轧机轧制35 mm板并进行热处理。利用等电位溶液电解、扫描电镜与能谱、夹杂物分析仪等...基于200 t BOF-LF-RH-板坯连铸的10CrNi3Mo钢冶金生产流程,分别通过向钢液喂入硅钙包芯线和钙镁复合包芯线,对夹杂物进行变性处理,之后通过4300厚板轧机轧制35 mm板并进行热处理。利用等电位溶液电解、扫描电镜与能谱、夹杂物分析仪等设备和方法对试验钢的夹杂物进行定量、定性分析,获得夹杂物的特性参数,主要表现为变性后夹杂物单位面积数量减少约40%,平均间距增加近1倍。结合夏比冲击试验结果,得出夹杂物变形处理对冲击韧性特别是低温冲击韧性有明显改善的结论。展开更多
Multi-stage igneous rocks developed in the recently discovered Huoluotai Cu-(Mo)deposit provide new insights into the controversial late Mesozoic geodynamic evolution of the northern segment of the Great Xing’an Rang...Multi-stage igneous rocks developed in the recently discovered Huoluotai Cu-(Mo)deposit provide new insights into the controversial late Mesozoic geodynamic evolution of the northern segment of the Great Xing’an Range(NSGXR).Zircon U-Pb dating suggests that the monzogranite,ore-bearing granodiorite porphyry,diorite porphyry,and granite porphyry in the deposit were emplaced at 179.5±1.6,148.9±0.9,146.1±1.3,and 142.2±1.5 Ma,respectively.The Re-Os dating of molybdenite yielded an isochron age of 146.9±2.3 Ma(MSWD=0.27).The Jurassic adakitic monzogranite and granodiorite porphyry are characterized by high SiO_(2)and Na_(2)O contents,low K_(2)O/Na_(2)O ratios,low Mg O,Cr,and Ni contents,low zirconεHf(t)values relative to depleted mantle,and relatively high Th contents.They were produced by partial melting of a subducted oceanic slab,with involvement of marine sediments in the magma source and limited interaction with mantle peridotites during magma ascent.The Late Jurassic diorite porphyry is characterized by moderate SiO_(2) contents,high Mg O,Cr,and Ni contents,and positive dominatedεHf(t)values,indicating it was produced by partial melting of a subduction-modified lithospheric mantle wedge and underwent limited crustal contamination during magma ascent.The early Early Cretaceous adakitic granite porphyry shows high SiO_(2) and K_(2)O contents and K_(2)O/Na_(2)O ratios,low Mg O,Cr,and Ni contents,enriched Sr-Nd isotopic compositions,and slightly positive zirconεHf(t)values,suggesting it was produced by partial melting of thickened mafic lower crust.The NSGXR experienced a tectonic history that involved flat-slab subduction(200-160 Ma),and tearing and collapse(150-145 Ma)of the Mongol-Okhotsk oceanic lithosphere.The period of magmatic quiescence from ca.160 to 150 Ma was a response to flat-slab subduction of the Mongol-Okhotsk oceanic lithosphere.Crustal thickening in the NSGXR(145-133 Ma)was due to the collision between the Amuria Block and the Siberian Craton.展开更多
12Cr2Mo1VR钢板生产的流程为100 t EAF-LF-VOD-CC-ESR-轧制工艺。电渣重熔过程中,采用熔速降低(160~180)kg/h及氮气保护等工艺;轧制过程采用低速大压下量轧制工艺;轧后采用650~700℃长时保温扩氢退火工艺;热处理采用930-950℃正火(加速...12Cr2Mo1VR钢板生产的流程为100 t EAF-LF-VOD-CC-ESR-轧制工艺。电渣重熔过程中,采用熔速降低(160~180)kg/h及氮气保护等工艺;轧制过程采用低速大压下量轧制工艺;轧后采用650~700℃长时保温扩氢退火工艺;热处理采用930-950℃正火(加速冷却)+680-700℃回火工艺。生产的钢板表面质量良好,探伤级别满足NB/T47013.3-2015及第1号修改单TⅠ级要求,钢板成分、显微组织均匀,力学性能满足技术要求。展开更多
The Xiaokele Cu(–Mo)deposit is a recently discovered porphyry deposit in the northern Great Xing’an Range(GXR)of northeast China.The ore bodies in this deposit are mainly hosted within granodiorite porphyry intrusio...The Xiaokele Cu(–Mo)deposit is a recently discovered porphyry deposit in the northern Great Xing’an Range(GXR)of northeast China.The ore bodies in this deposit are mainly hosted within granodiorite porphyry intrusions.Potassic,phyllic,and propylitic alteration zones develop from center to edge.In this paper,we present zircon LA–ICP–MS U–Pb ages,zircon Hf isotopic compositions,and whole-rock geochemistry of the ore-bearing granodiorite porphyries from the Xiaokele Cu(–Mo)deposit.Zircon U–Pb dating suggests that the Xiaokele granodiorite porphyries were emplaced at 148.8±1.1 Ma(weighted-mean age;n=14).The Xiaokele granodiorite porphyries display high SiO2,Al2O3,Sr,and Sr/Y,low K2O/Na2O,MgO,Yb,and Y,belonging to high-SiO2 adakites produced by partial melting of the subducted oceanic slab.Marine sediments were involved in the magma source of the Xiaokele granodiorite porphyries,as indicated by enriched Sr–Nd isotopic compositions(eNd(-t)=-1.17–-0.27),low positive zircon eHf(t)values(0.4–2.2),and high Th contents(4.06–5.20).The adakitic magma subsequently interacted with the mantle peridotites during ascent through the mantle wedge.The Xiaokele granodiorite porphyries were derived from slab melting during the southward subduction of the Mongol–Okhotsk Ocean.展开更多
基金supported by the National Natural Science Foundation of China (Grants No. 21073113)the Intramural Foundation of Shanxi Datong University
文摘The initial decomposition of methylamine on Mo（100） surface has been investigated by self-consistent （GGA-PW91） density functional theory combined with periodic slab model. The adsorption energies of possible species and the activation energies for possible elementary reactions involved are obtained in the present work. Our results indicate that the barriers decreased with the order of C-NN-HC-H. In addition, metastable adsorption of the abstracted hydrogen atom on the hollow site in the final state is also considered for the N-H and C-H bond breaking. For the C-H bond cleavage, the reaction barrier that the abstracted hydrogen located on the hollow site in the final state is lower than that on the bridge site. However, for the N H bond breaking, the barriers are alike for the abstracted hydrogen on both hollow and bridge sites in the final state.
文摘基于200 t BOF-LF-RH-板坯连铸的10CrNi3Mo钢冶金生产流程,分别通过向钢液喂入硅钙包芯线和钙镁复合包芯线,对夹杂物进行变性处理,之后通过4300厚板轧机轧制35 mm板并进行热处理。利用等电位溶液电解、扫描电镜与能谱、夹杂物分析仪等设备和方法对试验钢的夹杂物进行定量、定性分析,获得夹杂物的特性参数,主要表现为变性后夹杂物单位面积数量减少约40%,平均间距增加近1倍。结合夏比冲击试验结果,得出夹杂物变形处理对冲击韧性特别是低温冲击韧性有明显改善的结论。
基金funded by the Natural Science Foundation of Jilin Province(No.20180101089JC)Key Projects of Science and Technology Development Plan of Jilin Province(No.20100445)+5 种基金National Key R&D Program of China(2017YFC0601304)the Natural Science Foundation of Liaoning Province(2020-BS-258)the Department of Education of Liaoning Province(LJ2020JCL010)a Discipline Innovation Team Project of Liaoning Technical University(LNTU20TD-14)Graduate Innovation Research Project of Jilin University(Grant NO.101832020CX201)Heilongjiang Research Project of Land and Resources(201605,201704)。
文摘Multi-stage igneous rocks developed in the recently discovered Huoluotai Cu-(Mo)deposit provide new insights into the controversial late Mesozoic geodynamic evolution of the northern segment of the Great Xing’an Range(NSGXR).Zircon U-Pb dating suggests that the monzogranite,ore-bearing granodiorite porphyry,diorite porphyry,and granite porphyry in the deposit were emplaced at 179.5±1.6,148.9±0.9,146.1±1.3,and 142.2±1.5 Ma,respectively.The Re-Os dating of molybdenite yielded an isochron age of 146.9±2.3 Ma(MSWD=0.27).The Jurassic adakitic monzogranite and granodiorite porphyry are characterized by high SiO_(2)and Na_(2)O contents,low K_(2)O/Na_(2)O ratios,low Mg O,Cr,and Ni contents,low zirconεHf(t)values relative to depleted mantle,and relatively high Th contents.They were produced by partial melting of a subducted oceanic slab,with involvement of marine sediments in the magma source and limited interaction with mantle peridotites during magma ascent.The Late Jurassic diorite porphyry is characterized by moderate SiO_(2) contents,high Mg O,Cr,and Ni contents,and positive dominatedεHf(t)values,indicating it was produced by partial melting of a subduction-modified lithospheric mantle wedge and underwent limited crustal contamination during magma ascent.The early Early Cretaceous adakitic granite porphyry shows high SiO_(2) and K_(2)O contents and K_(2)O/Na_(2)O ratios,low Mg O,Cr,and Ni contents,enriched Sr-Nd isotopic compositions,and slightly positive zirconεHf(t)values,suggesting it was produced by partial melting of thickened mafic lower crust.The NSGXR experienced a tectonic history that involved flat-slab subduction(200-160 Ma),and tearing and collapse(150-145 Ma)of the Mongol-Okhotsk oceanic lithosphere.The period of magmatic quiescence from ca.160 to 150 Ma was a response to flat-slab subduction of the Mongol-Okhotsk oceanic lithosphere.Crustal thickening in the NSGXR(145-133 Ma)was due to the collision between the Amuria Block and the Siberian Craton.
文摘12Cr2Mo1VR钢板生产的流程为100 t EAF-LF-VOD-CC-ESR-轧制工艺。电渣重熔过程中,采用熔速降低(160~180)kg/h及氮气保护等工艺;轧制过程采用低速大压下量轧制工艺;轧后采用650~700℃长时保温扩氢退火工艺;热处理采用930-950℃正火(加速冷却)+680-700℃回火工艺。生产的钢板表面质量良好,探伤级别满足NB/T47013.3-2015及第1号修改单TⅠ级要求,钢板成分、显微组织均匀,力学性能满足技术要求。
基金the National Natural Science Foundation of China(No.41272093)National Key R&D Program of China(No.2017YFC0601304)+3 种基金Natural Science Foundation of Jilin Province(No.20180101089JC)Key Projects of Science and Technology Development Plan of Jilin Province(No.20100445)Self-determined Foundation of Key Laboratory of Mineral Resources Evaluation in Northeast Asia,Ministry of Natural Resources(No.DBY-ZZ-19-04)Heilongjiang Research Project of Land and Resources(No.201605 and 201704)。
文摘The Xiaokele Cu(–Mo)deposit is a recently discovered porphyry deposit in the northern Great Xing’an Range(GXR)of northeast China.The ore bodies in this deposit are mainly hosted within granodiorite porphyry intrusions.Potassic,phyllic,and propylitic alteration zones develop from center to edge.In this paper,we present zircon LA–ICP–MS U–Pb ages,zircon Hf isotopic compositions,and whole-rock geochemistry of the ore-bearing granodiorite porphyries from the Xiaokele Cu(–Mo)deposit.Zircon U–Pb dating suggests that the Xiaokele granodiorite porphyries were emplaced at 148.8±1.1 Ma(weighted-mean age;n=14).The Xiaokele granodiorite porphyries display high SiO2,Al2O3,Sr,and Sr/Y,low K2O/Na2O,MgO,Yb,and Y,belonging to high-SiO2 adakites produced by partial melting of the subducted oceanic slab.Marine sediments were involved in the magma source of the Xiaokele granodiorite porphyries,as indicated by enriched Sr–Nd isotopic compositions(eNd(-t)=-1.17–-0.27),low positive zircon eHf(t)values(0.4–2.2),and high Th contents(4.06–5.20).The adakitic magma subsequently interacted with the mantle peridotites during ascent through the mantle wedge.The Xiaokele granodiorite porphyries were derived from slab melting during the southward subduction of the Mongol–Okhotsk Ocean.
