This work is a simulation model with the LAMMPS calculation code of an electrode based on alkali metal oxides (lithium, sodium and potassium) using the Lennard Jones potential. For a multiplicity of 8*8*8, we studied ...This work is a simulation model with the LAMMPS calculation code of an electrode based on alkali metal oxides (lithium, sodium and potassium) using the Lennard Jones potential. For a multiplicity of 8*8*8, we studied a gap-free model using molecular dynamics. Physical quantities such as volume and pressure of the Na-O and Li-O systems exhibit similar behaviors around the thermodynamic ensembles NPT and NVE. However, for the Na2O system, at a minimum temperature value, we observe a range of total energy values;in contrast, for the Li2O system, a minimum energy corresponds to a range of temperatures. Finally, for physicochemical properties, we studied the diffusion coefficient and activation energy of lithium and potassium oxides around their melting temperatures. The order of magnitude of the diffusion coefficients is given by the relation Dli-O >DNa-O for the multiplicity 8*8*8, while for the activation energy, the order is well reversed EaNa-O > EaLi-O.展开更多
Objective:To investigate the protective effect and mechanism of lithium chloride pretreatment on myocardial ischemia-reperfusion injury(I-RI)in rats.Methods:A total of 60 SD rats were randomly divided into control gro...Objective:To investigate the protective effect and mechanism of lithium chloride pretreatment on myocardial ischemia-reperfusion injury(I-RI)in rats.Methods:A total of 60 SD rats were randomly divided into control group,model group,lithium chloride intervention group and L-arginine methyl ester+lithium chloride intervention group with 15 in each.The I-RI model was established in model group,the Utliium chloride intervention group and L-arginine methyl ester+lithium chloride intervention group by method of seaming along left anterior descending coronary artery myocardial,control group was only opened the chest without seaming,STelevation within 2 min was regarded as modeling success.Model group did not adopted any intervention,lithium chloride intervention group was treated with lithium chloride injection15 mg/kg by jugular venipuncture preoperatively,L-arginine methyl ester+lithium chloride intervention group was treated with intraperitoneal injection of 30mg·kg～(-1)·d～(-1)(L—arginine methyl ester 7 d before the test,and intravenous catheter of 15 mg/kg lithium chloride preoperatively.The hydroxybulyric acid dehydrogenase(HBDH),creatine kinase isoenzyme(CK-MB),superoxide dismutase(SOD),malondialdehyde(MDA)level and nitric oxide synthase(NOS)activites were tested.Each large area of myocardial ischemia tissue was extracted for determination of the MDA content,SOD activity in tissue and serum,and morphological changes of myocardial tissue.Results:SOD activity was highest in lithium chloride intervention group,followed by L-arginine methyl ester+lithium chloride intervention group,control group and model group(P<0.05);SOD activity was highest in L-arginine methyl ester+lithium chloride intervention group intervention group,followed by lithium chloride intervention group,control group and model group(P<0.05).MDA content of myocardial tissue was highest in model group,followed by L-arginine methyl ester+lithium chloride intervention group,the lithium chloride intervention group and control group(P<0.05);serum M展开更多
The electrical properties of (Nb, Li)-doped SnO2 ceramics as a new varistor material were investigated. The sample 97.95%SnO2·0.50%Li2O·0.05%Nb2O5 (mol fraction) sintered at 1450= possess the highest densit...The electrical properties of (Nb, Li)-doped SnO2 ceramics as a new varistor material were investigated. The sample 97.95%SnO2·0.50%Li2O·0.05%Nb2O5 (mol fraction) sintered at 1450= possess the highest density (ρ=6.77 g/cm3) and nonlinear electrical coefficient (α=11.6). The substitution of Sn4+ with Li+ increases the concentration of oxygen vacancies, together with the formation of solid solution, which will increase the sintering rate greatly and decrease the optimized sintering temperature. The substitution of Sn4+ with Li+ and the variation of temperature play very important effects on the densities, dielectric constant, nonlinear electrical properties and other characteristics of the samples. The properties of the grain boundary barrier and the microstructural characteristics were investigated to ensure the effect of the dopants and the temperature. A grain boundary defect barrier model was used to illustrate the grain boundary barriers formation in SnO2-Li2O-Nb2O5 varistors.展开更多
文摘This work is a simulation model with the LAMMPS calculation code of an electrode based on alkali metal oxides (lithium, sodium and potassium) using the Lennard Jones potential. For a multiplicity of 8*8*8, we studied a gap-free model using molecular dynamics. Physical quantities such as volume and pressure of the Na-O and Li-O systems exhibit similar behaviors around the thermodynamic ensembles NPT and NVE. However, for the Na2O system, at a minimum temperature value, we observe a range of total energy values;in contrast, for the Li2O system, a minimum energy corresponds to a range of temperatures. Finally, for physicochemical properties, we studied the diffusion coefficient and activation energy of lithium and potassium oxides around their melting temperatures. The order of magnitude of the diffusion coefficients is given by the relation Dli-O >DNa-O for the multiplicity 8*8*8, while for the activation energy, the order is well reversed EaNa-O > EaLi-O.
基金supported by Target Scientific Research of Zhangjiakou Technology Bureau No.12110044D-2
文摘Objective:To investigate the protective effect and mechanism of lithium chloride pretreatment on myocardial ischemia-reperfusion injury(I-RI)in rats.Methods:A total of 60 SD rats were randomly divided into control group,model group,lithium chloride intervention group and L-arginine methyl ester+lithium chloride intervention group with 15 in each.The I-RI model was established in model group,the Utliium chloride intervention group and L-arginine methyl ester+lithium chloride intervention group by method of seaming along left anterior descending coronary artery myocardial,control group was only opened the chest without seaming,STelevation within 2 min was regarded as modeling success.Model group did not adopted any intervention,lithium chloride intervention group was treated with lithium chloride injection15 mg/kg by jugular venipuncture preoperatively,L-arginine methyl ester+lithium chloride intervention group was treated with intraperitoneal injection of 30mg·kg～(-1)·d～(-1)(L—arginine methyl ester 7 d before the test,and intravenous catheter of 15 mg/kg lithium chloride preoperatively.The hydroxybulyric acid dehydrogenase(HBDH),creatine kinase isoenzyme(CK-MB),superoxide dismutase(SOD),malondialdehyde(MDA)level and nitric oxide synthase(NOS)activites were tested.Each large area of myocardial ischemia tissue was extracted for determination of the MDA content,SOD activity in tissue and serum,and morphological changes of myocardial tissue.Results:SOD activity was highest in lithium chloride intervention group,followed by L-arginine methyl ester+lithium chloride intervention group,control group and model group(P<0.05);SOD activity was highest in L-arginine methyl ester+lithium chloride intervention group intervention group,followed by lithium chloride intervention group,control group and model group(P<0.05).MDA content of myocardial tissue was highest in model group,followed by L-arginine methyl ester+lithium chloride intervention group,the lithium chloride intervention group and control group(P<0.05);serum M
文摘The electrical properties of (Nb, Li)-doped SnO2 ceramics as a new varistor material were investigated. The sample 97.95%SnO2·0.50%Li2O·0.05%Nb2O5 (mol fraction) sintered at 1450= possess the highest density (ρ=6.77 g/cm3) and nonlinear electrical coefficient (α=11.6). The substitution of Sn4+ with Li+ increases the concentration of oxygen vacancies, together with the formation of solid solution, which will increase the sintering rate greatly and decrease the optimized sintering temperature. The substitution of Sn4+ with Li+ and the variation of temperature play very important effects on the densities, dielectric constant, nonlinear electrical properties and other characteristics of the samples. The properties of the grain boundary barrier and the microstructural characteristics were investigated to ensure the effect of the dopants and the temperature. A grain boundary defect barrier model was used to illustrate the grain boundary barriers formation in SnO2-Li2O-Nb2O5 varistors.
