The relationship between hydrocarbon generation and the evolution of shale pore structure and its heterogeneity of continental shale from the Ordos Basin,China was quantitatively studied based on thermal simulation ex...The relationship between hydrocarbon generation and the evolution of shale pore structure and its heterogeneity of continental shale from the Ordos Basin,China was quantitatively studied based on thermal simulation experiment,mercury injection capillary pressure(MICP),gas adsorption,vitrinite reflectance(R_(o))analysis,and hydrocarbon generation test combined with Frenkel-Halsey-Hill(FHH)fractal model.The result shows that the pore volume(PV)and specific surface area(SSA)of pores with different pore sizes show a trend of decreasing first and then increasing as the maturity increases in general,R_(o)>1.59%is initially defined as a favorable stage for pore development in continental shale.Hydrocarbon generation has different effects on pore heterogeneity of different scales.For the N_(2)adsorption,the roughness of small pore surface(D_(1))decreases in the oil window;the complexity of large pore structure(D_(2))increases in the oil window but decreases in the gas window.For the MICP,the heterogeneity of small pore(D_(1))increases in the oil window and increases first and then decreases in the gas window;D_(2)remains basically constant during the whole stage and is close to 3,indicating that the heterogeneity of large pores is extremely strong and is not affected by hydrocarbon generation.展开更多
We study the effect of dimension variation for second-harmonic generation(SHG) in lithium niobate on insulator(LNOI)waveguides. Non-trivial SHG profiles in both type-0 and type-I quasi-phase matching are observed duri...We study the effect of dimension variation for second-harmonic generation(SHG) in lithium niobate on insulator(LNOI)waveguides. Non-trivial SHG profiles in both type-0 and type-I quasi-phase matching are observed during the wavelength tuning of the fundamental light. Theoretical modeling shows that the SHG profile and efficiency can be greatly affected by the waveguide cross-section dimension variations, especially the thickness variations. In particular, our analysis shows that a thickness variation of tens of nanometers is in good agreement with the experimental results. Such investigations could be used to evaluate fabrication performance of LNOI-based nonlinear optical devices.展开更多
基金supported by the National Science and Technology Major Project of the Ministry of Science and Technology of China"Study on Formation Mechanism and Enrichment Regularity of Different Types of Shale Gas"(2016ZX05034)the Oil&Gas Survey,China Geological Survey for their support of this research。
文摘The relationship between hydrocarbon generation and the evolution of shale pore structure and its heterogeneity of continental shale from the Ordos Basin,China was quantitatively studied based on thermal simulation experiment,mercury injection capillary pressure(MICP),gas adsorption,vitrinite reflectance(R_(o))analysis,and hydrocarbon generation test combined with Frenkel-Halsey-Hill(FHH)fractal model.The result shows that the pore volume(PV)and specific surface area(SSA)of pores with different pore sizes show a trend of decreasing first and then increasing as the maturity increases in general,R_(o)>1.59%is initially defined as a favorable stage for pore development in continental shale.Hydrocarbon generation has different effects on pore heterogeneity of different scales.For the N_(2)adsorption,the roughness of small pore surface(D_(1))decreases in the oil window;the complexity of large pore structure(D_(2))increases in the oil window but decreases in the gas window.For the MICP,the heterogeneity of small pore(D_(1))increases in the oil window and increases first and then decreases in the gas window;D_(2)remains basically constant during the whole stage and is close to 3,indicating that the heterogeneity of large pores is extremely strong and is not affected by hydrocarbon generation.
基金supported by the National Key R&D Program of China(No.2019YFA0705000)Key R&D Program of Guangdong Province(No.2018B030329001)+2 种基金Leading-edge Technology Program of Jiangsu Natural Science Foundation(No.BK20192001)National Natural Science Foundation of China(Nos.51890861,11690031,11674169,91950206,and 11974178)Fundamental Research Funds for the Central Universities(No.021314380177)。
文摘We study the effect of dimension variation for second-harmonic generation(SHG) in lithium niobate on insulator(LNOI)waveguides. Non-trivial SHG profiles in both type-0 and type-I quasi-phase matching are observed during the wavelength tuning of the fundamental light. Theoretical modeling shows that the SHG profile and efficiency can be greatly affected by the waveguide cross-section dimension variations, especially the thickness variations. In particular, our analysis shows that a thickness variation of tens of nanometers is in good agreement with the experimental results. Such investigations could be used to evaluate fabrication performance of LNOI-based nonlinear optical devices.
