Extraction of vanadium（IV） from sulphate acid solution was studied using organophosphorous-based extractants D2EHPA, EHEHPA and CYANEX 272 in kerosene. The different parameters affecting the extraction of vanadium...Extraction of vanadium（IV） from sulphate acid solution was studied using organophosphorous-based extractants D2EHPA, EHEHPA and CYANEX 272 in kerosene. The different parameters affecting the extraction of vanadium（IV） under equilibrium conditions were separately investigated to elucidate the stoichiometry of the extracted species. The distribution ratio of vanadium increased with increasing equilibrium pH of the aqueous phase, concentration of the extractants and temperature. D2EHPA was found to be a stronger extractant, having greater pH functionality than EHEHPA and CYANEX 272. Extraction of vanadium（IV） by these organophosphorous-based extractants involved cation exchange mechanism, and the extracted species appear to be VOR2（HR）2 in the low equilibrium pH and VOR2 in the higher equilibrium pH, where HR refers to the three acidic extractants.展开更多
研究了Cyanex272从盐酸介质中萃取Nd(Ⅲ)和Y(Ⅲ)的性能,考察了平衡相酸度、振荡时间和平衡相温度对萃取的影响。结果表明,分配比在一定时间内随振荡时间、平衡相温度的增加而增加。在pH 1.54、振荡时间为20 m in时,Nd(Ⅲ)的分配比最小;...研究了Cyanex272从盐酸介质中萃取Nd(Ⅲ)和Y(Ⅲ)的性能,考察了平衡相酸度、振荡时间和平衡相温度对萃取的影响。结果表明,分配比在一定时间内随振荡时间、平衡相温度的增加而增加。在pH 1.54、振荡时间为20 m in时,Nd(Ⅲ)的分配比最小;而在pH 2.62、振荡时间为25 min时,Y(Ⅲ)能很好地被萃取。Nd(Ⅲ)-Y(Ⅲ)能很好地分离。展开更多
基金Project (2009AA06Z106) supported by the High-tech Research and Development Program of ChinaProject (51174104) supported by the National Natural Science Foundation of ChinaProject (20115314110001) supported by the Doctoral Fund of Ministry of Education of China
文摘Extraction of vanadium（IV） from sulphate acid solution was studied using organophosphorous-based extractants D2EHPA, EHEHPA and CYANEX 272 in kerosene. The different parameters affecting the extraction of vanadium（IV） under equilibrium conditions were separately investigated to elucidate the stoichiometry of the extracted species. The distribution ratio of vanadium increased with increasing equilibrium pH of the aqueous phase, concentration of the extractants and temperature. D2EHPA was found to be a stronger extractant, having greater pH functionality than EHEHPA and CYANEX 272. Extraction of vanadium（IV） by these organophosphorous-based extractants involved cation exchange mechanism, and the extracted species appear to be VOR2（HR）2 in the low equilibrium pH and VOR2 in the higher equilibrium pH, where HR refers to the three acidic extractants.
