CeCO_(3)OH has a unique crystal structure and excellent optical,electronic and catalytic properties,which has been widely investigated for many applications.Interestingly,ceria obtained from CeCO_(3)OH has a morpholog...CeCO_(3)OH has a unique crystal structure and excellent optical,electronic and catalytic properties,which has been widely investigated for many applications.Interestingly,ceria obtained from CeCO_(3)OH has a morphology that is similar to that of the precursor,and the CeO_(2)-based products obtained from CeCO_(3)OH exhibit outstanding properties,such as catalytic performances,owing to their designed morphology and oxygen vacancies(OVs).To introduce CeCO_(3)OH into a wider range of potential researchers,we first systematically review the physico-chemical properties,synthesis,reaction and morphology tuning mechanism of CeCO_(3)OH,and summarize the conversion behavior from CeCO_(3)OH to ceria.Then,we thoroughly survey the applications of CeCO_(3)OH and its conversion products.Suggestions for further investigations of CeCO_(3)OH are also made in this review.It is hoped that the exhaustive co mpilation of the valuable properties and considerable potential investigations of CeCO_(3)OH will promote further applications of CeCO_(3)OH and CeO_(2)-based functional materials.展开更多
Ru/CeO_2[RC] and Ru/CeO_2/ethylene glycol（EG） [RCE] nanoparticles were produced by performing a simple hydrothermal reaction at 200℃ for 24 h and found to have two distinct morphologies. The RC nanoparticles are ph...Ru/CeO_2[RC] and Ru/CeO_2/ethylene glycol（EG） [RCE] nanoparticles were produced by performing a simple hydrothermal reaction at 200℃ for 24 h and found to have two distinct morphologies. The RC nanoparticles are phase pureCeO_2; triangular highly crystallineCeCO_3OH nanoparticles are formed from the solution containing EG under the same hydrothermal reaction conditions at p H 8.5. EG plays an important role in the formation of the triangularCeCO_3OH nanoparticles. The polycrystallineCeCO_3OH nanoparticles retain their triangular structure even after calcination at 600℃in air but are transformed into a pureCeO_2 phase. The room temperature photoluminescence of the RC and RCE nanoparticles and of RCE calcined at 600℃[RCE-600] was also investigated. It was found that the high crystallinity triangular RCE-600 sample exhibits the highest photoluminescence intensity.展开更多
基金supported by the National Natural Science Foundation of China (52164025)Basic Research Program from Science&Technology Department of Guizhou Province (20201Y219)Natural Science Research Project of Guizhou Provincial Department of Education (2022041)。
文摘CeCO_(3)OH has a unique crystal structure and excellent optical,electronic and catalytic properties,which has been widely investigated for many applications.Interestingly,ceria obtained from CeCO_(3)OH has a morphology that is similar to that of the precursor,and the CeO_(2)-based products obtained from CeCO_(3)OH exhibit outstanding properties,such as catalytic performances,owing to their designed morphology and oxygen vacancies(OVs).To introduce CeCO_(3)OH into a wider range of potential researchers,we first systematically review the physico-chemical properties,synthesis,reaction and morphology tuning mechanism of CeCO_(3)OH,and summarize the conversion behavior from CeCO_(3)OH to ceria.Then,we thoroughly survey the applications of CeCO_(3)OH and its conversion products.Suggestions for further investigations of CeCO_(3)OH are also made in this review.It is hoped that the exhaustive co mpilation of the valuable properties and considerable potential investigations of CeCO_(3)OH will promote further applications of CeCO_(3)OH and CeO_(2)-based functional materials.
基金support provided by King Abdulaziz City for Science and Technology(KACST)through the Science&Technology Unit at King Fahd University of Petroleum&Minerals(KFUPM)for funding this work through project No.AT-32-21
文摘Ru/CeO_2[RC] and Ru/CeO_2/ethylene glycol（EG） [RCE] nanoparticles were produced by performing a simple hydrothermal reaction at 200℃ for 24 h and found to have two distinct morphologies. The RC nanoparticles are phase pureCeO_2; triangular highly crystallineCeCO_3OH nanoparticles are formed from the solution containing EG under the same hydrothermal reaction conditions at p H 8.5. EG plays an important role in the formation of the triangularCeCO_3OH nanoparticles. The polycrystallineCeCO_3OH nanoparticles retain their triangular structure even after calcination at 600℃in air but are transformed into a pureCeO_2 phase. The room temperature photoluminescence of the RC and RCE nanoparticles and of RCE calcined at 600℃[RCE-600] was also investigated. It was found that the high crystallinity triangular RCE-600 sample exhibits the highest photoluminescence intensity.
